• Title/Summary/Keyword: Intrinsic Parameter

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Study on Rheological and Phermal Properties of Dioiscorea batatas DECAISNE Starch (마(Dioscorea batatas DECAISNE)전분의 Rheology 및 열적 특성에 관한 연구)

  • 최일숙;이임선;구성자
    • Korean journal of food and cookery science
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    • v.8 no.1
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    • pp.57-63
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    • 1992
  • The purpose of this study was to investigate the rheological and thermal properties of yam starch. Yam starch had a hydrodynamic volume with the intrinsic viscosity,[$\eta$], of 0.29dl/g deionized water. The values of the intrinsic viscosity of yam starch, determined to pH 2-11, varied between 0.07 to 0.18 dl/g. The highest intrinsic viscosity was obtained at pH 7. At salt concentrations 0-0.2 M NaCl, the intrinsic viscosity of yam starch was decreased up to 0.05 M NaCl concentration then increased to 0.07 M NaCl concentration and remained constant to reach 0.2 M NaCl concentration. The overlap parameter, calculated with the intrinsic vicosity data, was 3.45 g/dl in deionized water. The thermal properties of yam starch were investigated by Differential Scanning Calorimetry. Three endotherms were observed both pH solution and salt concentation. In the presence of pH 9, the onset temperature of gelatinization peak was the lowest temperature of 50.$32^{\circ}C$ and the enthalpy ($\Delta$H) was increased in this solution. The effect of salt on the thermal properties of yam starch was determined at salt concetration of 0-0.2 M NaCl. The enthalpy significantly decreased to salt concentration 0.07 M NaCl and the lowest onset temperature of this concentration was 52.$90^{\circ}C$.

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Structural Dynamics Optimization by Second Order Sensitivity with respect to Finite Element Parameter (유한요소 구조 인자의 2차 민감도에 의한 동적 구조 최적화)

  • Kim, Yong-Yun
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.15 no.3
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    • pp.8-16
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    • 2006
  • This paper discusses design sensitivity analysis and its application to a structural dynamics modification. Eigenvalue derivatives are determined with respect to the element parameters, which include intrinsic property parameters such as Young's modulus, density of the material, diameter of a beam element, thickness of a plate element, and shape parameters. Derivatives of stiffness and mass matrices are directly calculated by derivatives of element matrices. The first and the second order derivatives of the eigenvalues are then mathematically derived from a dynamic equation of motion of FEM model. The calculation of the second order eigenvalue derivative requires the sensitivity of its corresponding eigenvector, which are developed by Nelson's direct approach. The modified eigenvalue of the structure is then evaluated by the Taylor series expansion with the first and the second derivatives of eigenvalue. Numerical examples for simple beam and plate are presented. First, eigenvalues of the structural system are numerically calculated. Second, the sensitivities of eigenvalues are then evaluated with respect to the element intrinsic parameters. The most effective parameter is determined by comparing sensitivities. Finally, we predict the modified eigenvalue by Taylor series expansion with the derivatives of eigenvalue for single parameter or multi parameters. The examples illustrate the effectiveness of the eigenvalue sensitivity analysis for the optimization of the structures.

Detecting the Influential Observation Using Intrinsic Bayes Factors

  • Chung, Younshik
    • Journal of the Korean Statistical Society
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    • v.29 no.1
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    • pp.81-94
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    • 2000
  • For the balanced variance component model, sometimes intraclass correlation coefficient is of interest. If there is little information about the parameter, then the reference prior(Berger and Bernardo, 1992) is widely used. Pettit nd Young(1990) considered a measrue of the effect of a single observation on a logarithmic Bayes factor. However, under such a reference prior, the Bayes factor depends on the ratio of unspecified constants. In order to discard this problem, influence diagnostic measures using the intrinsic Bayes factor(Berger and Pericchi, 1996) is presented. Finally, one simulated dataset is provided which illustrates the methodology with appropriate simulation based computational formulas. In order to overcome the difficult Bayesian computation, MCMC methods, such as Gibbs sampler(Gelfand and Smith, 1990) and Metropolis algorithm, are empolyed.

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Objective Bayesian testing for the location parameters in the half-normal distributions

  • Kang, Sang-Gil;Kim, Dal-Ho;Lee, Woo-Dong
    • Journal of the Korean Data and Information Science Society
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    • v.22 no.6
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    • pp.1265-1273
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    • 2011
  • This article deals with the problem of testing the equality of the location parameters in the half-normal distributions. We propose Bayesian hypothesis testing procedures for the equality of the location parameters under the noninformative prior. The non-informative prior is usually improper which yields a calibration problem that makes the Bayes factor to be defined up to arbitrary constants. This problem can be deal with the use of the fractional Bayes factor or intrinsic Bayes factor. So we propose the default Bayesian hypothesis testing procedures based on the fractional Bayes factor and the intrinsic Bayes factors under the reference priors. Simulation study and an example are provided.

Accuracy of Multiple Outlier Tests in Nonlinear Regression

  • Kahng, Myung-Wook
    • Communications for Statistical Applications and Methods
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    • v.18 no.1
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    • pp.131-136
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    • 2011
  • The original Bates-Watts framework applies only to the complete parameter vector. Thus, guidelines developed in that framework can be misleading when the adequacy of the linear approximation is very different for different subsets. The subset curvature measures appear to be reliable indicators of the adequacy of linear approximation for an arbitrary subset of parameters in nonlinear models. Given the specific mean shift outlier model, the standard approaches to obtaining test statistics for outliers are discussed. The accuracy of outlier tests is investigated using subset curvatures.

Impact of Internal/External Diffusion on Gasification Reaction Rate Analysis of Coal Char in High Temperatures and Elevated pressures (고온/고압 조건에서의 석탄 촤 내부 및 외부 가스화 반응효과)

  • Kim, Gyeong-Min;Kim, Jin-Ho;Lisandy, Kevin Yohanes;Kim, Ryang-Gyoon;Kim, Gyu-Bo;Jeon, Chung-Hwan
    • Journal of the Korean Society of Combustion
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    • v.21 no.4
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    • pp.23-29
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    • 2016
  • Reactivity of gasification defined by bouardard reaction is critical parameter in efficiency of the gasifier. In this study, char reactivity of the gasification was derived from the experiments using the intrinsic reaction kinetics model. Pressurized wire mesh heating reactor (PWMR) can produce high temperature and high pressure conditions up to 50 atm and 1750 K, respectively and PWMR was designed to evaluate the intrinsic reaction kinetics of $CO_2$ gasification. In this study, Kideco and KCH (sub-bituminous Indonesian coal) were pulverized and converted into char. Experiments used the PWMR were conducted and the conditions of the temperature and pressure were 1373~1673 K, 1~40 atm. To distinguish the pressure effect from high pressurized condition, internal and external effectiveness factors were considered. Finally, the intrinsic kinetics of the Kideco and KCH coal char were derived from $n^{th}$ order reaction rate equations.

Kinetic Model of Steam-Methane Reforming Reactions over Ni-Based Catalyst (니켈기반 촉매를 사용한 메탄가스-수증기 개질반응의 모사)

  • Lee, HongJin;Kim, Woohyun;Lee, Kyubock;Yoon, Wang Lai
    • Korean Chemical Engineering Research
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    • v.56 no.6
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    • pp.914-920
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    • 2018
  • The intrinsic kinetic parameters of steam-methane reforming reactions over commercial nickel-based catalyst were determined. The reaction rate equations were derived from the reaction mechanism-based Langmuir-Hinshelwood chemisorption theory. As the experimental variables for the kinetic study, the reaction temperature ranged from 630 to $750^{\circ}C$ and the steam-to-carbon ratio also varied from 2.7 to 3.5. Based on the experimental data, the efficient optimization algorithm was used to determine the intrinsic kinetic parameters due to the high-dimensional objective function. It is confirmed that the parameter estimation results showed good agreement with the experimental values. Thus, this proposed mathematical reaction model can be used as the basic information to design a catalytic reactor and to optimize operating conditions.

A study on parameter extraction for equivalent circuit model of RF silicon MOSFETs (RF용 Silicon MOSFET 등가회로 모델의 변수추출에 관한 연구)

  • 이성현;류현규
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.12
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    • pp.54-61
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    • 1997
  • An accurate extraction technique is developed to determine full euqivalent circuit parameters of Si MOSFETs using 1 set of measured S-parametes without complicated optimization process. This technique is based on the use of anlytic Z-parameters experessions for resistances and inductances and the Y-parameter ones for ntrinsic parameters. This accuracy is proved over the wide range of gate voltage by observing good agreement between measured and fitted Z-parameter equations and frequency-independent response of the extracted intrinsic parameters. Using this technique, gate voltage-dependencies of model parameters are obained in the saturation region and these results show the similar behavior to the short-channel effects expected from the device theory.

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New RF Empirical Nonlinear Modeling for Nano-Scale Bulk MOSFET (나노 스케일 벌크 MOSFET을 위한 새로운 RF 엠피리컬 비선형 모델링)

  • Lee, Seong-Hearn
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.43 no.12 s.354
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    • pp.33-39
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    • 2006
  • An empirical nonlinear model with intrinsic nonlinear elements has been newly developed to predict the RF nonlinear characteristics of nano-scale bulk MOSFET accurately over the wide bias range. Using an extraction method suitable for nano-scale MOSFET, the bias-dependent data of intrinsic model parameters have been accurately obtained from measured S-parameters. The intrinsic nonlinear capacitance and drain current equations have been empirically obtained through 3-dimensional curve-fitting to their bias-dependent curves. The modeled S-parameters of 60nm MOSFET have good agreements with measured ones up to 20GHz in the wide bias range, verifying the accuracy of the nano-scale MOSFET model.

Intrinsic alignments of emission line galaxies at z ~1.4 from the FastSound redshift survey

  • Tonegawa, Motonari;Okumura, Teppei;Totani, Tomonori;Dalton, Gavin;Yabe, Kiyoto
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.54.1-54.1
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    • 2017
  • Intrinsic alignments (IA), the coherent alignment of intrinsic galaxy orientations, can be a source of a systematic error of weak lensing surveys. The redshift evolution of IA also contains information about the physics of galaxy formation and evolution. We present the first measurement of IA at high redshift, z~1.4, using the spectroscopic catalog of blue star-forming galaxies of the FastSound redshift survey, with the galaxy shape information from the Canada-Hawaii-France telescope lensing survey. The IA signal is consistent with zero with power-law amplitudes fitted to the projected correlation functions for density-shape and shape-shape correlation components, $A_{\delta+}=-0.0040\pm 0.0754$ and $A_{++}=-0.0159\pm 0.0271$, respectively. These results are consistent with those obtained from blue galaxies at lower redshifts (e.g., $A_{\delta+}=0.0035_{-0.0389}^{+0.0387}$ and $A_{++}=0.0045_{-0.0168}^{+0.0166}$ at z=0.51 from the WiggleZ survey), suggesting no strong redshift evolution of IA. The upper limit of the constrained IA amplitude corresponds to a few percent contamination to the weak-lensing shear power spectrum, resulting in systematic uncertainties on the cosmological parameter estimations by $-0.035<\Delta \sigma_8<0.026$ and $-0.025<\Delta \Omega_{\mathrm m}<0.019$.

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