• Title/Summary/Keyword: Internal electrode

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Prgress in MEMS Engine Development for MAV Applications (KAIST의 MAV용 MEMS 엔진 개발 현황)

  • Lee, Dae-Hoon;Park, Dae-Eun;Yoon, Eui-Sik;Kwon, Se-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.6
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    • pp.1-6
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    • 2002
  • Micro engine that includes Micro scale combustor is fabricated. Design target was focused on the observation of combustion driven actuation in MEMS scale. Combustor design parameters are somewhat less than the size recommended by feasibility test. The engine structure is fabricated by isotropic etching of the photosensitive glass wafers. Electrode is formed by electroplating of the Nickel. Photosensitive glass can be etched isotropically with almost vertical angle. Bonding and assembly of structured photosensitive glass wafer from the engine. Combustor size was determined to be 1mn scale. Piston in cylinder moves by fuel injection and reaction. In firing test, adequate engine operation including ignition, flame propagation and piston motion was observed. Present study warrants further application research on MEMS scale internal combustion power units.

Pressure Loss Analysis of the 75 kW MCFC Stack with Internal Manifold Separator (75 kW 용융탄산염 연료전지 (MCFC) 스택 내 압력 손실 해석)

  • Kim, Beom-Joo;Lee, Jung-Hyun;Kim, Do-Hyeong;Kang, Seung-Won;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.5
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    • pp.367-376
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    • 2008
  • To obtain the data of the pressure loss and differential pressure at the inside of the stack that was composed of 126 cells with 7,500 cm2 electrode area, 75kW molten carbonate fuel cell system has been operated. Computational fluid dynamics was applied to estimate reactions and thermal fluid behavior inside of the stack that was adopted with internal manifold type separator. The pressure loss coefficient K showed 72.29 to 84.01 in anode and 6.34 to 8.75 in cathode at low part of cells at the inside of 75 kW MCFC stack respectively. Meanwhile, the pressure loss coefficient of the higher part of cells at the interior of the stack showed 15.36 and 56.44 in anode and cathode respectively. These results mean that there is no big total pressure difference between anode and cathode at the inner part of 75 kW MCFC stack. This result will be reflected in 250kW MCFC system design.

Effects of Remanent Polarization State and Internal Field in Ferroelctric Film on the Hydrogen-induced Degradation Characteristics in Pt/Pb(Zr, Ti)O3/Pt Capacitor (강유전막의 잔류 분극 상태와 내부 전계가 Pt/Pb(Zr,Ti)O3/Pt 커패시터의 수소 열화 특성에 미치는 영향)

  • Kim, Dong-Cheon;Lee, Gang-Un;Lee, Won-Jong
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.75-81
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    • 2002
  • The ferroelectric properties of Pb(Zr,Ti)O$_3$[PZT] films degrade when the films with Pt top electrodes are annealed in hydrogen containing environment. This is due to the reduction activity of atomic hydrogen that is generated by the catalytic activity of the Pt top electrode. At the initial stage of hydrogen annealing, oxygen vacancies are formed by the reduction activity of hydrogen mainly at the vicinity of top Pt/PZT interface, resulting in a shift of P-E (polarization-electric field) hysteresis curve toward the negative electric field direction. As the hydrogen annealing time increases, oxygen vacancies are formed inside the PZT film by the inward diffusion of hydrogen ions, as a result, the polarization degrades significantly and the degree of P-E curve shift decreases gradually. The direction and the magnitude of the remnant polarization in the PZT film affect the motion of hydrogen ions which determines the degradation of polarization characteristics and the shift in the P-E hysteresis curve of the PZT capacitor during hydrogen annealing. When the remnant polarization is formed in the PZT film by applying a pre-poling voltage prior to hydrogen annealing, the direction of the P-E curve shift induced by hydrogen annealing is opposite to the polarity of the pre-poling voltage. The hydrogen-induced degradation behavior of the PZT capacitor is also affected by the internal field that has been generated in the PZT film by the charges located at the top interface prior to hydrogen annealing.

Electrical Pulses of Internal Partial Discharges Accompanying with Electrical Tree in LDPE (LDPE에서 발생된 전기트리에 수반된 내부 부분방전 펄스 해석)

  • Kang, S.H.;Park, Y.G.;Kwon, S.S.;Shin, T.S.;Lim, K.J.
    • Journal of the Korean Society of Safety
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    • v.14 no.1
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    • pp.216-221
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    • 1999
  • The correlation between propagation of electrical tree and internal partial discharges is discussed. We use specimens with needle-plane electrode system made of LDPE(Low Density Polyethylene), observed inception and propagation of electrical tree by optical microscope and investigated the characteristics of the partial discharge (PD) pulses accompanying with propagation of electrical tree. In the specimens with needle-shaped void, the tree propagates branch type. The length of the tree has good linear relation with average discharge power of PD pulses. In the specimens without needle-shaped void, the tree grows bush type tree. The correlation between the area of the tree and the average discharge power of PD pulses has linear relation.

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A Study on the Current-Voltage Measurement of Self-Assembled Organic molecular onto Au Electrode (Au기판에 자기조립화된 유기 단분자의 전압-전류 측정 연구)

  • Kim, Seung-Un;Park, Sang-Hyun;Park, Jae-Chul;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1730-1733
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    • 2004
  • Device miniaturization and high integrated circuit design is of major interest for the development of electronic devices. Various studies have been conducted to develop new material and processing technique[1]. Negative Differential Resistance(NDR) is the defining behavior in several electronic components, including the Esaki diode and most notably, resonant tunneling diodes(RTD)[2]. We made a comparison of electrical properties between 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene and 4-[2,5-dimethoxy-4-(p henylethynyl)phenyl]ethynylphenylethanethioate, which have been well known as a conducting molecule having possible application to molecular level NDR devices. As a result, we measured current-voltage curves using Scanning Tunneling microscopy(STM), I-V curves also showed several current peaks between negative and positive bias region.

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Piezoelectric and Dielectric Characteristics of Low Loss Low Temperature Sintering PMN-PNN-PZT Ceramics with the amount of PNN Substitution (PNN 치환량에 따른 저손실 저온소결 PMN-PNN-PZT 세라믹스의 압전 및 유전특성)

  • Yoo, Ju-Hyun;Kim, Kook-Jin;Jeong, Yeong-Ho;Lee, Su-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.766-770
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    • 2007
  • In this study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator, $0.07Pb(Mn_{1/3}Nb_{2/3})O_3-xPb(Ni_{1/3}Nb_{2/3})O_3-(0.93-x)Pb(Zr,Ti)O_3$ ceramics system were fabricated using $Li_2CO_3-Bi_2O_3-CuO$ sintering aids and the specimens were sintered at $930^{\circ}C$. Thereafter, their piezoelectric and dielectric characteristics were investigated according to the amount of PNN substitution. At 9 mol% PNN substitution, density, electromechanical coupling factor ($k_p$), dielectric constant, mechanical quality factor ($Q_m$) and piezoelectric constant ($d_{33}$) showed the optimum value of $7.86g/cm^3$, 0.60, 1640, 1323 and 387 pC/N, respectively. It is considered that these values are suitable for piezoelectric divece application such ad multilayer piezoelectric actuator and ultrasonic vibrator with pure Ag internal electrode.

A study on the formation and properties of silicone thin film by the plasma polymerization. (플라즈마를 이용한 유기 실리콘 박막의 합성과 그 특성에 관한 연구)

  • Kim, I.S.;Kang, D.P.;Han, D.H.;Yun, M.S.;Park, S.H.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.233-237
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    • 1991
  • In the study, samples were made on the electrode in internal glass bell jar by the radio frequency discharge polymerization. The polymerization rate of samples was observed as a function of r.f. discharge power. The characteristics of polymers obtained from TMDSO and HMDSO were analyzed by FT-IR and TGA, and their electrical properties were examined on insulation resistivity, breakdown voltage, dielectric constant, and tan ${\delta}$. (1) There was no difference between PPTMDSO and PPHMDSO in a polymerization rate and thermal and electrical properties. (2) The growing rates of thin film with discharge powers were from $0.42{\mu}/h$ to $1.2{\mu}m/h$. (3) According to IR spectra analysis, discharge power did not effect polymer structure due to polyermization mechanism and effected only polymerization rate. (4) PPTMDSO and PPHMDSO were thermally resistive polymers which did not decompose to $300^{\circ}C$.

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VISUALIZATION OF THE INTERNAL WATER DISTRIBUTION AT PEMFC USING NEUTRON IMAGING TECHNOLOGY: FEASIBILITY TEST AT HANARO

  • Kim Tae-Joo;Jung Yong-Mi;Kim Moo-Hwan;Sim Cheul-Muu;Lee Seung-Wook;Jeon Jin-Soo
    • Nuclear Engineering and Technology
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    • v.38 no.5
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    • pp.449-454
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    • 2006
  • Neutron imaging technique was used to investigate the water distribution and movement in Polymer Electrolyte Membrane Fuel Cell (PEMFC) at HANARO, KAERI. The Feasibility tests were performed in the first and second exposure rooms at the neutron radiography facility (NRF) at HANARO in order to check the ability of each exposure room, respectively. The feasibility test apparatus was composed of water and pressurized air before making up the actual test apparatus. Due to the low neutron intensity in the second exposure room, the exposure time was too long to investigate the transient phenomena of PEMFC. Although the exposure time was improved to 0.1 sec in the first exposure room, it was difficult to discriminate detail water movement at the channel due to the high noise level. Therefore, the experimental setup must be optimized according to the test conditions. Water discharge characteristics were investigated under different flow field geometries by using feasibility test apparatus and the neutron imaging technique. The water discharge characteristics of a 3-parallel serpentine are superior to those of a 1-parallel serpentine, but water at Membrane Electrode Assembly (MEA) was not removed, regardless of the flow field type.

Effect of Flow Direction on Temperature Uniformity in Solid Oxide Fuel Cell (고체산화물 연료전지의 유동방향에 따른 온도 균일성 영향)

  • Jeon, Dong Hyup;Shin, Dong-Ryul;Ryu, Kwang-Hyun;Song, Rak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.10
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    • pp.667-673
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    • 2017
  • We investigated the temperature uniformity in an anode-supported solid oxide fuel cell, using the open source computational fluid dynamics (CFD) toolbox, OpenFOAM. Numerical simulation was performed in three different flow paths, i.e., co-flow, counter-flow, and cross-flow paths. Gas flow in a porous electrode was calculated using effective diffusivity while considering the effect of interconnect rib. A lumped internal resistance model derived from a semi-empirical correlation was implemented for the calculation of electrochemical reaction. The result showed that the counter-flow path displayed the most uniform temperature distribution.

Performance Evaluation of a Plate-Type Membrane Humidifier for PEMFC (고분자전해질연료전지용 판형막가습기 성능 평가)

  • Kho, Back Kyun;Park, JongCheol;Han, In-Su;Shin, Hyun Khil;Hur, Tae Uk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.98.2-98.2
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    • 2011
  • For optimal performance of a proton exchange membrane fuel cell (PEMFC), the membrane electrode assembly (MEA) requires hydration, and the membrane's conductivity depends on water content. A humidifier is required to ensure that the reactant gas, usually hydrogen and air, is hydrated before entering the fuel cell. Dry membrane operation or improper hydration causes performance degradation. Typically, the humidification of a fuel cell is carried out by means of an internal or external humidifier. A membrane humidifier is applied to the external humidification of transportation or residential power generation fuel cell due to its convenience and high performance. In this study, The experiments were constructed with a plate-type membrane humidifier in terms of geometric parameters and operating parameters. The results show that the temperature and pressure, the channel length, the membrane thickness and gas flow rate are critical parameters affecting the performance of the humidifier.

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