DOI QR코드

DOI QR Code

Piezoelectric and Dielectric Characteristics of Low Loss Low Temperature Sintering PMN-PNN-PZT Ceramics with the amount of PNN Substitution

PNN 치환량에 따른 저손실 저온소결 PMN-PNN-PZT 세라믹스의 압전 및 유전특성

  • Published : 2007.09.01

Abstract

In this study, in order to develop low temperature sintering ceramics for multilayer piezoelectric actuator, $0.07Pb(Mn_{1/3}Nb_{2/3})O_3-xPb(Ni_{1/3}Nb_{2/3})O_3-(0.93-x)Pb(Zr,Ti)O_3$ ceramics system were fabricated using $Li_2CO_3-Bi_2O_3-CuO$ sintering aids and the specimens were sintered at $930^{\circ}C$. Thereafter, their piezoelectric and dielectric characteristics were investigated according to the amount of PNN substitution. At 9 mol% PNN substitution, density, electromechanical coupling factor ($k_p$), dielectric constant, mechanical quality factor ($Q_m$) and piezoelectric constant ($d_{33}$) showed the optimum value of $7.86g/cm^3$, 0.60, 1640, 1323 and 387 pC/N, respectively. It is considered that these values are suitable for piezoelectric divece application such ad multilayer piezoelectric actuator and ultrasonic vibrator with pure Ag internal electrode.

Keywords

References

  1. 정광현, 이덕출, 이창배, 이상호, 류주현, 이형규, 강형원, '$MnO_{2}$ 첨가에 따른 저온소결PCW-PMN-PZT세라믹스의 유전 및 압전특성', 전기전자재료학회논문지, 18권, 2호, p. 136, 2005
  2. 정광현, 이덕출, 류주현, '소결조제 변화에 따른 PCW-PMN-PZT세라믹스의 저온소결 및 압전특성', 전기전자재료학회논문지, 17권, 12호, p. 1320, 2004
  3. H. Li, Z. Yanh, X. Zong, and Y. Chang, 'High electrical properties of W-additive Mn-modified PZT-PMS-PZN ceramics for high power piezoelectric transformer', J. of The Materials Science and Engineering B, Vol. 130, No. 1-3, p. 288, 2006 https://doi.org/10.1016/j.mseb.2006.02.061
  4. X. Zonh, Z. Yang, H. Li, and M. Yuan, 'Effects of $WO_{3}$ addition on the srructure and electrical properties of $Pb_{3}O_{4}$ modified PZT-PFW-PMN piezoelectric ceramics', J. of Materials Research Bulletin, Vol. 41, No. 8, p. 1447, 2006 https://doi.org/10.1016/j.materresbull.2006.02.002
  5. B. Li, G. Li, W. Zhang, and A. Ding, 'Influence of particle size on the sintering behavior and high-power piezoelectric properties of PMnN-PZT ceramics', J. of Materials Science and Engineering B, Vol. 121, No. 1-2, p. 92, 2005 https://doi.org/10.1016/j.mseb.2005.03.007
  6. 류주현, 이상호, 백동수, '$Pb(Ni_{1/3}Nb_{2/3})O_{3}$ 치환에 따른 저온소결 $Pb(Ni_{1/3}Nb_{2/3})O_{3}-Pb(Ni_{1/3}Nb_{2/3})O_{3}-Pb(Zr,Ti)O_{3}$ 세라믹스의 압전 및 유전 특성', 전기전자재료학회논문지, 19권, 1호, p. 35, 2006 https://doi.org/10.4313/JKEM.2006.19.1.035
  7. C. Y. Chen and H. L. Lin, 'Piezoelectric properties of $Pb(Mn_{1/3}Nb_{2/3})O_{3}-PbZrO_{3}-PbTiO_{3}$ ceramics with sintering aid of $2CaO-Fe_{2}O_{3}$ compound', Ceramics International, Vol. 30, No. 8, p. 2075, 2004 https://doi.org/10.1016/j.ceramint.2003.11.010
  8. Z. Yang, X. Zong, H. Li, and Y. Chang, 'Structure and electrical properties of new $Pb(Zr,Ti)O_{3}-Pb(Fe_{2/3}W_{1/3})O_{3}-Pb(Mn_{1/3}Nb_{2/3})O_{3}$ ceramics', J. of Material letters, Vol. 59, No. 27, p. 3476, 2005 https://doi.org/10.1016/j.matlet.2005.06.017
  9. 류주현, 이창배, 정광현, 이충호, 정영호, 백동수, '저온소성 적층 압전변압기용 PMN-PZT계 세라믹스의 $CaCO_{3}$첨가에 따른 압전 특성', 대한전기학회 충북지회, p. 54, 2004

Cited by

  1. Physical properties of inorganic PMW-PNN-PZT ceramics vol.87, 2015, https://doi.org/10.1088/1757-899X/87/1/012099