• Title/Summary/Keyword: Interfacial Treatment

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Nanoparticle Size Effect on Mechanical Properties of Carbon Fiber-reinforced Polymer Composites (탄소섬유강화 에폭시수지의 기계적 성질에 미치는 나노입자크기의 영향)

  • Moon, Chang-Kwon;Kim, Bu-Ahn
    • Journal of Ocean Engineering and Technology
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    • v.29 no.2
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    • pp.186-190
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    • 2015
  • $TiO_2$ nanoparticles can be used to improve the performance of carbon fiber-reinforced epoxy resin composites. In this study, the effect of the size of $TiO_2$ nanoparticles on the mechanical properties of carbon fiber-reinforced epoxy resin composites was investigated. The size of the $TiO_2$ nanoparticles was easily controlled using heat treatment. The size of the $TiO_2$ nanoparticles for this study were20nm, 100nm, and 200nm. Three types of carbon fibers with different diameters were also used in this study. The carbon fiber-reinforced epoxy resin composites with 20-nm $TiO_2$ powder showed the highest tensile strength compared to the other types of CFRP, regardless of the fiber maker or fiber diameter. The size of the $TiO_2$ powder and the diameter of the carbon fiber strongly affected the interfacial properties of all kinds of CFRP in this study.

Temperature Dependence of Thermo-Mechanical Properties of Banana Fiber-Reinforced Polyester Composites

  • Shaktawat, Vinodini;Pothan, Laly A.;Saxena, N.S.;Sharma, Kananbala;Sharma, T.P.
    • Advanced Composite Materials
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    • v.17 no.1
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    • pp.89-99
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    • 2008
  • Using a Dynamic Mechanical Analyzer (DMA), mechanical properties like modulus and phase transition temperature of polyester composites of banana fibers (treated and untreated) are measured simultaneously. The shifting of phase transition temperature is observed in some treatments. The performance of the composite depends to a large extent on the adhesion between polymer matrix and the reinforcement. This is often achieved by surface modification of the matrix or the filler. Banana fiber was modified chemically to achieve improved interfacial interaction between the fiber and the polyester matrix. Various silanes and alkalies were used to modify the fiber surface. Chemical modification was found to have a profound effect on the fiber/matrix interaction, which is evident from the values of phase transition temperatures. Of the various chemical treatments, simple alkali treatment with 1% NaOH was found to be the most effective.

Effect of Atmospheric Plasma Treatments on Mechanical Properties of VGCF/Epoxy

  • Khuyen, Nguyen Quang;Kim, Jin-Bong;Kim, Byung-Sun;Lee, Soo
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.167-175
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    • 2008
  • Vapor grown carbon fibers (VGCF) were treated with atmospheric plasma enhancing the surface area in order to improve the bonding to the matrix in epoxy composites. The changes in the mechanical properties of VGCF/epoxy nanocompostes, such as tensile modulus and tensile strength were investigated in this study. VGCF with and without atmospheric plasma treatment for surface modification were used in this investigation. The interdependence of these properties on the VGCF contents and interfacial bonding between VGCF/epoxy matrix were discussed. The mechanical properties of atmospheric plasma treated (APT) VGCF/epoxy were compared with raw VGCF/epoxy. The tensile strength of APT VGCF/epoxy nanocomposites showed higher value than that of raw VGCF. The tensile strength was increased with atmospheric plasma treatment, due to better adhesion at VGCF/epoxy interface. The tensile modulus of raw VGCF and APT VGCF/epoxy matrix were of the similar value. The dispersion of the VGCF was investigated by scanning electron microscopy (SEM), SEM micrographs showed an excellent dispersion of VGCF in epoxy matrix by ultrasonic method.

Interfacial Properties and Stress-Cure Sensing of Single-Shape Memory Alloy (SMA) Fiber/Epoxy Composites using Electro-Micromechanical Techniques (미세역학적 시험법을 이용한 단-섬유 형태 형상기억합금/에폭시 복합재료의 계면특성 및 응력-경화 감지능)

  • Jang, Jung-Hoon;Kim, Pyung-Gee;Wang, Zuo-Jia;Lee, Sang-Il;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.9 no.3
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    • pp.20-26
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    • 2008
  • It is well know that the structure of shape memory alloy (SMA) can change from martensite austenite by either temperature or stress. Due to their inherent shape recovery properties, SMA fiber can be used such as for stress or cure-monitoring sensor or actuator, during applied stress or temperature. Incomplete superelasticity was observed as the stress hysteresis at stress-strain curve under cyclic loading test and temperature change. Superelasticity behavior was observed for the single-SMA fiber/epoxy composites under cyclic mechanical loading at stress-strain curve. SMA fiber or epoxy embedded SMA fiber composite exhibited the decreased interfacial properties due to the cyclic loading and thus reduced shape memory performance. Rigid epoxy and the changed interfacial adhesion between SMA fiber and epoxy by the surface treatment on SMA fiber exhibited similar incomplete superelastic trend. Epoxy embedded single SMA fiber exhibited the incomplete recovery during cure process by remaining residual heat and thus occurring residual stress in single SMA fiber/epoxy composite.

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Oxygen sensor for the low temperature-measurement using yttria stabilized zirconia(YSZ) electrolyte and Ag electrode (YSZ 전해질과 은 전극을 이용한 저온 산소센서에 대한 연구)

  • Yang, Young-Chang;Park, Chong-Ook
    • Journal of Sensor Science and Technology
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    • v.15 no.2
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    • pp.97-101
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    • 2006
  • Silver electrode having a high Electrocatalytic activity is oxygen-permeable electrode, in which oxygen ad-atoms are adsorbed and moved toward YSZ electrolyte by bulk diffusion. It is the different point in comparison to usual porous electrodes, especially platinum, which react with oxygen only in TPBs(Three Phase Boundaries). Also ad-atoms at TPBs of Pt are diffused to YSZ electrolyte by interfacial diffusion mechanism. These properties were used for turning down the operating temperature of YSZ from over $600^{\circ}C$ to below $450^{\circ}C$. The different heat-treatment temperature between a working electrode and a reference electrode suppresses the formation of silver oxides and reduces a volatility of Ag as well. Above all, these own characteristics and special processes of Ag improved a long-term stability of a oxygen sensor.

Application of a fixed Eulerian mesh-based scheme based on the level set function generated by virtual nodes to large-deformation fluid-structure interaction

  • Hashimoto, Gaku;Ono, Kenji;Okuda, Hiroshi
    • Interaction and multiscale mechanics
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    • v.5 no.3
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    • pp.287-318
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    • 2012
  • We apply a partitioned-solution (iterative-staggered) coupling method based on a fixed Eulerian mesh with the level set function to a large-deformation fluid-structure interaction (FSI) problem where a large-deformable thin structure moves in a high-speed flow field, as an airbag does during deployment. This method combines advanced fluid and structure solvers-specifically, the constrained interpolation profile finite element method (CIP-FEM) for fluid Eulerian mesh and large-deformable structural elements for Lagrangian structural mesh. We express the large-deformable interface as a zero isosurface by the level set function, and introduce virtual nodes with level sets and structural normal velocities to generate the level set function according to the large-deformable interfacial geometry and enforce the kinematic condition at the interface. The virtual nodes are located in the direction normal to the structural mesh. It is confirmed that application of the method to unfolded airbag deployment simulation shows the adequacy of the method.

DEVELOPMENT OF A NUMERICAL TECHNIQUE FOR IMPACT AND SPREADING OF A DROPLET CONTAINING PARTICLES ON THE SOLID SUBSTRATE (미세입자분산 액적의 고체면에서 충돌과 퍼짐현상에 관한 직접수치해석 기법개발)

  • Jeong, Hyun-Jun;Hwang, Wook-Ryol;Kim, Chong-Youp
    • Journal of computational fluids engineering
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    • v.13 no.3
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    • pp.8-13
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    • 2008
  • We present a numerical simulation technique and some preliminary results of the impact and spreading of a droplet containing particles on the solid substrate in 2D. We used the 2nd-order Adams-Bashforth / Crank-Nicholson method to solve the Navier-Stokes equation and employed the level-set method with the continuous surface stress for description of droplet spreading with interfacial tension. The impact velocity has been generated by the instantaneous gravity. The distributed Lagrangian-multipliers method has been combined for the implicit treatment of rigid particles and the discontinuous Galerkin method has been used for the stabilization of the interface advection equation. We investigated the droplet spreading by the inertial force and discussed effects of the presence of particles on the spreading behavior using an example problem. We observed reduced oscillation and spread for the particulate droplet.

A Study on the Dielectric Properties of Epoxy Composites with Frequency Variation (주파수 변화에 따른 에폭시 복합체의 유전특성에 관한 연구)

  • 김상걸;이동규;안준호;이상극;오현석;박건호;박우현;이기식;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.813-816
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    • 2001
  • In this paper, the dielectric properties of epoxy composites used for transformers are studied. The dielectric permittivity and loss of specimen are measured at the frequency range of 30[Hz]∼1[MHz] about temperature 20[$^{\circ}C$],100[$^{\circ}C$] and 140[$^{\circ}C$] respectively from a series of experiments. When the filler is added, between epoxy and silica is formed interface. Therefore, observed higher values of dielectric permittivity and loss in filled epoxy are attributed to MWS polarization effect. Also, glass transition temperature was shifted to higher temperature and value of dielectric permittivity and loss were decreased due to 2nd curing. Deformation of interfacial state is improved and value of dielectric permittivity and loss were decreased at low frequency region by the surface treatment of fillers with silane coupling agents.

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Improvement of carrier mobility on Silicon-Germanium on Insulator MOSFEI devices with a Si-strained layer (Si-strained layer를 가지는 Silicon-Germanium on Insulator MOSFET에서의 이동도 개선 효과)

  • Cho, Won-Ju;Koo, Hyun-Mo;Lee, Woo-Hyun;Koo, Sang-Mo;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.7-8
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    • 2006
  • The effects of heat treatment on the electrical properties of SGOI were examined. We proposed the optimized heat treatments for improving the interfacial electrical properties in SGOI-MOSFET. By applying the additional pre-RTA(rapid thermal annealing) before gate oxidation and post-RTA after dopant activation, the driving current, the transconductance, and the leakage current were improved significantly.

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Preparation and Characterization of Polyimide/Carbon-Nanotube Composites

  • Kim, Bong-Sup;Bae, Sang-Hoon;Park, Young-Hwan;Kim, Ji-Heung
    • Macromolecular Research
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    • v.15 no.4
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    • pp.357-362
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    • 2007
  • Polyimide/carbon nanotube (CNT) composite films, for potential use in high performance microelectronics and aerospace applications, were prepared by mixing a polyisoimide (PII) solution and a CNT suspension in NMP, followed by casting, evaporation and thermal imidization. The CNTs were modified by a nitric acid treatment to improve the thermal and electrical properties, as well as to provide good dispersion of the CNTs in a polymer matrix. The formation of functional groups on the modified CNT was confirmed by Raman spectroscopy. Scanning electron microscopy revealed the modified CNTs to be well dispersed in the polyimide matrix, with a uniform diameter of ca. 50 nm. The thermal stability of the films containing the CNTs was improved due to the enhanced interfacial interaction and good dispersion between the polyimide matrix and modified CNTs. In addition, the thermal expansion coefficient of the composites films was slightly decreased, but the dielectric constants increased linearly with increasing CNT content.