• Title/Summary/Keyword: Interfacial Treatment

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Breakdown Characteritics of XLPE/EPDM on the Treatment Condition of the Interfacial layer (XLPE/EPDM의 계면처리조건에 따른 절연파괴 특성)

  • 한성구;조정형;이창종;박양범;박강식;한상옥
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.230-233
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    • 1996
  • In this paper, We intended to evaluate characteristics of XLPE/EPDM interface which exists in the cable joint. Because the fault was mainly occurred in this interface. We investigated breakdown characteristics of XLPE/EPDM double layered insulator as a funtion of temperature, pressure, annealing time, kinds of jointmaterial. It was shown that breakdown strength of XLPE/EPDM insulators is higher that of XLPE/XLPE or EPDM/EPDM

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The GaAs Inversion-type MISFET using Fluoride Gate Insulator (불화물 게이트 절연막을 이용한 반전형 GaAs MISFET)

  • KWang Ho Kim
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.3
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    • pp.61-66
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    • 1993
  • The interface properties of Fluoride/GaAs structures were investigated. It was foung that rapid thermal annealing(RTA) typically 800-850$^{\circ}C$for 1 min, was useful for improving the interface properties of that structures. The analysis by means of SIMS indicated that interdiffusion of each constitutional atom through the interface was negligible. The interfacial atom bonding model for RTA treatment was proposed. Bases on these results, inversion-type GaAs MISFET was fabricated using standard planar technologies.

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Mechanical Properties of Jute Fiber Reinforced Thermosetting Composites (황마섬유 보강 열경화성 복합재료의 기계적 특성)

  • Lee, C.H.;Song, J.E.;Nam, W.S.;Byun, J.H.;Kim, B.S.;Hwang, B.S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.04a
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    • pp.111-115
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    • 2005
  • Recently, natural fibers draw much interests in composite industry due to low cost, light weight, and environment-friendly characteristics compared with glass fibers. In this study, mechanical properties were evaluated for two extreme cases of jute fiber orientations, i.e. the unidirectional yarn composites and the felt fabric composites. Samples of jute fiber composites were fabricated by RTM process using epoxy resin, and tensile, compression, and shear tests were conducted. As can be expected, unidirectional fiber specimens in longitudinal direction showed the highest strength and modulus. Compared with glass/epoxy composites of the similar fabric architecture and fiber volume fraction, the tensile strength and modulus of jute felt/epoxy composites reached only 40% and 50% levels. However, the specific tensile strength and modulus increased to 80% and 90% of the glass/epoxy composites. The main reason for the poor mechanical properties of jute composites is associated with the weak interfacial bonding between fiber and matrix. The effect of surface treatment of jute fibers on the interfacial bonding will be examined in the future work.

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Equilibrium Thermodynamics of Chemical Reaction Coupled with Other Interfacial Reactions Such as Charge Transfer by Electron, Colligative Dissolution and Fine Dispersion: A Focus on Distinction between Chemical and Electrochemical Equilibria

  • Pyun, Su-Il;Lee, Sung-Jai;Kim, Ju-Sik
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.227-241
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    • 2008
  • This article involves a unified treatment of equilibrium thermodynamics of the chemical reaction coupled with other interfacial (phase boundary) reactions. The modified (restrictive) chemical potential ${\mu}_k^+$, such as electrochemical potential, hydrostatic-chemical (mechanochemical) potential (exceptionally in the presence of the pressure difference) and surface-chemical potential, was first introduced under the isothermal and isobaric conditions. This article then enlightened the equilibrium conditions in case where the release of chemical energy is counterbalanced by the supply of electrical energy, by the supply of hydrostatic work (exceptionally in the presence of ${\Delta}p$), and finally by the release of surface energy, respectively, at constant temperature T and pressure p in terms of the modified chemical potential ${\mu}_k^+$. Finally, this paper focussed on the difference between chemical and electrochemical equilibria based upon the fundamentals of the isothermal and isobaric equilibrium conditions described above.

Fast and Soft Functionalization of Carbon Nanotube with -SO3H, -COOH, -OH Groups for Catalytic Hydrolysis of Cellulose to Glucose

  • Lusha, Qin;Lee, Sungho;Li, Oi Lun
    • Journal of the Korean institute of surface engineering
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    • v.53 no.3
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    • pp.87-94
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    • 2020
  • Herein, sulfonated carbon nanotubes (CNT) have been prepared in dilute sulfuric acid (H2SO4) via a novel sulfonation approach based on gas-liquid interfacial plasma (GLIP) at room temperature. The sulfonic acid groups and total acid groups densities of CNT after GLIP treatment in 2 M H2SO4 for 45 min can reach to 0.53 mmol/g and 3.64 mmol/g, which is higher than that of sulfonated CNT prepared under 0.5 M / 1 M H2SO4. The plasma sulfonated CNT has been applied as catalysts for the conversion of microcrystalline cellulose to glucose. The effect of hydrolysis temperature and hydrolysis time on the conversion rate and product distribution have been discussed. It demonstrates that the total conversion rate of cellulose increasing with hydrolysis temperature and hydrolysis time. Furthermore, the GLIP sulfonated CNT prepared in 2 M H2SO4 for 45 min has shown high catalytic stability of 85.73 % after three cycle use.

Effects of Ar+ ion Beam Irradiation on the Adhesion Forces between Carbon fibers and Thermosetting Resins (Ar+ 이온 빔 조사가 탄소섬유와 열경화성 수지 간 계면결합력에 미치는 영향)

  • 박수진;서민강;김학용;이경엽
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.718-727
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    • 2002
  • In this work, an Ar+ beam was irradiated on carbon fiber surfaces to improve the interfacial shear strength (IFSS) of the resulting composites using an ion assisted reaction (IAR) method h single fiber pull-out test was executed to investigate the basic characteristics of the single Carbon fiber/matrix interface. Based on Greszczuk's geometrical model, the debonding force for pull-out of the fiber from the resins was discussed with the applied ion beam energy as a result, it was known that an ion beam treatment produced the functional groups on fiber surface and etching lines along the fiber axis direction, resulting in increasing the adhesion forces between fibers and matrix, which caused the improvement of the IFSS in a composite system. And, it was also found that the maximum IFSS was shown at 0.8 keV ion beam energy in this system.

Reliability Investigation and Interfacial Reaction of BGA packages Using the Pb-free Sn-Zn Solder (Sn-Zn 무연솔더를 사용한 BGA패키지의 계면반응 및 신뢰성 평가)

  • Jeon, Hyeon-Seok;Yun, Jeong-Won;Jeong, Seung-Bu
    • Proceedings of the KWS Conference
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    • 2005.06a
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    • pp.25-27
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    • 2005
  • Sn-9Zn solder balls were bonded to Cu and ENIG (Electroless Nickel/Immersion Gold) pads, and the effect of aging on their joint reliability was investigated. The interfacial products were different from the general reaction layer formed in a Sn-base solder. The intermetallic compounds formed in the solder/Cu joint were $Cu_{5}Zn_{8}$ and $Cu_{6}Sn_{5}$. After aging treatment, voids formed irregularly at the bottom side of the solder because of Sn diffusion into the $Cu_{5}Zn_{8}$ IMC. In the case of the solder/ENIG joint, $AuZn_{3}$ IMCs were formed at the interface. In the case of the Sn-9Zn/ENIG, the shear strength remained nearly constant in spite of aging for 1000 hours at $150^{\circ}C$. On the other hand, in the case of the Sn-9Zn/Cu, the shear strength significantly decreased after aging at $150^{\circ}C$ for 100hours and then remained constant by further prolonged aging. Therefore, the protective plating layer such as ENIG must be used to ensure the mechanical reliability of the Sn-9Zn/Cu joint.

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Preparation of novel NF membrane via interfacial cross-linking polymerization

  • Lehi, Arash Yunessnia;Akbari, Ahmad;Soleimani, Hosna
    • Membrane and Water Treatment
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    • v.6 no.3
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    • pp.173-187
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    • 2015
  • The goal of present work is the preparation of a novel positively charged nanofiltration (NF) membrane and its development for the cation removal of aqueous solutions. This NF membrane was fabricated by the surface modification of polysulfone (PSf) ultrafiltration support. The active top-layer was formed by interfacial cross-linking polymerization of poly(ethyleneimine) (PEI) with p-xylylene dichloride (XDC) and then quaternized with methyl iodide to form a perpetually positively charged layer. In order to improve the efficiency of nanofiltration membrane, the concentration of PEI, XDC and methyl iodide solutions, PEI coating and cross-linking time have been optimized. As a result, a high water flux and high $CaCl_2$ rejection (1,000 ppm) was obtained for the composite membrane with values of $18.29L/m^2.h$ and 93.62% at 4 bar and $25^{\circ}C$, respectively. The rejections of NF membrane for different salt solutions followed the order of $Na_2SO_4$ < $MgSO_4$ < NaCl < $CaCl_2$. Molecular weight of cut off (MWCO) was calculated via retaining of PEG solutions with different molecular weights that finally, it revealed the Stokes and hydrodynamic radius of 1.457 and 2.507 nm on the membrane selective layer, respectively. The most efficient positively charged nanofiltration membrane exhibited a $Ni^{2+}$ rejection of 96.26% for industrial wastewater from Shamse Hadaf Co. (Kashan, Iran).

INTERFACIAL MORPHOLOGY BETWEEN DENTIN AND ADHESIVES ACCORDING TO TREATMENT OF DENTIN SURFACE OF CERVICAL ABRASION LESION (치경부 마모병소의 상아질 표면처리 방식에 따른 상아질과 접착제 간의 계면 양상)

  • Lee, Yong-Hee;Lee, Hee-Joo;Hur, Bock
    • Restorative Dentistry and Endodontics
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    • v.26 no.1
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    • pp.51-63
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    • 2001
  • In order to know the effect of dentin bonding agents on the restoration of cervical abrasion, Scotchbond Multipurpose Single Bond and Clearfil Liner Bond 2 were used in 51 teeth with abrasion lesion and normal teeth. The surface structure and dentinal tubules of acid etched dentin and resin replica were examined using scanning electron microscopy. The interfacial morphology between dentin and adhesives was investigated by confocal laser scanning microscopy. Following results were obtained. 1. The hybrid layer and resin tag of the dentin showing cross-sectional surface of dentinal tubules are thicker and longer than those of dentin showing oblique surface of dentinal tubules. 2. The sclerotic cast was frequently observed in dentinal tubule, and the cast looked like cuboidal or rhomboidal-shaped crystals clumped from outer side to inner side. 3. The formation of hybrid layer and resin tag was the most prominent in Scotchbond Multipurpose group, whereas Clearfil Liner Bond 2 group showed very poor formation. The formation of hybrid layer and resin tag in Single Bond group was less than Scotchbond Multipurpose group.

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A Study on the Direct Synthesis of TaC by Cast-bonding (주조접합법에 의한 TaC 직접합성에 관한 연구)

  • Park, Heung-Il;Lee, Sung-Youl
    • Journal of Korea Foundry Society
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    • v.17 no.4
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    • pp.371-378
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    • 1997
  • The study for direct synthesis of TaC carbide which was a reaction product of tantalum and carbon in the cast iron was performed. Cast iron which has hypo-eutectic composition was cast bonded in the metal mold with tantalum thin sheet of thickness of $100{\mu}m$. The contents of carbon and silicon of cast iron matrix was controlled to have constant carbon equivalent of 3.6. The chracteristics of microstructure and the formation mechanism of TaC carbide in the interfacial reaction layer in the cast iron/tantalum thin sheet heat treated isothermally at $950^{\circ}C$ for various time were examined. TaC carbide reaction layer was grown to the dendritic morphology in the cast iron/tantalum thin sheet interface by the isothermal heat treatment. The composition of TaC carbide was 48.5 at.% $Ti{\sim}48.6$ at.% C-2.8 at.% Fe. The hardness of reaction layer was MHV $1100{\sim}1200$. The thickness of reaction layer linearly increased with increasing the total content of carbon in the cast iron matrix and isothermal heat treating time. The growth constant for TaC reaction layer was proportional to the log[C] of the matrix. The formation mechanism of TaC reaction layer at the interface of cast iron/tantalum thin sheet was proved to be the interfacial reaction.

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