• Title/Summary/Keyword: Interfacial Layer

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A Study on Zirconia/Metal Functionally Gradient Materials by Sintering Method(II) (소결법에 의한 $ZrO_2/Metal$계 경사기능재료에 관한 연구(II))

  • 정연길;최성철
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.120-130
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    • 1995
  • To analyze the mechanical property and the residual stress in functionally gradient materials(FGMs), disctype TZP/Ni-and TZP/SUS304-FGM were hot pressed using powder metallurgy compared with directly bonded materials which were fabricated by the same method. The continuous interface and the microstructure of FGMs were characterized by EPMA, WDS, optical microscope and SEM. By fractography, the fracture behavior of FGMs was mainly influenced by the defects which originated from the fabrication process. And the defectlike cracks in the FGMs induced by the residual stress have been shown to cause failure. This fact has well corresponded to the analysis of the residual stress distribution by Finite Element Method (FEM). The residual stress generated on the interface (between each layer, and matrix and second phase, respectively) were dominantly influenced on the sintering temperature and the material constants. As a consequence, the interfacial stability and the relaxation of residual stress could be obtained through compositional gradient.

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Enhanced Interfacial Adhesion between Polymers and Metals(Cu) by Low Energy Ion-beam Irradiation with Reactive Gases (반응성 기체를 첨가한 저 에너지 이온빔 처리에 의한 고분자와 금속 간의 계면 접착력 증가에 관한 연구)

  • Lee, Ji-Seok;Seo, Yong-Sok;Kim, Han-Seong;Gang, Tae-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.75-78
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    • 2005
  • Using a low-energy Ar+ ion-beam with and without reactive gases, polymers such as chemically stable poly(ether ether ketone) (PTFE) and poly(ether ether ketone) (PEEK) films were modified to have special surface features. The adhesion strength between the polymers and the copper was significantly improved because of both changes in the surface topography and chemical interactions due to polymer surface functionalization (oxidation and amination). The surface modification altered the failure mode from adhesive failure for the unmodified polymer/Cu interface to cohesive failure for the surface-modified polymer/Cu layer interface..

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Suppression of interfacial crack for foam core sandwich panel with crack arrester

  • Hirose, Y.;Hojo, M.;Fujiyoshi, A.;Matsubara, G.
    • Advanced Composite Materials
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    • v.16 no.1
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    • pp.11-30
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    • 2007
  • Since delamination often propagates at the interfacial layer between a surface skin and a foam core, a crack arrester is proposed for the suppression of the delamination. The arrester has a semi-cylindrical shape and is arranged in the foam core and is attached to the surface skin. Here, energy release rates and complex stress intensity factors are calculated using finite element analysis. Effects of the arrester size and its elastic moduli on the crack suppressing capability are investigated. Considerable reductions of the energy release rates at the crack tip are achieved as the crack tip approached the leading edge of the crack arrester. Thus, this new concept of a crack arrester may become a promising device to suppress crack initiation and propagation of the foam core sandwich panels.

Effect of Pretreatments on Graphene Coated Bipolar Plate of PEMFC on Electrochemical (전처리가 그래핀을 코팅한 고체고분자 연료전지 분리판의 전기화학적 특성에 미치는 영향)

  • Cha, Seong-Yun;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.13 no.6
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    • pp.224-232
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    • 2014
  • Effect of pretreatments on the graphene coated bipolar plate of proton exchange membrane fuel cell(PEMFC) was investigated in simulated environments for PEMFC by using electrochemical measurement techniques. Interfacial contact resistance(ICR) between the graphene coated bipolar plate and the gas diffusion layer(GDL) was measured. The value of ICR decreased with an increase in compaction stress($20N/cm^2{\sim}220N/cm^2$). ICR of graphene coated bipolar plate was higher than that of bare 316L stainless steel. However, Potentiodynamic measurement results showed that the corrosion resistance of graphene coated bipolar plate was higher than that of bare 316L stainless steel. $H_2SO_4$ acid pretreatment was the most effective among various pretreatments. The lowest ICR and the corrosion current density were obtained when using $H_2SO_4$ solution pretreatment.

A study of a new interfacial instability between two vertical fluid layers of different densities (수직평판 사이를 흐르는 두 점성유체의 밀도차에 의한 계면의 새로운 불안정성 연구)

  • Lee, Cheol-U;Ju, Sang-U;Lee, Sang-Chun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.12
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    • pp.3949-3959
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    • 1996
  • A new interfacial instability between two vertical fluid layers of different densities is studied. The two layers are flowing between two parallel vertical plates vertically upward or downward, forming counter- or concurrent flows. In order to extend the study to highly-nonlinear regime in future studies, a nonlinear interface evolution equation is derived, and the stability analysis is performed based on the evolution equation. Among the parameters studies are the ratios of the fluid densities and layer thicknesses and the net flow rate.

Interfacial Reaction of Galvanized Steel in Ni Added Zn-0.18Al Bath (Zn-0.18Al 도금욕에서 Ni첨가에 따른 아연 도금강의 계면반응)

  • 이경구;기회봉;이도재
    • Journal of the Korean institute of surface engineering
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    • v.32 no.4
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    • pp.547-554
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    • 1999
  • The interfacial reaction, spangle and coating thickness of galvanized steel in Ni added Zn-0.18Al bath have been investigated. The size of spangle and thickness of reaction layer were observed under an optical microscope, SEM and EDS. Analysing the experimental results concerning spangle size of galvanized steel it was found that Ni addition in Zn-0.18Al bath tended to be minimized spangle size. For Zn-0.18Al bath, addition of 0.1Ni suppressed the formation of Fe-Zn intermetallic compounds but increased with Ni content above 0.1%. The coating thickness of galvanized steel was reduced with Ni addition in Zn-0.18Al bath, especially in Zn-0.18Al-0.05Ni bath. Addition of Al in Ni containing bath resulted in forming the Al-Ni intermetallic compounds such as $Al_3$Ni$_2$ and $Al_2$Ni which consist most of top precipitates.

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The Study on the Properties of EPDM/NR Blends (EPDM/NR 블랜드의 물성에 관한 연구)

  • Go, Jin-Hwan;Park, Sung-Soo
    • Elastomers and Composites
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    • v.29 no.2
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    • pp.121-130
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    • 1994
  • The physical properties of rubber blend between natural rubber(NR) and ethylene propylene diene terpolymer(EPDM) were investigated as a study of EPDM composite materials. For EPDM/NR blends, the effects of ethylene and diene contents in EPDM, blend ratio, dicumyl peroxide(DCP) curing system on the physical properties, interfacial adhesion force and dynamic crack growth etc. were studied. EPDM/NR blends loaded with carbon black were prepared by mechanical mixing and cured by plate heating cure press. Crosslinking density was measured by swelling method with toluene. The physical properties of all blends were measured with Instron, fatigue to failure(FTF), Demattia flex cracking tester(DMFC), scanning electron microscopy (SEM), etc. As the ethylene and diene contents in EPDM increased, the physical properties, such as dynamic crack growth, adhesion to other component were increased too. Interfacial adhesion force of EPDM/NR blends to dissimilar layer was improved by the use of optimum peroxide curing system.

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A Study of Conjugate Laminar Film Condensation on a Flat Plate (수평평판에서 복합 층류 막응축에 대한 연구)

  • Lee Euk-Soo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.303-311
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    • 2005
  • The problem of conjugate laminar film condensation of the pure saturated vapor in forced flow over a flat plate has been investigated as boundary layer solutions. A simple and efficient numerical method is proposed for its solution. The interfacial temperature is obtained as a root of 3rd order polynomial for laminar film condensation, and it is presented as a function of the conjugate parameter. The momentum and energy balance equations are reduced to a nonlinear system of ordinary differential equations with four parameters: the Prandtl number, Pr, Jacob number, $Ja^{\ast}$, defined by an overall temperature difference, a property ratio R and the conjugate parameter ${\zeta}$. The approximate solutions thus obtained reveal the effects of the conjugate parameter.

Evaluation of Electrochemical Characteristics on Graphene Coated Austenitic and Martensitic Stainless Steels for Metallic Bipolar Plates in PEMFC Fabricated with Hydrazine Reduction Methods (하이드라진으로 환원시킨 그래핀을 코팅한 오스테나이트와 마르텐사이트 스테인리스 강 고체고분자형 연료전지 금속 분리판의 전기화학적 특성 평가)

  • Cha, Seong-Yun;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.15 no.2
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    • pp.92-107
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    • 2016
  • Graphene was coated on austenitic and martensitic stainless steels to simulate the metallic bipolar plate of proton exchange membrane fuel cell (PEMFC). Graphene oxide (GO) was synthesized and was reduced to reduced graphene oxide (rGO) via a hydrazine process. rGO was confirmed by FE-SEM, Raman spectroscopy and XPS. Interfacial contact resistance (ICR) between the bipolar plate and the gas diffusion layer (GDL) was measured to confirm the electrical conductivity. Both ICR and corrosion current density decreased on graphene coated stainless steels. Corrosion resistance was also improved with immersion time in cathodic environments and satisfied the criteria of the Department of Energy (DOE), USA. The total concentrations of metal ions dissolved from graphene coated stainless steels were reduced. Furthermore hydrophobicity was improved by increasing the contact angle.

The Effect of Pressure on Laminar Film Condensation along a Horizontal Plate (수평평판의 층류 막응축에서 압력의 영향)

  • Lee, Euk-Soo;Lee, Sung-Hong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.12
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    • pp.945-953
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    • 2008
  • Laminar film condensation of saturated vapor in forced flow over a flat plate is analysed. The problem is formulated as exact boundary-layer solution and integral approximate solution. From numerical solutions of the governing equations, it is found that the energy transfer by convection and the effect of inertia term in the momentum equation in negligibly small for low pressure but quite important for high pressure. The condensate rate, liquid-vapor interfacial shear stress and local heat transfer are strongly dependent on the reduced pressure $P_r$ and the modified Jacob number Ja/Pr.