• Title/Summary/Keyword: Interfacial Layer

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Surface Reaction between Phosphate bonded Investment and Ti-Zr-Cr based Alloy for Dental castings (인산염계 주형재와 치과주조용 Ti-Zr-Cr계 합금의 계면반응)

  • Jung, Jong-Hyun;Joo, Kyu-Ji
    • Journal of Technologic Dentistry
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    • v.27 no.1
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    • pp.73-78
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    • 2005
  • The surface-reacted layer of titanium castings greatly affects their mechanical properties. This study analyzed the interfacial zone of Ti-20%Zr-5%Cr alloy castings obtained from phosphate bonded investment and examined the relationship between the surface-reacted layer and hardness. The Vickers hardness of cast disks were tested at 20$\mu m$ intervals from the surface to 120$\mu m$ in depth. The cross-section was observed metallurgically, and line profile of the reacted layer was conducted under the EDX. The surface-reacted layer of Ti-20%Zr-5%Cr alloy is showed a similar tendency to Ti-6%Al-4%V alloy in thickness, and also Si diffusion in multiple reacted layer of Ti-20%Zr-5%Cr alloy is less than cp Ti and similar to Ti-6%Al-4%V alloy. The Vickers hardness in the surface layer was greater than in the inner part, and the Vickers hardness of Ti-20%Zr-5%Cr alloy ranged 650 to 390 and cp Ti ranged 810 to 160, Ti-6%Al-4%V alloy ranged 710 to 530 respectively.

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Buffer Effect of Copper Phthalocyanine(CuPC) (카퍼 프탈로시아닌의 완충효과)

  • Kim, Jung-Hyun;Shin, Dong-Muyng;Shon, Byoung-Choung
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.4
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    • pp.307-311
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    • 1999
  • Interfacial properties of electrode and organic thin layer is one of the most important factor in performing a Light Emitting Diodes(LED). Phthalocyanine copper was used as a buffer layer to improve interface characteristic, so that device efficiency was improved. In this study, LEDs were fabricated as like structures of Indium-Tin-Oxide (ITO) / N,N' -Diphenyl-N,N'-di(m-tolyl)-benzidine (TPD) / 8-Hydroxyquinoline aluminum(Alq) / Aluminum(Al) and Indium-Tin-Oxide(ITO) / N,N'-Diphenyl-N,N' -di(m-tolyl)-benzidine(TPD) / 2-(4-Biphenylyl)-5(4-tert-butyl-phenyl)-1,3,4-oxadiazole(PBD) / Aluminum(Al). In these devices, CuPC was layered at electrode/organic layer interface. As position is changing and thickness is changing, devices showed characteristic luminescence efficiency and luminescence inensity respectively. We showed in this study that luminescence efficiency was improved with CuPC layer in LEDs. The efficiency of device with layer CuPC is higher than that of 2 layer CuPC. However, the luminescence of 2 layer CuPC device got higher value.

Anomalous Exchange Bias of the Top and Bottom NiFe Layers in NiFe/FeMn/NiFe Based Spin Valve Multilayers (NiFe/FeMn/NiFe 스핀밸브 구조의 다층박막에서 상 하부 NiFe 두께에 따른 교환바이어스 조사)

  • S.M. Yoon;J.J. Lim;V.K. Sankar;Kim, C.G.;Kim, C.O.
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.212-212
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    • 2003
  • Many of the spin valve multilayer structures with FeMn as antiferromagnetic layer consist of a NiFe/FeMn/NiFe trilayer where the bottom NiFe layer is the seed layer to facilitate the growth of (111) gama-FeMn antiferromagnetic phase and the top NiFe layer forms the pinned layer[1], In this study, exchange bias of bottom NiFe layer has been investigated as functions of thicknesses of top and bottom NiFe in NiFe/FeMn/NiFe, prepared by rf magnetron sputtering, MH-loop was measured by vibration sample magnetometer (VSM). Two hysteresis loops are corresponded to bottom and top layers, similar to reported loops in spin valve structure. Exchange bias of bottom NiFe could be induced by the interfacial coupling between bottom NiFe and FeMn. But those coupling are strongly dependent on the top and bottom NiFe thicknesses, revealing anomalous character ul exchange bias of bottom NiFe layer.

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Effect of Ni Addition Interfacial Reaction and Corrosion Resistance in Hot Dip Galvanizing (용융안연 도금욕의 Ni첨가가 도금강판의 게면반응 및 내식성에 미치는 영향)

  • 이경구;시희봉;이도재
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.379-388
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    • 1998
  • The iron-zinc interfacial reaction and corrosin properties in galvanizing bath containning Ni have been intestigated. The substrate steel plates were galvanized in Zn or Zn-0.018Al baths with various Ni contents. The corrosion resistance of galvanized specimens was also evaluated by $60^{\circ}$bending test for galvannealing speaaimens. The corrosion resistance was improved with Ni addition in pure Zn bath, while deteriorated with Ni addition in Zn-0.18Al bath. The anti-powdering property, on thhe otherhand, was improved with Ni addition in Zn-0.18Al bath, while deteriorated with Ni addition in pure Zn. It was found that the anti-powdering property was improved with increasing $\xi$ phase ratio in reaction layer.

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Effect of Fabricating Temperature on Hardness Characteristics of $Nb/MoSi_2$ Laminate Composite ($Nb/MoSi_2$ 적층복합재료의 경도특성에 미치는 제조온도의 영향)

  • Lee, Sang-Pill;Yoon, Han-Ki
    • Journal of Ocean Engineering and Technology
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    • v.13 no.4 s.35
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    • pp.37-44
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    • 1999
  • Hardness characteristics and microstructures of $Nb/MoSi_2$ laminate composites were evaluated from the variation of fabricating conditions such as preparation temperature, applied pressure and pressure holding time. $Nb/MoSi_2$ laminate composites composed of $MoSi_2$ powder and Nb sheets were fabricated by the hot press. From experimental results, it was found that the lamination from Nb sheet and $MoSi_2$ powder was an excellent strategy to improve hardness characteristics of monolithic $MoSi_2$. However, interfacial reaction products like(Nb, Mo)$SiO_2\;and\;Nb2Si_3$ formed at the interface of $Nb/MoSi_2$ and increased with fabricating temperature.

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High performance epoxy nanocomposites with amine-functionalized graphenes

  • Park, Sol-Mon;Kim, Dae-Su
    • Proceedings of the KAIS Fall Conference
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    • 2010.11a
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    • pp.470-473
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    • 2010
  • Graphene, consisting of a single layer of carbon in a two-dimensional lattice, has been emerging as a fascinating material with many unique physical, chemical and mechanical properties. In this study, graphenes were prepared by a chemical method. To develop high performance polymer nanocomposites reinforced by graphenes, adequate dispersion of the fillers and strong interfacial bonding between the fillers and the polymer matrix are essential. The purpose of this study was to examine the influence of introducing amine groups on the surfaces of graphenes. FT-IR spectroscopy, SEM were used to confirm the functionalization. Epoxy nanocomposites comprising the graphenes were prepared and their characteristics were investigated by DSC, DMA and TMA. Fracture surfaces of the nanocomposites were investigated by SEM. The functionalized graphenes induced strong interfacial bonding than the pristine graphenes and resulted in considerable improvements in the performance of the nanocomposites.

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Layered Silicate-Polymer Nanocomposites

  • Jeong, Han-Mo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.18-18
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    • 2003
  • Natural clays are composed of oxide layers whose thickness is about 1nm and cations existing between the layers. A number of these layers makes primary particles with a height of about 8∼10nm and these primary particles make aggregates with a size of about 0.1∼10$\mu\textrm{m}$. When layered silicate was made to be organophilic, by exchanging the interlayer cations with organic cationic molecules, the matrix polymer can penetrate between the layers to give a nanocomposite, where 1nm-scal clay layers exist separately in a continuous polymer matrix. These nanostructured hybrid organic-inorganic composites have attracted the great interest of researchers over the last 10 years. They exhibit improved performance properties compared with conventional composites, because their unique phase morphology by layer intercalation or exfoliation maximizes interfacial contact between the organic and inorganic phases and enhances interfacial properties. Since the advent of nylon-6/montmorillonite nanocomposite developed by Toyota Motor Co., the studies on layered silicate-polymer nanocomposites have been successfully extended to other polymer systems. They greatly improved the thermal, mechanical, barrier, and even the flame-retardant properties of the polymers.

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An Analysis on Direct-Contact Condensation in Horizontal Cocurrent Stratified How of Steam and Cold Water (동방향 성층이상유동에서의 직접접촉 응축현상에 대한 해석)

  • Lee, Sukho;Kim, Hho-Jung
    • Nuclear Engineering and Technology
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    • v.24 no.2
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    • pp.130-140
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    • 1992
  • The physical benchmark problem on the direct-contact condensation under the horizontal occurrent stratified flow was analyzed using the RELAP5/MOD2 and /MOD3 one-dimensional model. Analysis was peformed for the Northwestern experiments, which involved condensing steam/water flow in a rectangular channel. The study showed that the RELAP5 interfacial heat transfer model, under the horizontal stratified flow regime, predicted the condensation rate well though the interfacial heat transfer area was underpredicted. However, some discrepancies in water layer thickness and local heat transfer coefficient with experimental results were found especially when there is a wavy interface, and those were satisfied only within the range.

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Dependencies of Dielectric Properties on Temperature and Frequency in PET films with interfaces (계면을 갖는 PET 필름의 유전특성의 온도 및 주파수 의존성)

  • Lee, Chang-Hoon;Lee, Jong-Bok;Lee, Dong-Young;Kang, Moo-Sung;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.938-940
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    • 1998
  • In order to improve insulating character and ability of insulating system of power apparatus, the interfacial and complex structure is widely used. However, the interface or complex structure of insulation materials is reported as a weak point which causes breakdown. As the interface of insulation system degrades its electrical property and eventually causes a failure, the datailed phenomenon analysis is reported. The object of this paper is to evaluate dielectric property of PET film with the interface. The $tan{\delta}$ increased with the existence of semiconducting layer and showed prominent decrease as a function of temperature. Also, the $tan{\delta}$ showed prominent increase as a function of frequency. The dielectric properties of interfacial were affected by the interface characteristics.

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Seismic Analysis of Underground RC Structures considering Interface between Structure and Soil (경계면 요소를 고려한 지하 철근콘크리트 구조물의 지진해석)

  • 남상혁;변근주;송하원;박성민
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.87-92
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    • 2000
  • The real situation of an underground reinforced concrete(RC) structure with the surrounding soil medium subjected to seismic load is quite difficult to be simulated through an expensive work and, even if it is possible to arrange such an experiment, it will be too expensive. So development of analytical method can be applied usefully to seismic design and seismic retrofit through an analysis of seismic behavior and seismic performance evaluation. A path-dependent constitutive model for soil that can estimate the response of soil layer is indispensible for dealing with kinematic interaction of RC/soil entire system under seismic loads. And interface model which deals with the dynamic interaction of RC/soil entire system is also necessary. In this study, finite element analysis program that can consider path-dependent behavior of RC and soil, and interfacial behavior between RC and soil is developed for rational seismic analysis of RC/soil entire system. Using this program, nonlinear behavior of interface between RC and soil is analyzed, and the effect of interfacial behavior to entire system is investigated.

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