• Title/Summary/Keyword: Inorganic injection material

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A Study on the Durability and Environmentally Friendly of Inorganic Grouting Material (무기질계 지반주입재의 내구성 및 친환경적 특성에 관한 연구)

  • Chun, Byungsik;Park, Dukhyum;Kang, Hyoungnam;Do, Jongnam
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.5
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    • pp.37-43
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    • 2008
  • Inorganic injection material, which is one of the ground improvement materials, consists of cement accelerator and inorganic micro particle. The inorganic injection material is known to overcome the major limitations of water glass type improvement materials, which are leaching and accompanying strength loss. The inorganic injection material is superior in durability and strength, and environmentally friendly since leaching is prevented. In this study, the effectiveness and environment-friendliness of the MIS(Micro Injection-process System) using the inorganic injection material is compared to SGR, which uses the water glass. The performed tests were unconfined compression test, chemical resistance test, and fish poison test. The unconfined compression tests showed that the MIS results in 1.7 times higher 28 day strength compared to the SGR. In addition, the strength continually increased with time for the MIS, while it decreased for the SGR. The chemical resistance tests indicated that the rate of change in length using the MIS is 10~25 times smaller than when using the SGR. The fish poison test proved that MIS was more environmentally friendly. The analysis of chemical ingredients of leached showed that the amount of $Cr^{6+}$, Pb and Si leached from the MIS is less compared to the SGR. Accordingly, the MIS grout is more high-strength than existing SGR grout. It is excellent in shortening of construction period, structural stability of foundation and environmentally friendly. So, it is considered that it has not little the problem about groundwater pollution.

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Standardization of Injection System by Inorganic Materialfor Crack Repair of Tunnel Concrete Structures (터널 콘크리트 구조물의 보수를 위한 무기계 균열주입기술의 표준화 연구)

  • Bae, Kee-Sun;Gwak, Su-Jung;Baek, Jong-Myeong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.6
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    • pp.191-197
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    • 2006
  • This study is to establish a standardization of injection system by inorganic material for crack repair of tunnel concrete structures. For this various surveys and experiments were carried out as followed. The first we surveyed capability of injection and crack pattern of concrete structures in site. and second we analyzed the relationship between crack width and volume of injection, and decided pressure and volume of injection. Finally we evaluated the relationship between crack width and volume of injection with kind of concrete structures, and between required time for injection and crack width with thickness of structure. From these surveys and experiments, we cleared the relationship between crack patterns and injection technologies such as volume, pressure of injection and required time for injection with kind of structure.

Improved Electron Injection on Organic Light-emitting Diodes with an Organic Electron Injection Layer

  • Kim, Jun-Ho;Suh, Chung-Ha;Kwak, Mi-Young;Kim, Bong-Ok;Kim, Young-Kwan
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.5
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    • pp.221-224
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    • 2005
  • To overcome of poor electron injection in organic light-emitting diodes (OLEDs) with Al cathode, a thin layer of inorganic insulating materials, like as LiF, is inserted between an Al cathode and an organic electron transport layer. Though the device, mentioned above, improves both turn on voltage and luminescent properties, it has some problems like as thickness restriction, less than 2 nm, and difficulty of deposition control. On the other hand, Li organic complex, Liq, is less thickness restrictive and easy to deposit and it also enhances the performance of devices. This paper reports the improved electron injection on OLEDs with another I A group metal complex, Potassium quinolate (Kq), as an electron injection material. OLEDs with organic complexes showed improved turn-on voltage and luminous efficiency which are remarkably improved compared to OLEDs with Al cathode. Especially, OLEDs with Kq have longer life time than OLEDs with Liq.

Development and performance of inorganic thixotropic backfill for shield TBM tail voids (무기질계 가소성 TBM 뒤채움재 개발 및 성능)

  • Lee, Seongwoo;Park, Jinseong;Ryu, Yongsun;Choi, Byounghoon;Jung, Hyuksang
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.24 no.3
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    • pp.263-278
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    • 2022
  • This paper contains experimental study for the development and performance of TBM backfill material with thixotropic properties. The LW backfill material is widely applied to fill the cavity on the back side of the shield TBM excavation, but has disadvantages such as settlement caused by strength reduction, material separation by groundwater, and reduced plasticity. In this paper, laboratory tests and a model test were conducted to assess the performance of inorganic thixotropic backfill material proposed to improve these problems. The results of laboratory tests show that 1 hr-uniaxial compressive strength of ITB was 12 times higher than LW, and the rate of bleeding of 20 hr was 8.3 times lower, and the result of flow table test was more than 27 times higher. This result indicated that the inorganic thixotropic backfill material has superior properties to LW backfill in terms of strength reduction, material separation, and thixotropy. In the model experiment, a model injection device tester was manufactured and the injection performance and filling rate were verified. When material was injected in the water, it was visually checked whether material separation occurred, and it was confirmed that the filling rate was 96% or more. Comparison results with the test of LW and ITB materials was concluded that ITB can reduce the material separation by groundwater and the occurrence of tunnel cavity.

Electrical Characteristics of Organic Light Emitting Diodes (OLED) using the Alkali Metal Complex as New Electron Injection Layers (알칼리 금속 전자 주입층을 사용한 유기 전기 발광 소자 (OLED)의 전기적 특성)

  • Lee, Hyun-Koo;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1015-1018
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    • 2004
  • We investigate the influence of the New Electron Injection Layers (EIL) on the performance of the Alkali Metal Complex vapor-deposited Organic Light Emitting Diodes(OLED). Two different Alkali Metal Complex were used; Lithium Quinolate (Liq), and Sodium Quinolate (Naq). In all cases, $Alq_3$ was the Electron Transporting Layer (ETL). We measure and compare the current density-voltage (J-V) and luminance-voltage (L-V) characteristics. We concluded that the turn-on voltage, and luminance efficiency are controlled by the type of EIL material used. We show the longer life-time OLED with Alkali Metal Complex EIL than OLED with LiF EIL. And we show the Optimized Alkali Metal Complex thickness is 3nm. Existent LiF to because is inorganic material, there is trouble to do epitaxy into thin layers but regulates the thickness in case of Alkali Metal Complex matter characteristic that is easy be. Alkali Metal Complex also appeared by sensitive thing in thickness than LiF If utilize this material, It is thought much advantages may be at common use of OLED.

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Interfacial Electronic Structures for Electron and Hole Injection in Organic Devices: Nanometer Layers of CsN3 and 1,4,5,8,-naphthalene-tetracarboxylic-dianhydride (NTCDA)

  • Yi, Yeon-Jin;Jeon, Pyeongeu;Lee, Jai-Hyun;Jeong, Kwang-Ho;Kim, Jeong-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.90-90
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    • 2012
  • The electron/hole injections in organic electronic devices have long been an issue due to the large energy level mismatches between electrode and organic layer. To utilize the organic materials in electronic devices, functional thin layers have been used, which reduce the electron/hole injection barrier from electrode to organic material. Typically, inorganic compounds and organic molecules are used as an electron and hole injection layer, respectively. Recently, CsN3 and 1,4,5,8,- naphthalene-tetracarboxylic-dianhydride (NTCDA) are reported as a potential electron and hole injection layers. CsN3 shows unique properties that it breaks into Cs and N and thus Cs can dope organic layer into n-type. On the other side, hole injection anode, NTCDA forms gap states with anode material. In this presentation, we show the electronic structure changes upon the insertion of CsN3 and NTCDA at proper interfaces to reduce the charge injection barriers. These barrier reductions are correlated with device characteristics.

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A Study on the Ground Improvement Effect with Grouting in Backside of Retaining Wall (흙막이 벽체 배면 그라우팅 시 지반보강 효과에 관한 연구)

  • Chu, Ickchan;Byun, Yoseph;Baek, Seungin;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.10
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    • pp.77-83
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    • 2012
  • Recently, excavations using propped walls were popularized in downtown due to reduced settlement of nearby structures. These excavations is induced strain to propped walls or settlement in near ground. In this study, the ground reinforcing effect was proven using NDS, which is an inorganic injection material. Injection tests were performed to compute optimum injection pressure and volume. Next, calibration chamber tests were performed by using computed injection pressure and volume, and wall behaviour was examined for overburden pressures of 50kPa and 150kPa. Ground reinforcing effect was shown when the material behind the propped wall was grouted. From test results, optimum injection pressure was 350kPa and the optimum volume was 10L considering economics. Calibration chamber test results show that after the material was grouted, the maximum settlement was reduced to 19% of the non-grouted condition. For overburden pressures of 50kPa and 150kPa behind the wall, the settlement of the wall increased by 58% and 57% when compared to the case of no overburden pressure.

A Study on Durability and Impermeability of Environmentally Friendly Inorganic Ground Injection Material (환경 친화적인 무기질계 지반주입재의 내구성 및 차수효과에 관한 연구)

  • Chun, Byungsik;Kang, Hyoungnam;Do, Jongnam;Lim, Jooheon
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.6
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    • pp.113-119
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    • 2006
  • Recently, the ground injection method using water glasses as one of the main resources and the products of these constructions have basic problems in terms of the method of constructions for the permanent foundation reinforcement and stopping leakage of water because they have some serious problems such as durability, compressive strength, injectant eluviation and so forth even though they are still used to stop leakage of water in the temporary structures. The purpose of this study is to demonstrate the strength characteristic and environment friendliness of NDS method by unconfined compressive strenth test, permeability test, length change test, leaching test, and assessment of environmental impact in comparison water glass type material. The test results show that NDS method has significant improvement of strength, permeability, volume change, and leaching. An assessment of environmental impact also demonstrates that the NDS material is environmentally friendly.

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Technology Development Trends of Cesium Lead Halide Based Light Emitting Diodes (세슘납할로겐화물 페로브스카이트 기반 LED 기술개발 동향)

  • Pyun, Sun Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.12
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    • pp.737-749
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    • 2016
  • Recently perovskite materials with much cheaper cost and marvellous optoelectronic properties have been studied for next generation LED display devices overseas. Technology development trends of inorganic $CsPbX_3$(X=halogen) based LEDs (PeLEDs) with assumed high stability were investigated on literature worldwide. It was found that syntheses methods of these nanocrystals (NCs, mainly quantum dots, QDs) made great progress. A new room temperature synthesis method showed outstanding PL (photoluminescence) properties such as high quantum yield (QY), narrow emission width, storage stability comparable with, or often exceeding those of conventional hot injection method and CdSe@ZnS type inorganic colloidal QDs. PeLEDs with shell layers might be more promising, indicating urgent real research start of this solution processing technology for small businesses in Korea.

Strength Development Mechanism of Inorganic Injection Material (무기질계 주입재의 강도발현 메커니즘)

  • Han, yunsu;Lee, Jonghwi;Kang, Hyoungnam;Baeg, Seungin;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.10
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    • pp.5-12
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    • 2011
  • Recently, NDS(Natural and Durable Stabilizer)method and other similar methods are composed of inorganic accelerating agent and the ultra-super fine cement have been studied as the ground improvement material in Korea. However, in the existing research, the chemical changing process of NDS in the strength development mechanism with the elapsed curing time and the principles of strength development did not give an explanation. For the popularization of the inorganic grout material, it determined that the mechanism verifying of the curing process had to be clearly preceded. Therefore, unconfined compression test, SEM and XRD analysis were performed by the elapsed curing time and were analyzed. In addition, the same trial for SGR method, that is the representative example of the water glass grout material, was selected as comparative target in order to distinguish properties of NDS more clearly. The result of experiment, the strength development mechanism of NDS could be investigated through the close correlation of the unconfined compression strength - SEM - XRD analysis, and excellence of a performance was confirmed.