• Title/Summary/Keyword: Initial slope

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Electrochemical Characteristics of Transition Metal Pyrophosphate as Negative Electrode Materials through Solid-state Reaction (고상법으로 합성된 리튬이온 이차전지용 음극물질로서 전이금속 피로인산화물의 전기화학적 특성)

  • Hong, Min Young;An, Sang-Jo;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.23 no.4
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    • pp.105-112
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    • 2020
  • Transition metal oxide, which undergoes a conversion reaction in the negative electrode material for a lithium-ion batteries, has a high specific capacity, but still has several critical problems. In this study, manganese pyrophosphate (Mn2P2O7), nickel pyrophosphate (Ni2P2O7), and carbon composite materials with pyrophosphates as novel negative electrode materials instead of transition metal oxide, are synthesized through simple solid-state reaction. The initial reversible capacity of Mn2P2O7 and Ni2P2O7 are 333 and 340 mAh g-1, and when the composite materials are composed with carbon, the reversible capacity increases to 433 and 387 mAh g-1, respectively. The initial Coulombic efficiency is also improved by about 10%. The Mn2P2O7 and carbon composite material has the highest initial capacity and efficiency, and has the best cycle performance. Mn2P2O7 containing polyanion, has a lower specific capacity due to the large mass of polyanion compared to MnO (manganese oxide). However, since Mn2P2O7 shows a voltage curve with a slope, the charging (lithiation) voltage increases from 0.51 to 0.57 V (vs. Li/Li+), and the discharge (delithiation) voltage decreases from 1.15 to 1.01 V (vs. Li/Li+). Therefore, the voltage efficiency of the cell is improved because the voltage difference between charging and discharging is greatly reduced from 0.64 to 0.44 V, and the operating voltage of the full cell increases because the negative electrode potential is lowered during the discharging process.

Soil Analysis on Prediction of Consolidation Settlement in Marine Clays (항만점토(港灣粘土)의 압밀심하량(壓密沈下量) 예측(預測)을 위(爲)한 토질분석(土質分析))

  • Kwon, Moo Nam;Son, Kwang Sik;Lee, Sang Ho
    • Current Research on Agriculture and Life Sciences
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    • v.4
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    • pp.87-94
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    • 1986
  • This study was performed in order to contemplate their correlations between physical and mechanical properties of the marine clays which were collected from main harbors in Korea. The results obtained are as follows: 1. Most of the soils in experimental districts consist of CH. CL. and ML. and they are considered to be still proceeding. 2. The equations of the relationship between compression index and liquid limit are as, follows: CH : $C_c=0.0137$ (LL-22.60) CL : $C_c=0.0123$ (LL-14.64) 3. The relationship between compression index and initial void ratio appears that the higher the plasticity, the easier the slope of the regression line. The equations are as follows : CH : $C_c=0.431$ ($e_o-0.504$) CH : $C_c=0.471$ ($e_o-0.235$) ML : $C_c=0.641$ ($e_o-0.393$) 4. The equations of the relationship between compression index and natural water content are as follows: CH : $C_c=0.0133$ ($W_n-28.27$) CL : $C_c=0.0225$ ($W_n-23.56$) ML : $C_c=0.0106$ ($W_n-16.42$) 5. The relationship between initial void ratio and natural water content, and compression index is highly positive correlation and the equations are as follows : CH : $C_c=0.301$ ($e_o+0.017W_n-1.05$) CL : $C_c=0.141$ ($e_o+0.0567W_n-1.054$) ML : $C_c=0.421$ ($e_o+0.0214W_n-1.121$) 6. The equations of the relationship between initial void ratio and liquid limit, and compression index are as follows : CH : $C_c=0.36$ ($e_o+0.08LL-0.819$) CL : $C_c=0.269$ ($e_o+0.026LL-0.929$) 7. The cohesion of marine clays is no concerned with the increment of depth. The equations of relationship between cohesion and unconfined compression strength are as follows. CH : qu=1.896C+0.0107 CL : qu=1.849C+0.04.

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A Characteristic of Deformation and Strength of Domestic Sands by Triaxial Compression Tests (삼축압축시험에 의한 국내 모래의 변형-강도 특성)

  • Park, Choon Sik;Kim, Jong Hwan;Park, Cheol Soo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.2
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    • pp.515-527
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    • 2014
  • This study conducted experiment for understanding engineering characteristics of domestic sands by examining standard sand and sand from Yokji Island and Nakdong River in terms of confining pressure, $K_0$, over consolidation and relative density factors through triaxial compression test. The test showed that deviator stress by strain positively changed as confining pressure and relative density grow while $K_0$ and over consolidation factors do not directly correlated with it. Angle of internal friction decreases as confining pressure increases which strengthens contact force between particles, and declines as relative density drops, whereas $K_0$ and over consolidation factors hardly affect the results. When it comes to volumetric strain, volume expansion decreases as confining pressure increase due to crushability and rearrangement of particles while $K_0$ and over consolidation shows same movement unconditionally, and relative density appears compressed as it grows at the beginning however it expands as axial strain increases. Modulus of elasticity ($E_{sec}$) by strain has tendency into convergence resulting in initial secant modulus of elasticity ($E_{ini}$) > secant modulus of elasticity($E_{sec}$) > tangent modulus of elasticity ($E_{tan}$). On the other hand, it grows as confining pressure and relative density increase while indicating similar modulus of elasticity ($E_{sec}$) regarding on $K_0$ and over consolidation. Slope of critical line (M) tended to decrease as confining pressure increases, follow same line according to $K_0$, confining pressure and relative density, and increase as relative density grows.

Rearing Density of a Flounder, Paralichthys olivaceus Juveniles in a Closed Recirculating Sea Water System - Possibility of High-density Rearing - (폐쇄순환여과시스템에서의 넙치, Paralichthys olivaceus 치어의 사육밀도 - 고밀도사육의 가능성 -)

  • CHANG Young Jin;YOO Sung Kyoo
    • Journal of Aquaculture
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    • v.1 no.1
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    • pp.13-24
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    • 1988
  • In order to investigate a reasonable rearing density and the possibility of high-density rearing, flounder, Paralichthys olivaceus, juveniles of 2.53$\pm$0.24 cm in total length and 1.12$\pm$0.12 cm in body height were used in this study. The initial rearing density of them was 10 (D10), 20 (D20), 30 (D30) and 40 (D40) individuals per 137.75 $cm^2$ of bottom area, respectively. Ranges of water temperature and specific gravity during the rearing period of 65 days were $21.0\~27.0^{\circ}C$ and 1.024$\~$1.026, respectively, showing relatively higher values than that of natural sea water. Dissolved oxygen during the rearing period was 5.4$\~$7.5 ml/$\iota$ and inorganic nitrate was 0.07$\~$0.48 ppm in $NH_4^+-N$, 0.006$\~$0.33 ppm in $NO_2^{-}-N$ and 3.89$\~$34.06 ppm in $NO_3^{-}-N$. Growth in total length and body height of the juveniles in four rearing density at the end of the experiment was 8.17$\pm$0.80 em and 4.16$\pm$0.39 em, the highest in D20 and 7.72$\pm$0.40 cm and 3.94$\pm$0.21 cm, the lowest in D10. Significant differences, however, were not recognized between the slope values of growth regressions in four rearing density. Slope values of the relative growth between total length and body height of the juveniles in four rearing density were 0.5346, the highest in D10 and 0.5165, the lowest in D30, but there were no significant differences in those values. Survival rate of juveniles at the end of the experiment was $90\%$ in D10, D20 and D30, but that of D40 was $75\%$. The relationship between total length X body height (X) and body surface area of ocular side (Y) to calculate the rate of Y to bottom area in rearing tank (covering rate) as an indicator of rearing density was expressed by a linear regression, Y=0.5994X+0.1840. Covering rate in four rearing density at the end of the experiment was ranged 1.2$\~$4.1 times. Judging from the covering rate above 4 times, it seems to be possible rearing the flounder juveniles in high-density.

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Identification of Quaternary Faults and shallow gas pockets through high-resolution reprocessing in the East Sea, Korea (탄성파 자료 고해상도 재처리를 통한 동해해역의 제4기 단층 및 천부 가스 인지)

  • Jeong, Mi Suk;Kim, Gi Yeong;Heo, Sik;Kim, Han Jun
    • Journal of the Korean Geophysical Society
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    • v.2 no.1
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    • pp.39-44
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    • 1999
  • High-resolution images are drawn from existing seismic data which were originally obtained by Korea Ocean Research & Development Institute (KORDI) during 1994-1997 for deep seismic studies on the East Sea of Korea. These images are analyzed for mapping Quaternary faults and near-bottom gas pockets. First 12 channels are selected from shot gathers for reprocessing. The processing sequence adopted for high-resolution seismic images comprises data copy, trace editing, true amplitude recovery, common-midpoint sorting, initial muting, prestack deconvolution, bandpass filtering, stacking, highpass filtering, poststack deconvolution, f-x migration, and automatic gain control (AGC). Among these processing steps, predictive deconvolution, highpass filtering, and short window AGC are the most significant in enhancement of resolution. More than 200 Quaternanry faults are interpreted on the migrated sections in the shallow depths beneath the seafloor. Although numerous faults are found mostly at the western continental slope and boundaries of the Ulleung Basin, significant amount of the faults are also indicated within the basin. Many of these faults are believed to be formed with reactivation of basement, from geotectonic activities including volcanism, and often originated in Tertiary, indicating that the tectonic regime of the East Sea might be unstable. Existence of shallow gas pockets casts real hazardous warnings to deep-sea drillings and/or to underwater constructions such as inter-island cables and gas pipelines. On the other hand, discovery of these gas pockets heightens the interests in developing natural resources in the East Sea. Reprocessed seismic sections, however, show no typical seismic characteristics for gas hydrates such as bottom-simulating reflectors in the western continental slope and ocean floor.

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Numerical Simulation of Convection-dominated Flow Using SU/PG Scheme (SU/PG 기법을 이용한 이송이 지배적인 흐름 수치모의)

  • Song, Chang Geun;Seo, Il Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.3B
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    • pp.175-183
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    • 2012
  • In this study, Galerkin scheme and SU/PG scheme of Petrov-Galerkin family were applied to the shallow water equations and a finite element model for shallow water flow was developed. Numerical simulations were conducted in several flumes with convection-dominated flow condition. Flow simulation of channel with slender structure in the water course revealed that Galerkin and SU/PG schemes showed similar results under very low Fr number and Re number condition. However, when the Fr number increased up to 1.58, Galerkin scheme did not converge while SU/PG scheme produced stable solutions after 5 iterations by Newton-Raphson method. For the transcritical flow simulation in diverging channel, the present model predicted the hydraulic jump accurately in terms of the jump location, the depth slope, and the flow depth after jump, and the numerical results showed good agreements with the hydraulic experiments carried out by Khalifa(1980). In the oblique hydraulic jump simulation, in which convection-dominated supercritical flow (Fr=2.74) evolves, Galerkin scheme blew up just after the first iteration of the initial time step. However, SU/PG scheme captured the boundary of oblique hydraulic jump accurately without numerical oscillation. The maximum errors quantified with exact solutions were less than 0.2% in water depth and velocity calculations, and thereby SU/PG scheme predicted the oblique hydraulic jump phenomena more accurately compared with the previous studies (Levin et al., 2006; Ricchiuto et al., 2007).

Impact of Turbidity on Protected Plants along River Levees (탁수가 하천 제방보호 식물에 미치는 영향 분석)

  • Kim, Jong-Tae;Kim, Eun-Jin;Kang, Joon-Gu;Yeo, Hong-Koo
    • The Journal of Engineering Geology
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    • v.23 no.2
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    • pp.161-170
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    • 2013
  • We analyzed the effect of changing water level and turbidity on plants that serve to maintain slope stability on levees. In this experiment, soil collected from upstream of Imha Dam was placed in a water tank and planted with river plants of the Salix species: Salix gracilistyla, S. koreensis, and S. glanduosa. Plant regrowth was analyzed stage-by-stage during a recovery period. In addition, we assessed the tolerance of the plants to concentrated torrential rainfall and examined their recovery rates. The results indicate that in the case of these three Salix species, which are the most prevalent river plants in Korea, stem growth is arrested following serious damage and high turbidity. The possibility of regrowth was very low during the 20-day non-submerged recovery period. Although the number of leaves initially decreased during this period, subsequent regrowth was reasonably high: recovery in S. gracilistyla, S. koreensis, and S. glanduosa was up to 59.3%, 251.3%, and 148.4% respectively, compared with the initial condition.

Effects of Crack Velocity on Fracture Resistance of Concrete (콘크리트의 파괴저항에 대한 균열속도의 영향)

  • Yon, Jung-Heum
    • Journal of the Korea Concrete Institute
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    • v.15 no.1
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    • pp.52-59
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    • 2003
  • Tests of concrete CLWL-DCB specimens had been conducted with displacement-controlled dynamic loading. The crack velocities for 381mm crack extension were 0.80 mm/sec ~ 215m/sec. The external work and the kinetic and strain energies were derived from the measured external load and load-point displacement. The fracture resistance of a running crack was calculated from the fitted curves of the fracture energy required for the tests. The standard error of the fracture energy was less than 3.2%. The increasing rate of the fracture resistance for 28 mm initial crack extension or micro-cracking was relatively small, and then the slope of the fracture resistance increased to the maximum value at 90∼145 mm crack extension depending on crack velocity. The maximum fracture resistance remained for 185 mm crack extension, and then the faster crack velocity showed the faster decreasing rate of the maximum fracture resistance. The maximum fracture resistance increased proportionally to the logarithm of the crack velocity from 142 N/m to 217 N/m when the crack velocity was faster than 0.273 m/sec. The maximum fracture resistance of the fastest tests was similar to the average fracture energy density of 215 N/m. To measure the fracture resistance of concrete, the stable crack extension should be larger than 90∼145 mm depending on crack velocity.

Empirical Formula for Propagation Distance of Flood Wave-front in Flat Inundation Area without Obstacle due to Levee Breach (장애물이 없는 평탄지형 제내지에서의 범람홍수파 선단 전파거리 실험식 산정)

  • Yoon, Kwang-Seok;Lee, Jong-Kyu
    • Journal of Korea Water Resources Association
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    • v.40 no.10
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    • pp.833-840
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    • 2007
  • The experimental study was carried out to investigate propagation distance of flood wave due to levee breach in a flat inundation area without obstacle. Hitter solution was considered to formulate the experimental results and a representative form was written referring to existing researches. As a result of experiments, it was found that the propagation velocity of the wave front in inundation area was significantly influenced by the initial water level in a channel, which was similar to flow in a channel due to dam break. An empirical formula was also suggested using the experimental results. The dimensionless propagation distance L can be written as the power function of dimensionless time T Coefficients k and m were varied with the dimensionless time T whereas k and m in Ritter solution were 2 and 0, respectively. The variation of coefficients in the relationship between L and T was influenced by the water depth in the inundation area and the fact proved that the changing points of L in the slope of relationship between L and T are the same to those of relationship between the dimensionless maximum water depth in the inundation area, $h_{max}$ and L.

Words for Numbers and Transcoding Processes Reflected by ERPs during Mental Arithmetic (수 연산과정에서 ERP로 확인된 숫자어휘와 부호변환 과정)

  • Kim, Choong-Myung;Kim, Dong-Hwee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.2
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    • pp.689-695
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    • 2010
  • The effect of the code conversion process of Korean script (Hangul), also known as words for numbers, was investigated using event-related potentials (ERPs) during mental arithmetic operations. Study subjects were asked to determine whether the arithmetic results of a given target stimuli were correctly matched. Visual inspection and statistics of mean ERPs showed stimulus type-dependent processing rather than task-dependent processing. Results of addition and multiplication tasks revealed that the overall temporal profiles of the Arabic numerals were similar to the Hangul words for numbers. The only exception to this observation was a delayed positive-slope peak occurring around 300 ms, which was likely related to the encoding process of Hangul words for numbers to Arabic-digits, defined as a 'transcoding-related potential.' Source analysis confirmed that the topography of different waveforms for the two conditions was attributed to a single dipole located in the left temporo-parietal area; this area is known to be involved in Hangul words for number processing. These results suggest that the initial processing for encoding words for numbers was followed by arithmetic operations without direct access of internal number representation. Korea Academia-Industrial cooperation Society. The Korea Academia-Industrial cooperation Society. The Korea Academia-Industrial cooperation Society. The Korea Academia-Industrial cooperation Society.