• 제목/요약/키워드: Inherent optical properties

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Measuring and Modeling the Spectral Attenuation of Light in the Yellow Sea

  • Gallegos, Sonia-C.;Sandidge, Juanita;Chen, Xiaogang;Hahn, Sangbok-D.;Ahn, Yu-Hwan;Iturriaga, Rodolfo;Jeong, Hee-Dong;Suh, Young-Sang;Cho, Sung-Hwam
    • Journal of the korean society of oceanography
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    • 제39권1호
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    • pp.46-56
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    • 2004
  • Spectral attenuation of light and upwelling radiance were measured in the western coast of Korea on board the R/V Inchon 888 of the Korean National Fisheries Research and Development Institute(NFRDI) during four seasons. The goal of these efforts was to determine the spatial and temporal distribution of the inherent and apparent optical properties of the water, and the factors that control their distribution. Our data indicate that while stratification of the water column, phytoplankton, and wind stress determined the vertical distribution of the optical parameters offshore, it was the tidal current and sediment type that controlled both the vertical and horizontal distribution in the coastal areas. These findings led to the development of a model that estimates the spectral attenuation of light with respect to depth and time for the Yellow Sea. The model integrates water leaving radiance from satellites, sediment types, current vectors, sigma-t, bathymetry, and in situ optical measurements in a learning algorithm capable of extracting optical properties with only knowledge of the environmental conditions of the Yellow Sea. The performance of the model decreases with increase in depth. The mean absolute percentage error (MAPE) of the model is 2% for the upper five meters, 8-10% between 6 and 50 meters, and 15% below 51 meters.

Highly Stable Photoluminescent Qunatum Dot Multilayers by Layer-by-Layer Assembly via Nucleophilic Substitution Reaction in Organic Media

  • 윤미선;김영훈;정상혁;백현희;조진한
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2011년도 춘계학술발표대회
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    • pp.244.2-244.2
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    • 2011
  • We introduce a novel and robust method for the preparation of nanocomposite multilayers, which allows the excellent photoluminescent (PL) properties as well as the accurate control over the composition and dimensions of multilayers. By exchanging the oleic acid stabilizers of CdSe@ZnS quantum dots (QDs) synthesized in organic solvent with 2-bromo-2-methylpropionic acid (BMPA) in the same solvent, these nanoparticles were be alternately deposited by nucleophilic substitution reaction with highly branched poly(amidoamine) dendrimer (PAMA) through layer-by-layer (LbL) assembly process. Our approach does not need to be transformed into the water-dispersible nanoparticles with electrostatic or hydrogen-bonding groups, which can deteriorate their inherent properties, for the built-up of multilayers. The nanocomposite multilayers including QDs exhibited the strong PL properties achieving densely packed surface coverage as well as long-term PL stability under atmospheric conditions in comparison with those of conventional LbL multilayers based on electrostatic interaction. Furthermore, we demonstrate that the flexible multilayer films with optical properties can be easily prepared using nucleophilic substitution reaction between bromo and amino groups in organic media. This robust and tailored method opens a new route for the design of functional film devices based on nanocomposite multilayers.

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Validation of the semi-analytical algorithm for estimating vertical underwater visibility using MODIS data in the waters around Korea

  • Kim, Sun-Hwa;Yang, Chan-Su;Ouchi, Kazuo
    • 대한원격탐사학회지
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    • 제29권6호
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    • pp.601-610
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    • 2013
  • As a standard water clarity variable, the vertical underwater visibility, called Secchi depth, is estimated with ocean color satellite data. In the present study, Moderate Resolvtion Imaging Spectradiometer (MODIS) data are used to measure the Secchi depth which is a useful indicator of ocean transparency for estimating the water quality and productivity. To estimate the Secchi depth $Z_v$, the empirical regression model is developed based on the satellite optical data and in-situ data. In the previous study, a semi-analytical algorithm for estimating $Z_v$ was developed and validated for Case 1 and 2 waters in both coastal and oceanic waters using extensive sets of satellite and in-situ data. The algorithm uses the vertical diffuse attenuation coefficient, $K_d$($m^{-1}$) and the beam attenuation coefficient, c($m^{-1}$) obtained from satellite ocean color data to estimate $Z_v$. In this study, the semi-analytical algorithm is validated using temporal MODIS data and in-situ data over the Yellow, Southern and East Seas including Case 1 and 2 waters. Using total 156 matching data, MODIS $Z_v$ data showed about 3.6m RMSE value and 1.7m bias value. The $Z_v$ values of the East Sea and Southern Sea showed higher RMSE than the Yellow Sea. Although the semi-analytical algorithm used the fixed coupling constant (= 6.0) transformed from Inherent Optical Properties (IOP) and Apparent Optical Properties (AOP) to Secchi depth, various coupling constants are needed for different sea types and water depth for the optimum estimation of $Z_v$.

Synthesis and Optical Properties of Poly[6'-(N-carbazolyl)hexyl-2-ethynylpyridinium bromide]

  • 갈영순;이상섭;배장순;김봉식;장상희;진성호
    • Bulletin of the Korean Chemical Society
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    • 제20권4호
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    • pp.451-455
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    • 1999
  • The polymerization of 2-ethynylpyridine by alkyl bromide carrying carbazole moiety, 6-(N-carbazolyl)hexyl bromide, relatively proceed well to give the corresponding poly[6'-(N-carbazolyl)hexyl-2-ethynylpyridinium bromide) in high yields under DMF reflux conditions without any initiator or catalyst. This polymerization was influenced upon the initial monomer concentration. The polymer yields and inherent viscosities of the resulting polymers were in the range of 34-85% and 0.11-0.21 dL/g, respectively. Instrumental analyses using NMR, IR, and UV-visible spectroscopies and elemental analysis indicated that the resulting polymer has a conjugated polymer backbone system carrying pyridine and n-hexyl carbazole moiety. The polymers were mostly brown powders and completely soluble in DMF, DMSO, nitrobenzene, and formic acid. The photoluminescence spectrum of the dilute polymer solution with the excitation at 383 nm exhibited two sharp peaks at 495 and 540 nm.

저조도 환경 감시 영상에서 시공간 패치 프레임을 이용한 이상행동 분류 (Spatiotemporal Patched Frames for Human Abnormal Behavior Classification in Low-Light Environment)

  • ;공성곤
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2023년도 추계학술발표대회
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    • pp.634-636
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    • 2023
  • Surveillance systems play a pivotal role in ensuring the safety and security of various environments, including public spaces, critical infrastructure, and private properties. However, detecting abnormal human behavior in lowlight conditions is a critical yet challenging task due to the inherent limitations of visual data acquisition in such scenarios. This paper introduces a spatiotemporal framework designed to address the unique challenges posed by low-light environments, enhancing the accuracy and efficiency of human abnormality detection in surveillance camera systems. We proposed the pre-processing using lightweight exposure correction, patched frames pose estimation, and optical flow to extract the human behavior flow through t-seconds of frames. After that, we train the estimated-action-flow into autoencoder for abnormal behavior classification to get normal loss as metrics decision for normal/abnormal behavior.

광섬유 센서의 보링 바 삽입에 의한 진동측정 (The Vibration Measurement of Boring Process by Using the Optical Fiber Sensor at inside of Boring Bar)

  • 송두상;홍준희;곽양양
    • 한국정밀공학회지
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    • 제28권6호
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    • pp.709-715
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    • 2011
  • Chattering in cutting operations are usually a cumbersome part of the manufacturing process in mechanical. Particular, machining performance such as that of the boring process is limited by cutting condition at the movable components. Among various sources of chatter vibration, detrimental point in cutting condition is found a mechanical condition on overhang. It limits cutting speed, depth, surface roughness and tool wear failure as result because the all properties are varying with the metal removal process. In this case, we have to observe the resonance frequencies of a boring bar for continuous cutting. In the established research, boring bar vibration of cutting system has been measured with the aid of accelerometer. However, the inherent parameters of internal turning operations are severely limit for the real time monitoring on accelerometers. At this point, this paper is proposed other method for real time monitoring during continuous cutting with optical fiber at the inside of boring bar. This method has been used a plastic fiber in the special jig on boring bar by based on experimental modal analysis. In this study, improvement of monitoring system on continuous internal cutting was attempted using optical fiber sensor of inside type because usually chattering is investigated experimentally measuring the variation in chip thickness. It is demonstrated that the optical fiber sensor is possibility to measure of chattering with real time in boring process.

Mechanical Properties and Microstructures in WC-12%Co/Low Carbon Steel Metal Matrix Composites(MMC) Welding Overlay

  • 임희식;김태형;박경채
    • Journal of Welding and Joining
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    • 제21권2호
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    • pp.50-56
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    • 2003
  • Metal matrix composites(MMC) consist of metal matrix into which is distributed a second solid phase. The normal intension is to develop a material with superior mechanical properties (for example increased toughness, stiffness and wear resistance) compared to those inherent in the matrix component. In this study, WC-12%Co/low carbon steel MMC overlays have been prepared by Gas Metal Arc Welding(GMAW) according to feeding rate of WC-12%Co grit. The macro and microstructures were examined using optical microscopy (OM) and scanning electron microscopy(SEM) each other. The characteristics of hardness and wear resistance have been investigated. WC-12%Co/low carbon steel MMC overlays which have been taken good beads without porosity and cracks were manufactured by method of GMAW. Matrix of overlayed surface was seen as fish bone and faceted dendrite structures. It was known that structures were iron tungsten carbides, Fe$_{6}$W$_{6}$C which have been occurred by melting of WC-12%Co grits. After MMC had been tested by block-roll wear test it was known that WC-12%Co/low carbon steel MMC has a excellent wear resistance by exiting Fe6w6c and WC-12%Co grit. The consequence was that region of overlay with Fe$_{6}$W$_{6}$C phase has been showed a model of adhesive wear, but region of overlay with WC-12%Co grit was restrained as a result of mechanism that wear of WC-12%Co grit is not adhesive but fracture.racture.

국내 수계의 남조류 원격모니터링을 위한 고유분광특성모델 개선 연구 (A Study on Model Improvement using Inherent Optical Properties for Remote Sensing of Cyanobacterial Bloom on Rivers in Korea)

  • 하림;남기범;박상현;신현주;이혁;강태구;이재관
    • 한국물환경학회지
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    • 제35권6호
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    • pp.589-597
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    • 2019
  • The purpose of this study was improve accuracy the IOPs inversion model(IOPs-IM) developed in 2016 for phycocyanin(PC) concentration estimation in the Nakdong River. Additionally, two optimum models were developed and evaluated with 2017 measurement field spectral data for the Geum River and the Yeongsan River. The used measurement data for IOPs-IM analyzation was randomly classified as training and verification materials at the ratio of 2:1 in all data sets. Using the training data set from 2015-2017, accuracy results of the IOPs-IM generally improved for the Nakdong River. The RMSE(Root Mean Square Error) decreased by 14 % compared to 2016. For the GeumRiver, the results of the IOPs-IM were suitable, except for some point results in 2016. Results of the IOPs-IM in the Yeongsan River followed the overall 1:1 line and MAE(Mean Absolute Error) was lower than other rivers. But the RMSE and MAE values were higher. As a result of applying the validation data to the IOPs-IM, the accuracy of the Nakdong River was reduced to RMSE 17.7 % and MRE 16.4 %, respectively compared with 2016. However, the MRE(Mean Relative Error) was estimated to be higher by 400 % in the Geum River, and the RMSE was more than 100 mg/㎥ of the Yeongsan River. Therefore, it is necessary to get the continuously data with various sections of each river for obtain objective and reliable results and the models should be improved.

효소 모사 활성 무기 나노입자의 진단 및 치료 응용연구 동향 (Recent Progress in Inorganic Nanoparticles with Enzyme-Mimetic Activities and Their Applications to Diagnosis and Therapy)

  • 이준수;김태연;김봉근;나현빈
    • 공업화학
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    • 제31권4호
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    • pp.352-359
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    • 2020
  • 무기 나노입자는 나노미터 크기에서 유래된 광학 및 자성 성질과 같은 물리적 특성을 활용하여 생명-의학 분야에 적극적으로 응용되어왔다. 최근에는 물리적 성질 이외에 무기 나노입자가 갖는 화학적 성질, 특히 효소와 유사한 촉매활성을 이용한 새로운 진단법들이 개발되고 있다. 효소 모사 활성의 검증에 집중하던 초기연구에서, 현재는 활성 메커니즘의 이해를 통한 적극적 활성 제어 및 치료 특성의 직접적 응용으로 연구 범위가 확장되고 있다. 본 총설에서는 효소 모사 활성을 갖는 무기 나노입자, 소위 "나노자임"의 촉매 활성 제어와 치료 및 진단 분야에서의 연구성과들에 대한 최근 동향을 정리하였다. 무기 나노입자의 효소 모사 활성은 입자의 고유한 물리적 성질과 결합되어 새로운 진단 및 치료법의 개발로 이어질 것으로 기대한다.

방향족 고리 함량이 공중합 액정 폴리에스터의 성질에 미치는 영향 (Effect of Aromatic Ring Content on the Properties of Liquid Crystalline Copolyesters)

  • 박종률;방문수
    • 한국산학기술학회논문지
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    • 제15권1호
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    • pp.575-580
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    • 2014
  • 단위체로서 4-[4-(4-hydroxyphenoxy)butoxy]benzoic acid (HBBA)와 p-hydroxy benzoic acid (HBA)를 사용하여 직접 중축합방법에 의해 액정 공중합체를 합성하였다. 합성된 중합체의 구조와 성질은 $^1H$-NMR, FT-IR, DSC, TGA, POM에 의하여 조사되었다. 연구결과에 의하면, 페놀/p-클로로페놀/1,1,2,2-테트라클로로에탄 (25/40/35=w/w/w) 내에서 측정된 중합체의 고유점성도 (${\eta}_{inh}$)는 0.77~1.60 dL/g로 측정되었으며, 중합체 P-80을 제외하고, 공중합체들의 전이온도와 액정상의 범위는 HBA의 양이 증가함에 따라 증가하였다. 중합체의 이러한 특성은 중합체 사슬의 불규칙성과 강직성이 증가하였기 때문으로 생각된다.