• Journal of the Korean Society of Industry Convergence
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• v.26 no.5
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• pp.757-763
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• 2023

Major industrial accidents in which workers die due to fires or explosions while working at chemical substance handling workplaces continue to occur. Among the major industrial accidents that occurred between 2005 and 2021, the accident status by work situation and equipment was analyzed. Through analysis, it was confirmed that storage, reaction, and piping facilities were the main causes of the accident, and a self-checklist for each facility was developed. Verification was conducted through the supply and use groups to evaluate the suitability of the use, duties, and items of the self-checklist. The user group showed higher satisfaction than the supplier group for all three suitability of use, job, and item. In particular, since the inspection items of the self-checklist were organized around the cause of the accident derived through the analysis of actual accident cases, the satisfaction level was high in all groups. It is expected that the self-checklist developed through this study will be useful not only for large companies but also for small and medium-sized chemical industries that lack professional manpower.

• Journal of Industrial Technology
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• v.43 no.1
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• pp.1-6
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• 2023

TiO₂ is a versatile metal oxide material that is frequently used as a photo-catalyst for organic pollutant oxidation and a functional material for ultraviolet-ray protection. To improve its chemical/physical properties and widen the range of industrial application, it is demanded to control the crystalline feature and morphology precisely by applying advanced nano-synthesis methods. In this study, we prepared TiO₂ nanoparticles using the water-in-oil (W/O) microemulsion method and compared them with the particles synthesized by the conventional precipitation method. Also, we tried to find the optimum conditions for obtaining nano-sized, anatase-rich TiO₂ particles by the W/O microemulsion method. We analyzed the crystalline feature and particle size of the prepared samples using X-ray diffraction (XRD) and Transmission electron microscopy (TEM). In summary, we found the W/O microemulsion is more effective than precipitation in obtaining nano-sized TiO₂. The best result was derived when the microemulsion was formed using AOT surfactant, hydrolysis was performed under basic condition and the sample was calcined at 200℃.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.28 no.2
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• pp.175-189
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• 2018

Objectives: In this study, we analyze statistics on industrial accidents caused by chemical skin contact and provide skin toxicity hazard information on the related domestic system and circulation volumes. Methods and Results: We analyzed occupational fatalities and skin diseases caused by chemical leaks and contact from 2007 to 2016(10 years) and surveyed data on occupational skin diseases using the 2014 work environment survey data. The NIOSH Skin Notation Profiles for 57 chemical substances, which are provided to prevent occupational skin diseases, were searched and hazard information on skin contact with chemical substances was classified. In order to identify skin toxicity information among domestically distributed and legally regulated substances and to investigate skin-toxic substances, MSDS basic data on 19,740 chemical substances provided on the homepage of Korea Occupational Safety & Health Agency were searched. Acute toxicity(dermal) category 1-4 substances totaled 1,020, and the number of chemical substances classified as category 1 and 2 substances were 135 and 137, respectively. In the chemical substances prescribed by the Ministry of Employment and Labor, 173 substances were classified into acute toxicity(dermal) categories 1-4, 58 of which correspond to category 1 or 2. Conclusions: Within the present range of industrial accidents, the proportion of skin diseases due to contact with chemicals is not high. However, there is always a risk of occupational skin diseases due to increasing chemicals and due to the use of new chemicals. It is hoped that this information will be used by workplace safety and health officials and health and safety experts to prevent acute toxity(dermal) due to chemical skin contact.

• Applied Chemistry for Engineering
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• v.20 no.2
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• pp.201-207
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• 2009

The hydrogenation reaction of methyl dodecanoate for the synthesis of 1-dodecanol has been carried out in the presence of a copper chromite catalyst. The catalysts were synthesized by ceramic method, co-precipitation, and improved co-precipitation method and the particles were characterized by SEM and XRD. Also, the products of the reaction were assigned by GC, GC/MSD and NMR. The particles synthesized by each method showed (1) a spherical shape with the size of 3.2 to $7.0{\mu}m$, (2) an agglomerated spherical shape with the size of 50 to 500 nm and (3) a spherical shape with smaller particle size, respectively. Especially, in order to control the size of particles, the particles were synthesized in various dispersant solutions as Span 80, polyacrylate, and polyethyleneglycols (PEGs). The particles synthesized in PEG (Mw = 4000) solution showed the smallest particle size of 30 to 50 nm and the regularity of the particle size distribution. Our experimental results elucidated that the activity of catalyst for hydrogenation increases with decreasing the size of catalyst particle. The highest yield of dodecanol in the hydrogenation reaction was 95.5% when copper chromite synthesized in the PEG solution was used as a catalyst in the optimized reaction condition.

• Journal of the Korean Society of Industry Convergence
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• v.26 no.5
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• pp.765-774
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• 2023

The Ministry of Employment and Labor implemented the process safety management(PSM) system from 1996 to prevent major industrial accidents caused by chemical substances, but the number of accidents did not drastically decrease. Even in workplaces with excellent PSM ratings, large-scale chemical accidents still occur due to non-compliance with safety work procedures and insufficient safety measures during maintenance and other work. Accordingly, the chemical accident risk warning system was introduced in 2014 to supplement the PSM system and prevent accidents that may occur during regular or unexpected maintenance and repair work. In the meantime, changes in the safety management system have been checked since the introduction of the chemical accident risk warning system at chemical handling workplaces, and based on the results, a plan for upgrading this system has been proposed. The effect of the CARW system was found to directly prevent accidents through wired and on-site consulting and post-management at the workplace and indirectly contribute to the establishment of a safety and health management system at the workplace, such as improving safety culture awareness.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.43 no.3
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• pp.77-86
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• 2020

In this study, to improve the logistics flow of existing given chemical logistics warehouse, four logistics flow alternatives were proposed to minimize truck interference by building simulation model. The simulation model for chemical storage warehouse was built to evaluate system performance. Among the four new improved alternatives based on the basic model, the model with the same truck's pathways and locations of facilities identified an increase in the number of interferences but a decrease in daily working hours as the number of resources in a particular facility increases. Therefore, the three groups were classified as 'efficiency', 'complementary', and 'safety' based on the daily working hours, and the ratio of trucks entering two types of logistics warehouse was set in consideration of future market fluctuations. For each of the six types, the optimal number of resources was selected as the number of resources in the facilities with the least number of interferences in the basic model and the evaluation measures and characteristics set in this study were compared and analyzed. As a result, the Alternative 4 model operating the underground roadway produced interference between 17.0% and 36.4% of the basic model, with 113.3% of the interior loadspace.

• Journal of Microbiology and Biotechnology
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• v.14 no.6
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• pp.1190-1195
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• 2004

In recent years, there has been an intensive research on decolorization of dye and textile wastewater by various fungal strains. In this study, the decolorization ability of three commercial dyes, acid yellow 99, acid blue 350, and acid red 114, were investigated using 10 fungal strains. Among the fungal strains tested, Trametes versicolor KCTC 16781 completely decolorized all dyes in both solid and liquid experiments, and was also able to decolorize the mixture of those three dyes in liquid experiments. The secretion of the ligninolytic enzymes into the extracellular medium during decolorization by T versicolor KCTC 16781 was also studied. No lignin peroxidase activity was detected, and manganese peroxidase and laccase activities were investigated.

• 한국생물공학회:학술대회논문집
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• 2005.10a
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• pp.176-176
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• 2005

• Journal of the Korean Chemical Society
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• v.10 no.1
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• pp.23-23
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• 1966

• Bulletin of the Korean Chemical Society
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• v.12 no.6
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• pp.711-712
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• 1991