• Title/Summary/Keyword: Improvement rate

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Analysis of Electrochemical Properties of Sulfide All-Solid-State Lithium Ion Battery Anode Material Using Amorphous Carbon-Removed Graphite (비정질 탄소가 제거된 흑연을 이용한 황화물계 전고체 리튬이온전지 음극소재 전기화학적 특성 분석)

  • Choi, Jae Hong;Oh, Pilgun
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.58-63
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    • 2022
  • Graphite has been used as an anode material for lithium-ion batteries for the past 30 years due to its low de-/lithiation voltage, high theoretical capacity of 372 mAh/g, low price, and long life properties. Recently, all-solid-state lithium-ion batteries (ASSLB), which are composed of inorganic solid materials with high stability, have received great attention as electric vehicles and next-generation energy storage devices, but research works on graphite that works well for ASSLB systems are insufficient. Therefore, we induced the performance improvement of ASSLB anode electrode graphite material by removing the amorphous carbon present in the carbon material surface, acting as a resistive layer from the graphite. As a result of X-ray diffraction (XRD) analysis using heat treated graphite in air at 400, 500, and 600 ℃, the full width at half maximum (FWHM) at (002) peak was reduced compared to that of bare graphite, indicating that the crystallinity of graphite was improved after heat treatment. In addition, the discharge capacity, initial coulombic efficiency (ICE) and cycle stability increased as the crystallinity of graphite increased after heat treatment. In the case of graphite annealed in air at 500 ℃, the high capacity retention rate of 331.1 mAh/g and ICE of 86.2% and capacity retention of 92.7% after 10-cycle measurement were shown.

Effect of Nitrogen Plasma Surface Treatment of Rice Husk-Based Activated Carbon on Electric Double-Layer Capacitor Performance (질소 플라즈마 표면처리가 쌀겨 기반 활성탄소의 전기 이중층 커패시터 성능에 미치는 영향)

  • Lee, Raneun;Kwak, Cheol Hwan;Lee, Hyeryeon;Kim, Seokjin;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.71-77
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    • 2022
  • To increase biomass utilization, rice husk-based activated carbon (RHAC) followed by nitrogen plasma surface treatment was prepared and the electric double-layer capacitor performance was investigated. Through nitrogen plasma surface treatment, up to 2.17% of nitrogen was introduced to the surface of RHAC, and in particular the sample reacted for 5 min with nitrogen plasma showed dominant formation of pyrrolic/pyridine N functional groups. In addition, mesopores were formed on the RHAC material by the removal of silica, and the surface roughness of the carbon material increased by nitrogen plasma surface treatment, resulting in the formation of many micropores. As a result of cyclic voltammetry measurement, at a scan rate of 5 mV/s, the specific capacitance of the RHAC treated with nitrogen plasma increased up to 200 F/g, showing an 80.2% improvement compared to that of using untreated RHAC (111 F/g). This is attributed to the synergetic effect of the introduction of pyrrolic/pyridine-based nitrogen functional groups and the increase of the micropore volume on the surface of the carbon material. This study has a positive effect on the environment in terms of recycling waste resources and using plasma surface treatment.

Cyber Threats Analysis of AI Voice Recognition-based Services with Automatic Speaker Verification (화자식별 기반의 AI 음성인식 서비스에 대한 사이버 위협 분석)

  • Hong, Chunho;Cho, Youngho
    • Journal of Internet Computing and Services
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    • v.22 no.6
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    • pp.33-40
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    • 2021
  • Automatic Speech Recognition(ASR) is a technology that analyzes human speech sound into speech signals and then automatically converts them into character strings that can be understandable by human. Speech recognition technology has evolved from the basic level of recognizing a single word to the advanced level of recognizing sentences consisting of multiple words. In real-time voice conversation, the high recognition rate improves the convenience of natural information delivery and expands the scope of voice-based applications. On the other hand, with the active application of speech recognition technology, concerns about related cyber attacks and threats are also increasing. According to the existing studies, researches on the technology development itself, such as the design of the Automatic Speaker Verification(ASV) technique and improvement of accuracy, are being actively conducted. However, there are not many analysis studies of attacks and threats in depth and variety. In this study, we propose a cyber attack model that bypasses voice authentication by simply manipulating voice frequency and voice speed for AI voice recognition service equipped with automated identification technology and analyze cyber threats by conducting extensive experiments on the automated identification system of commercial smartphones. Through this, we intend to inform the seriousness of the related cyber threats and raise interests in research on effective countermeasures.

A Study on the Improvement of the Electrochemical Performance of Graphite Anode by Controlling Properties of the Coating Pitch (코팅 피치의 물성제어를 통한 흑연 음극재의 전기화학 성능 향상 연구)

  • Kim, Bo Ra;Kim, Ji Hong;Kang, Seok Chang;Im, Ji Sun
    • Applied Chemistry for Engineering
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    • v.33 no.5
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    • pp.459-465
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    • 2022
  • A pitch coating method was proposed for the purpose of improving the electrochemical properties of natural graphite. The synthesis conditions of pitch coating were optimized via measuring electrochemical properties of pitch-coated graphite anodes. As the synthesis temperature increased, the thermal stability was improved in addition to an increase in the softening point and residual carbon weight. However, the synthesis temperature of 430 ℃ resulted in the synthesis of a large amount of NI (NMP Insoluble) due to excessive condensation reaction. As the surface uniformity and coating thickness increased due to high thermal stability, the initial coulombic efficiency and rate capability of the pitch-coated graphite were improved. However, the graphite coated with the pitch containing excessive NI showed lower electrochemical properties than the uncoated graphite. NI had low dispersibility and formed spheres after heat treatment, so it formed the heterogeneous and thicker SEI layer. The optimum conditions for forming a uniform surface and an appropriate coating layer were investigated.

A Study on Improving Facial Recognition Performance to Introduce a New Dog Registration Method (새로운 반려견 등록방식 도입을 위한 안면 인식 성능 개선 연구)

  • Lee, Dongsu;Park, Gooman
    • Journal of Broadcast Engineering
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    • v.27 no.5
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    • pp.794-807
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    • 2022
  • Although registration of dogs is mandatory according to the revision of the Animal Protection Act, the registration rate is low due to the inconvenience of the current registration method. In this paper, a performance improvement study was conducted on the dog face recognition technology, which is being reviewed as a new registration method. Through deep learning learning, an embedding vector for facial recognition of a dog was created and a method for identifying each dog individual was experimented. We built a dog image dataset for deep learning learning and experimented with InceptionNet and ResNet-50 as backbone networks. It was learned by the triplet loss method, and the experiments were divided into face verification and face recognition. In the ResNet-50-based model, it was possible to obtain the best facial verification performance of 93.46%, and in the face recognition test, the highest performance of 91.44% was obtained in rank-5, respectively. The experimental methods and results presented in this paper can be used in various fields, such as checking whether a dog is registered or not, and checking an object at a dog access facility.

Effects of Acupuncture with a Combination of GV20 and EX-HN1 Acupoints on CO2 Reactivity in the Anterior and Middle Cerebral Arteries during Hypercapnia in Normal Subjects: A Randomized Crossover Trial

  • Park, Hojung;Moon, Sang-Kwan;Lee, Han-Gyul;Kwon, Seungwon;Cho, Seung-Yeon;Park, Seong-Uk;Jung, Woo-sang;Park, Jung-Mi;Ko, Chang-Nam;Cho, Ki-Ho
    • The Journal of Internal Korean Medicine
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    • v.43 no.4
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    • pp.582-595
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    • 2022
  • Objectives: To investigate the effects of acupuncture at GV20 and EX-HN1 on cerebral blood flow (CBF) velocity and cerebrovascular reactivity (CVR) in the middle cerebral arteries (MCA) and anterior cerebral arteries (ACA) and to compare the effects to acupuncture at GV20. Methods: The study was a randomized, crossover trial that included 10 healthy men aged 20 to 29 years who underwent acupuncture treatment four times with a washout period of one week. The CBF velocity and CVR were measured by transcranial Doppler sonography (TCD) on both MCAs at the first and second visits, and both ACAs at the third and fourth visits. Participants were randomly assigned to one of two groups (A and B) before the first and third visits. Group A received two phases of acupuncture intervention at a single GV20 point and a combination of GV20 and EX-HN1 acupoints. Group B received the same interventions, but in the reverse order. Results: The increase in CO2 reactivity was significantly higher for the combination acupoints of GV20 and EX-HN1 than for the GV20 single acupoint in both MCAs (Right: 136 to 178, p=0.017; Left: 127 to 191, p=0.017) and ACAs (Right: 133 to 158, p=0.013; Left: 122 to 168, p=0.025). No significant change was noted in the corrected velocity at PETCO2 40 mmHg, blood pressure, or heart rate. Conclusions: The findings suggest that improvement of the CBF in the MCA and ACA after GV20 acupuncture increases when acupuncture is also performed at EX-HN1. These results clinically support the combined use of EX-HN1 and GV20 to treat disorders of MCA and ACA circulation.

A Study on the Seismic Response Formula for Improvement of Seismic Design Code of Water Treatment Underground Structures (수처리 지중구조물의 내진설계 기준 개선을 위한 지진 응답 제안식의 관한 연구)

  • Lee, Joung-Bae;Bae, Sang-Soo;Chung, Kwang-Mo;Bang, Myung-Seok
    • Journal of the Korean Geosynthetics Society
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    • v.21 no.3
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    • pp.41-48
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    • 2022
  • Generally it was known that member forces in the earthquake resistant design is lower than those in the general design. But it is not true in cases of water treatment underground structures, which is different in each case like water treatment plant, sedimentation basin, and utility-pipe conduit. Also, looking at the scale of earthquakes that have recently occurred in Korea, large-scale earthquakes are frequent, so when the magnitude of the design seismic force increases, it is necessary to investigate the seismic behavior of the water treatment underground structure and to deal with it. In this study the change rate of member forces was investigated by the change of design load factor (earthquake acceleration design criteria), earth depth, underground water level. The pseudo-static analysis and response displacement method was applied, and various analyzes were conducted depending on the ground water and soil depth. The proposed formula in this study will be efficient when the earthquake design code of water treatment underground structures is revised.

Effects of Yigong-san for the Treatment of Anorexia in Children: A Systematic Review and Meta-Analysis (소아 식욕부진에 대한 이공산(異功散) 치료의 효과 : 체계적 문헌고찰 및 메타분석)

  • Lee, Bo-ram;Ha, Da-jung;Huh, Tae-young;Park, Sang-eun;Lee, Sun-haeng;Chang, Gyu-tae
    • The Journal of Internal Korean Medicine
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    • v.43 no.4
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    • pp.542-558
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    • 2022
  • Objectives: The purpose of this study was to assess the effect of Yigong-san on anorexia in children by conducting a systematic review and meta-analysis of randomized controlled trials (RCTs). Methods: Eleven electronic databases were searched on May 30, 2022 to collect relevant studies. All studies published up to the search date were considered. RCTs reporting the effect of Yigong-san on the treatment of anorexia in children were included. The primary outcome was an improvement in clinical anorexia symptoms after treatment. In this meta-analysis, continuous and binary outcomes were assessed, and the data were presented as the mean difference and risk ratio with their 95% confidence intervals. The risk of bias was assessed using the Cochrane Collaboration's risk of bias tool. Results: A total of nine studies were included in this systematic review. The treatment group (Yigong-san only or Yigong-san plus conventional treatment) showed a statistically significant effect compared to the control group (conventional treatment only) in total effective rate (Yigong-san only: RR 1.26, 95% CI 1.17, 1.36, I2=0%; Yigong-san plus conventional treatment: RR 1.32, 95% CI 1.18, 1.47, I2=0%), clinical symptoms, some of the anthropometric outcomes, and biological markers related to appetite and growth in children with anorexia. No serious adverse events related to Yigong-san were reported. Conclusions: Yigong-san showed statistically significant effects as a treatment for anorexia in children. However, the number of studies included in the meta-analysis was insufficient, and the herbs contained in the Yigong-san used in the included studies were not standardized. Future research should focus on the implementation of methodologically robust clinical research.

Quantitative precipitation estimation of X-band radar using empirical relationship (경험적 관계식을 이용한 X밴드 레이더의 정량적 강우 추정)

  • Song, Jae In;Lim, Sanghun;Cho, Yo Han;Jeong, Hyeon Gyo
    • Journal of Korea Water Resources Association
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    • v.55 no.9
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    • pp.679-686
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    • 2022
  • As the occurrences of flash floods have increased due to climate change, faster and more accurate precipitation observation using X-band radar has become important. Therefore, the Ministry of Environment installed two dual-pol X-band radars at Samcheok and Uljin. The radar data used in this study were obtained from two different elevation angles and composed to reduce the shielding effect. To obtain quantitative rainfall, quality control (QC), KDP retrieval, and Hybrid Surface Rainfall (HSR) methods were sequentially applied. To improve the accuracy of the quantitative precipitation estimation (QPE) of the X-band radar, we retrieved parameters for the relationship between rainfall rate and specific differential phase, which is commonly called the R-KDP relationship; hence, an empirical approach was developed using multiple rain gauges for those two radars. The newly suggested relationship, R = 27.4K0.81DP, slightly increased the correlation coefficient by 1% more than the relationship suggested by the previous study. The root mean square error significantly decreased from 3.88 mm/hr to 3.68 mm/hr, and the bias of the estimated precipitation also decreased from -1.72 mm/hr to -0.92 mm/hr for overall cases, showing the improvement of the new method.

Improvement of Water Quality by Corona Discharge Plasma-activated Water in a Tilapia Recirculating Aquaculture System (코로나 방전-플라즈마 처리수의 틸라피아 순환여과양식시스템 수질 개선 효과)

  • You, Jin Ho;Mun, Seong Hee;Oh, Hyeon Ji;Park, Tae Sup;Kwon, Joon Yeong
    • Journal of Marine Life Science
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    • v.5 no.2
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    • pp.51-57
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    • 2020
  • Disinfection and maintenance of rearing water in aquaculture is an essential element for the prevention of fish diseases. This is especially important in recirculating aquaculture systems (RAS) in which fish are reared at high density using recycled water. In this study, tilapia was reared in two different RAS (one with plasma generator - PW system, another without plasma generator - No PW system). In plasma treated group, UVT% of water was improved clearly, and the number of heterotrophic bacteria decreased significantly after 40 days. Total weight gain of tilapia in PW system was significantly higher, and other growth indicators were also relatively higher although not statistically significant. In addition, the fish in PW system had a 100% survival rate, and there were no histological differences between fish from both systems. Fish did not seem to be affected by the toxicity of ROS. In conclusion, it is expected that plasma water can effectively deactivate fish pathogens and improve the quality of rearing water.