• Title/Summary/Keyword: Improved Shape

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Synthesis and Characterization of the Co-electrolessly Deposited Metallic Interconnect for Solid Oxide Fuel Cell (무전해 코발트 코팅된 금속계 SOFC분리판의 제조 및 특성 평가)

  • Han, Won-Kyu;Ju, Jeong-Woon;Hwang, Gil-Ho;Seo, Hyun-Seok;Shin, Jung-Chul;Jun, Jae-Ho;Kang, Sung-Goon
    • Korean Journal of Materials Research
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    • v.20 no.7
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    • pp.356-363
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    • 2010
  • For this paper, we investigated the area specific resistance (ASR) of commercially available ferritic stainless steels with different chemical compositions for use as solid oxide fuel cells (SOFC) interconnect. After 430h of oxidation, the STS446M alloy demonstrated excellent oxidation resistance and low ASR, of approximately 40 $m{\Omega}cm^2$, of the thermally grown oxide scale, compared to those of other stainless steels. The reason for the low ASR is that the contact resistance between the Pt paste and the oxide scale is reduced due to the plate-like shape of the $Cr_2O_3$(s). However, the acceptable ASR level is considered to be below 100 $m{\Omega}cm^2$ after 40,000 h of use. To further improve the electrical conductivity of the thermally grown oxide on stainless steels, the Co layer was deposited on the stainless steel by means of an electroless deposition method; it was then thermally oxidized to obtain the $Co_3O_4$ layer, which is a highly conductive layer. With the increase of the Co coating thickness, the ASR value decreased. For Co deposited STS444 with 2 ${\mu}m$hickness, the measured ASR at $800^{\circ}$ after 300 h oxidation is around 10 $m{\Omega}cm^2$, which is lower than that of the STS446M, which alloy has a lower ASR value than that of the non-coated STS. The reason for this improved high temperature conductivity seems to be that the Mn is efficiently diffused into the coating layer, which diffusion formed the highly conductive (Mn,Co)$_3O_4$ spinel phases and the thickness of the $Cr_2O_3$(S), which is the rate controlling layer of the electrical conductivity in the SOFC environment and is very thin

Recovery and Disaster Prevention Capability of Coastal Japanese Black Pine (Pinus thunbergii) Forests on the Fukiage Sand Dunes of Southern Kyushu, Japan

  • Teramoto, Yukiyoshi;Shimokawa, Etsuro;Ezaki, Tsugio;Chun, Kun-Woo;Kim, Suk-Woo;Lee, Youn-Tae
    • Journal of Forest and Environmental Science
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    • v.30 no.4
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    • pp.383-392
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    • 2014
  • In this study, we investigated the Fukiage sand dunes of southern Kyushu, Japan. We surveyed the status of recovery of coastal Japanese black pine forests damaged by pine wilt disease and their disaster prevention capability. We placed two transects: Transect 1, in an area that was severely damaged (80-90% damage rate) by pine wilt disease, and Transect 2, in an area that was mostly undamaged (<10% damage rate). Then, we installed survey lines, carried out vegetation surveys, and measured the depth and pH of humus soil. The survey lines were placed perpendicular to the coastline from the top of the fore-dune to the inland area, and divided into five 50 m sections. Before the point 100 m inland from the top of the fore-dune, the number of invasive hardwoods and of Japanese black pines were small because of the poor growth environment in both transects. Past the 100 m point, the species and number of Japanese black pines and broad-leaved trees increased further inland because the growth environment improved. In addition, the recovery metrics of tree height, diameter at breast height, age, and number in Transect 1 were much lower than those in Transect 2, and the basal area of broad-leaved trees and the depth of humus soil in Transect 1 were lower than in Transect 2, and the soil pH of humus soil in Transect 1 was higher than that of Transect 2. The shape ratio of the Japanese black pine forests indicated that they were insufficient for disaster prevention. Therefore, in order to fully promote the disaster prevention capability of coastal Japanese black pine forests, we should not only focus on prevention of pine wilt disease but also undertake continuous control efforts taking into consideration the sound growth environment such as appropriate density and soil management and removal of invasive broad-leaved trees.

Fabrication of $TiO_2$ Electrode Containing Scattering Particles in Dye-Sensitized Solar Cells (산란 입자를 포함하는 염료감응 태양전지용 $TiO_2$ 전극 제조)

  • Lee, Jin-Hyoung;Lee, Tae-Kun;Kim, Cheol-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.2
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    • pp.57-62
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    • 2011
  • The energy conversion efficiency of DSSCs (Dye-Sensitized Solar Cells) is dependent on the powder size, the structure, and the morphology of $TiO_2$ electrode. The higher efficiency is obtained with high surface area of the nanoanatase-$TiO_2$ powder adsorbed onto a lot more of the dye. Also, the enhancement of light scattering increases the efficiency with high adsorption of the dye. Powder size, crystalline phase, and shape of $TiO_2$ obtained by hydrothermal method have 15-20 nm, anatase and round. $TiO_2$ electrode has fabricated with the mixture of scattering $TiO_2$ particle with 0.4 ${\mu}m$ in nano-sized powder. Conversion efficiency of series of DSSCs was measured with volume fraction of scattering particle. Photovoltaic characteristics of DSSCs with 10% scattering particles are 3.51 mA for Jsc (short circuit current), 0.79 V for Voc(open circuit potential), filling factor 0.619 and 6.86% for efficiency. Jsc was improved by 11% and enhancement of efficiency by 0.77% compared with that of no scattering particles. The confinement of inserted light by light scattering particles has more increase of the injection of exiton(electron-hole pair) and decrease of moving path in electron. Efficiencies of DSSCs with more than 10% for scattering particles have reduced with increasing the pore in the $TiO_2$ electrode.

Development of DHLT Joint for Vertical Cutoff Walls in Offshore Waste Landfill Site (해상처분장 연직차수공을 위한 DHLT 이음부의 개발)

  • Hong, Young-Ho;Lee, Jong-Sub;Lee, Dongsoo;Chae, Kwang-Seok;Yu, Jung-Doung
    • Journal of the Korean Geotechnical Society
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    • v.34 no.3
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    • pp.43-56
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    • 2018
  • Vertical cutoff walls such as steel pipe sheet piles (SPSPs) have been commonly applied for the construction of the offshore waste landfill site. Because the SPSPs are sequentially installed by connecting their joints to those of adjacent piles, their mechanical stability should be ensured against the inherent external forces on the sea. The objective of this study is to evaluate the structural performances of the newly developed types of SPSP joint compared with those of other joint types. The problems of the traditional SPSP joints are investigated, and an advanced joint shape of SPSP, which is named double H with L-T (DHLT) joint, are designed for improving the constructability and maintenance. Full-scale models of the DHLT joint are manufactured, and then its joint areas are filled with grout material. After 28 days of curing time, compressive and tensile strength tests were performed on the joint models and the test results were compared with those of the traditional joints. Experimental results show that the structural capacities of the DHLT joint models are lower than those of traditional joints due to the influence of grout and steel members. In the cases of the compressive strength test, especially, bending occurs on steel H-beam with no distinct cracks in grout due to the asymmetrical structure of joint which has no reaction force. This study shows that the performance of the SPSP joint can be improved by considering the influence factors on the structural capacities estimated by the experimental tests.

White light scanner-based repeatability of 3-dimensional digitizing of silicon rubber abutment teeth impressions

  • Jeon, Jin-Hun;Lee, Kyung-Tak;Kim, Hae-Young;Kim, Ji-Hwan;Kim, Woong-Chul
    • The Journal of Advanced Prosthodontics
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    • v.5 no.4
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    • pp.452-456
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    • 2013
  • PURPOSE. The aim of this study was to evaluate the repeatability of the digitizing of silicon rubber impressions of abutment teeth by using a white light scanner and compare differences in repeatability between different abutment teeth types. MATERIALS AND METHODS. Silicon rubber impressions of a canine, premolar, and molar tooth were each digitized 8 times using a white light scanner, and 3D surface models were created using the point clouds. The size of any discrepancy between each model and the corresponding reference tooth were measured, and the distribution of these values was analyzed by an inspection software (PowerInspect 2012, Delcamplc., Birmingham, UK). Absolute values of discrepancies were analyzed by the Kruskal-Wallis test and multiple comparisons (${\alpha}$=.05). RESULTS. The discrepancy between the impressions for the canine, premolar, and molar teeth were $6.3{\mu}m$ (95% confidence interval [CI], 5.4-7.2), $6.4{\mu}m$ (95% CI, 5.3-7.6), and $8.9{\mu}m$ (95% CI, 8.2-9.5), respectively. The discrepancy of the molar tooth impression was significantly higher than that of other tooth types. The largest variation (as mean [SD]) in discrepancies was seen in the premolar tooth impression scans: $26.7{\mu}m$ (95% CI, 19.7-33.8); followed by canine and molar teeth impressions, $16.3{\mu}m$ (95% CI, 15.3- 17.3), and $14.0{\mu}m$ (95% CI, 12.3-15.7), respectively. CONCLUSION. The repeatability of the digitizing abutment teeth's silicon rubber impressions by using a white light scanner was improved compared to that with a laser scanner, showing only a low mean discrepancy between $6.3{\mu}m$ and $8.9{\mu}m$, which was in an clinically acceptable range. Premolar impression with a long and narrow shape showed a significantly larger discrepancy than canine and molar impressions. Further work is needed to increase the digitizing performance of the white light scanner for deep and slender impressions.

Effect of Infographic Instruction to Promote Elementary Students' Use of Scientific Model (초등학생들의 과학적 모델 사용 활성화를 위한 인포그래픽 수업의 효과)

  • Jung, Jinkyu;Kim, Youngmin
    • Journal of The Korean Association For Science Education
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    • v.36 no.2
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    • pp.279-293
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    • 2016
  • The purpose of this study was to analyze the effect of infographic instruction to promote the use of the scientific model in the 'lens' unit of elementary science textbooks. The participants were $6^{th}$ grade students(n=53) of G elementary school in G city, Gyeongsangnam-do. For this study, the lesson plan of the 'lens' unit consisted of three steps as investigation of students' prior concept about the lens, scientific model construction activity, and infographic construction activity. We then analyzed the results of this study from three perspectives: the scientific concept, scientific model, and infographic. Before the lesson, students focused on the external shape and material of the lens in prior concept of it. However, after the scientific model construction activity and infographic construction activity, students' scientific concept about the lens improved in the categories of features of lens, features of glasses, light path, and applications of the lens. In terms of the scientific model, use of type and frequency of scientific model increased more in the infographic construction activity than the scientific construction model activity. Also, in terms of infographic, the two infographic types as function based infographic and connection based infographic used more than non-infographic in the infographic construction activity. Also, the frequency of Gestal theory's visual perception increased more in the infographic construction activity than the scientific model construction activity.

Preparation of the Hollow Fiber Type Perovskite Catalyst for Methane Complete Oxidation (메탄의 완전산화 반응을 위한 중공사형 페롭스카이트 촉매 제조)

  • Lee, Seong Woon;Kim, Eun Ju;Lee, Hong Joo;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.297-302
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    • 2018
  • Bead type and hollow fiber type catalyst (HFC, Hollow Fiber type Catalyst) was prepared by $La_{0.1}Sr_{0.9}Co_{0.2}Fe_{0.8}O_{3-{\delta}}$ (LSCF1928) perovskite powder catalyst which showed excellent methane complete oxidation characteristics through previous studies. The HFC have a cylindrical shape with an empty interior, and pores can be formed through Phase inversion method so the specific surface area can be remarkably improved. In the case of the bead type catalyst prepared by adding Methyl Cellulose (MC), $SrCO_3$ was produced in addition to the original catalyst composition of LSCF1928 due to the reaction of $CO_2$ emitted from MC and Sr of the catalyst. In the case of the HFC, a single phase perovskite structure was obtained without impurities. The HFC calcined at $700{\sim}900^{\circ}C$ showed pore structure of finger-sponge-finger structure, and 99.9% oxygen conversion rate was achieved through complete oxidation of methane at $475^{\circ}C$. Air gap and spinning pressure condition were changed to control the HFC pore. 2 cm air gap and 7 bar spinning pressure showed the best catalytic performance and achieved oxygen conversion rates of more than 70.65%, 93.01%, and 99.99% at $425^{\circ}C$, $450^{\circ}C$ and $475^{\circ}C$, respectively.

Effects of Pre-synthesized $BaTiO_3$ Addition on the Microstructure and Dielectric/ Piezoelectric Properties of $(Bi_{0.5}Na_{0.5})_{0.94}Ba_{0.06}TiO_3$ Piezoelectric Ceramics

  • Khansur, Neamul Hayet;Yoon, Man-Soon;Kweon, Soon-Yong;Lee, Young-Geun;Ur, Soon-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.189-189
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    • 2008
  • Due to the environmental issue vast research is going on to replace the widely used lead contented piezoelectric materials. Bismuth sodium titanate (abbreviated as BNT) based bismuth sodium titanate-barium titanate (abbreviated as BNBT) ceramic was prepared by using modified method rather than conventional mixed oxide method. This modification was made to improve the properties of BNT based ceramic. In this procedure $BaTiO_3$ (abbreviated as BT) was prepared using conventional mixed oxide method. Analytical grade raw materials of $BaCO_3$ and $TiO_2$ were weighted and ball milled using ethanol medium. The mixed slurry was dried and sieved under 80 mesh. Then the powder was calcined at $1100^{\circ}C$ for 2 hours. This calcined BT powder was used in the preparation of BNBT. Stoichiometric amount of $Bi_2O_3$, $Na_2CO_3$, $TiO_2$ and BT were weighted and mixed by using ball mill. The used calcination temperature was $850^{\circ}C$ for 2 hours. Calcined powder was taken for another milling step. BNBT disks were pressed to 15 mm of diameter and then cold isostatical press (CIP) was used. Pressed samples were sintered at $1150^{\circ}C$ for 2 hours. The SEM microstructure analysis revealed that the grain shape of the sintered ceramic was polyhedral and grain boundary was well matched where as the sample prepared by conventional method showed irregular arrangement and grain boundary not well matched. And sintered density was better (5.78 g/cc) for the modified method. It was strongly observed that the properties of BNBT ceramic near MPB composition was found to be improved by the modified method compare to the conventional mixed oxide method. The piezoelectric constant dB of 177.33 pC/N, electromechanical coupling factor $k_p$ of 33.4%, dielectric constant $K_{33}^T$ of 688.237 and mechanical quality factor $Q_m$ of 109.37 was found.

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Mechanism of Strength Development in Ultra High Strength Concrete Using the Electric Arc Furnace Oxidizing Slag as Fine Aggregate (초고강도 콘크리트에서 전기로 산화 슬래그 잔골재 사용에 의한 강도 증진 기구)

  • Lee, Seung-Heun;Lim, Doo-Sub;Lee, Seung-Hoon;Lee, Joo-Ha
    • Journal of the Korea Concrete Institute
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    • v.25 no.1
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    • pp.3-9
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    • 2013
  • In ultra high strength concrete, when electric arc furnace oxidizing slag is substituted for sea sand as fine aggregate, compressive strength was improved about 15 MPa. To figure out the cause of the improvement in compressive strength, this study considered the dissolution characteristics of Ca component in fine aggregate and examined the microstructure, porosity, microhardness, and Ca/Si mole ratio on the interface of fine aggregate and paste. And to examine the mechanism of strength improvement resulted from the shape of fine aggregate, this study measured the surface roughness of fine aggregate with AFM. According to the result of this experiment, the mechanisms of strength improvement in ultra high strength concrete resulted from the use of electric arc furnace oxidizing slag as fine aggregate can be divided into chemical and physical mechanisms. In the chemical mechanism, the soluble Ca component contained in electric arc furnace oxidizing slag is dissolved and forms a hydrate between fine aggregate and paste to improve the interlocking strength of fine aggregate-paste. Also, it makes the microstructure around the fine aggregate. And in the physical mechanism, electric arc furnace oxidizing slag has a twice greater surface roughness than sea sand, so the interlocking strength between fine aggregate and paste increases, which contributes to the development of compressive strength.

Eliminating Color Mixing of Projector-Camera System for Fast Radiometric Compensation (컬러 보정의 고속화를 위한 프로젝터-카메라 시스템의 컬러 혼합 성분 제거)

  • Lee, Moon-Hyun;Park, Han-Hoon;Park, Jong-Il
    • Journal of Broadcast Engineering
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    • v.13 no.6
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    • pp.941-950
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    • 2008
  • The quality of projector output image is influenced by the surrounding conditions such as the shape and color of screen, and environmental light. Therefore, techniques that ensure desirable image quality, regardless of such surrounding conditions, have been in demand and are being steadily developed. Among the techniques, radiometric compensation is a representative one. In general, radiometric compensation is achieved by measuring the color of the screen and environmental light based on an analysis of camera image of projector output image and then adjusting the color of projector input image in a pixel-wise manner. This process is not time-consuming for small sizes of images but the speed of the process drops linearly with respect to image size. In large sizes of images, therefore, reducing the time required for performing the process becomes a critical problem. Therefore, this paper proposes a fast radiometric compensation method. The method uses color filters for eliminating the color mixing between projector and camera because the speed of radiometric compensation depends mainly on measuring color mixing between projector and camera. By using color filters, there is no need to measure the color mixing. Through experiments, the proposed method improved the compensation speed by 44 percent while maintaining the projector output image quality. This method is expected to be a key technique for widespread use of projectors for large-scale and high-quality display.