• 전기화학회지
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• 제8권2호
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• pp.106-114
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• 2005

This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

• 한국소음진동공학회논문집
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• 제18권6호
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• pp.598-605
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• 2008

An improved beamforming method is proposed to measure the surface impedance of absorbing materials in a free field. It is possible to estimate the surface impedance by decomposing measured signals into incident and reflected signals by using the spatial filter matrix of the beamforming method. Wavelet do-noising techniques which reduce the white Gaussian noise are applied to improve the results. Phase calibration method is also used to improve the results of the measured surface impedance in a low frequency range. The results of the normal incidence experiments that are performed in a semi-anechoic chamber are verified by comparing with those of the standard test method that is presented in ASTM E1050. The proposed method is found to be reliable to measure the surface impedance for frequencies higher than 400 Hz.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2002년도 봄 학술발표회 논문집
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• pp.395-400
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• 2002

Epoxy coating and sealing used in nuclear plants for the protection of radiation degrades with aging and hazardous atmosphere. In order to evaluate the degradation of the epoxy, dependence of the acoustic impedance on the change of mechanical properties has been used. Unlike metals, the surface of the epoxy coating on a concrete liner is so wavy that the acoustic impedance is difficult to measure by using the reflectivity of the ultrasound on the interface surface because of the irregular reflection and propagation from the epoxy surface. SA(simulated annealing) algorithm is applied to calculate the acoustic impedance using a reflection wave from the rough epoxy surface. The surface waviness and acoustic impedance are taken into account and determined by SA method to evaluate the state of degradation quantitatively.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 C
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• pp.1744-1746
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• 1996

Surface impedance boundary condition(SIBC) concepts are introduced into the finite-difference time-domain(FDTD) method. Lossy conductors are replaced by surface impedance boundary computations reducing the soluton space and producing significant computational savings. Specifically, a surface impedance boundary condition is developed to reduce a lossy dielectric half-space. Since Maxwell's eqations are solved directly, the reflected and transmitted pulse amplitude demonstrate how the reflection and transmision coefficient determine reflected wave amplitude. In this paper, two implementations of reflection coefficient are presented. One implementation is a standard FDTD technique and the other is a FDTD using surface impedence boundary condition(FDTD-SIBC) that are applicabIe over a very large frequency bandwidth. Particulary, an efficient way to transform the time domain results to frequency domain is presented. Thus, frequency domain results are presented in one dimension and are compared with exact results.

• 소음진동
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• 제6권2호
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• pp.225-231
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• 1996

A free field method using two microphones is used for measuring surface impedance and absorption coefficient of the absorbent materials. It is shown that this method can be performed in a large non-anechoic room. Precise values of the surface impedance can be obtained by changing the spaces between the two microphones. Comparison between experimental values of the surface impedance of the glass wool and the mineral wool and Miki's empirical model shows agreement.

• 전기화학회지
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• 제11권3호
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• pp.147-153
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• 2008

Improvement of the selectivity of nonenzymatic glucose based on mesoporous platinum ($H_1$-ePt) by using A.C. impedance is reported. The idea of the present work is based on the novel effect of the mesoporous electrode that the apparent exchange current due to glucose oxidation remarkably grows although the reaction kinetics on the surface is still sluggish. It is expected that the enlarged apparent exchange current on the mesoporous electrode can raise the sensitivity of admittance in A.C. impedance to glucose concentration. At a low frequency, A.C. impedance could become more powerful. The admittance at 0.01 Hz is even more sensitive to glucose than to ascorbic acid while amperometry exhibits the inverse order of sensitivity. This is the unique behavior that is neither observed by A.C. impedance on flat platinum electrode nor obtained by amperometry. The study shows how the combination of A.C. impedance and nano-structured surface can be applied to the detection of sluggish reaction such as electrochemical oxidation of glucose.

• The Journal of the Acoustical Society of Korea
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• 제18권1E호
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• pp.20-26
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• 1999

Although the radiation impedance of a transducer with a regular square surface has been studied by many researchers, the formulas are still very complicated, which results in long computation time and low accuracy. In this paper, we propose a new algorithm for the calculation of acoustic radiation impedance in which the regular square vibrating surface of a transducer is divided into small elements and duplicate calculations are eliminated in the process of calculating mutual effects of the elements. Using this algorithm, shorter computation time and higher accuracy of results can be obtained. As a demonstration, the self and the mutual radiation impedance of transducers with a regular square surface are calculated and the accuracy of the results is evaluated.

• 공업화학
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• 제34권1호
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• pp.9-14
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• 2023

본 논문에서는 용액의 이온 농도 측정이 가능한 나피온 폴리머(Nafion polymer) 코팅 기반 2상 금 전극의 임피던스(Impedance) 센서를 개발하였다. 스퍼터링(Sputtering) 공정을 통해서 제작된 금 전극의 표면을 나피온 폴리머를 사용하여 표면 개질 하였다. 상기 제작된 전극은 분극 현상 제어가 가능하여 전기화학적 신호를 안정적으로 측정할 수 있도록 하였다. 분광학과 전자주사현미경 관찰을 통하여 박막의 나피온 폴리머 코팅을 확인하였다. 나피온 코팅이 된 전극은 기존 금 전극에 비해 안정적인 임피던스 신호를 보여 주었으며, 표준 염화나트륨(NaCl) 용액 사용 시 임피던스 센서의 신뢰성 높은 검정 곡선(R² = 0.983)을 나타내었다. 또한, 임피던스 센서는 상용화 전도도 장치와 인공 눈물의 이온 농도 측정 비교 실험을 진행하였으며, 유사한 결과값을 확인하였다.

• 한국음향학회지
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• 제36권2호
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• pp.108-114
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• 2017

수중 초음파 탐지 시스템에서 배열 진동소자로 사용되는 정방형의 방사면을 갖는 초음파 트랜스듀서의 자기 방사임피던스를 실험적으로 해석하였다. 7개의 진동수가 서로 다른 란주반형 진동자를 제작하여 파수와 진동자의 한변의 길이의 곱인 ka의 값이 1~3의 범위에 대해서 방사리액턴스 및 방사저항을 측정하였다. 이 결과를 수열을 이용한 방사임피던스의 이론계산 결과와 비교하여 본 연구에서 수행한 실험방법의 유효성을 확인 하였고 정방형의 방사면에 대한 방사임피던스의 변화경향을 실험적으로 확인할 수 있었다.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2008년도 추계학술대회B
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• pp.2670-2675
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• 2008

We introduce a new type of surface microscope using hydrodynamic phenomena. The fluid flow through the opening of the pipette probe is blocked at short distances between the probe and the surface, thus increasing the pressure loss. Therefore, a scanning flow impedance microscope (SFIM) can image the surface topology by scanning the probe with measuring the pressure loss. The SFIM can display the topology regardless of surface hardness, surface electrical conductivity, and surrounding fluid. The present letter contains the first experimental results on surface topography obtained with this novel microscope. The preliminary results in air demonstrate the lateral resolution of the SFIM is very close to the inner diameter of the probe.