• Title/Summary/Keyword: Immiscible

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이액상계 생물반응기를 이용한 PAH의 분해

  • Lee Jae-Yeong;Kim Yong-Gi;Yang Ji-Won
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2005.04a
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    • pp.159-162
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    • 2005
  • In this study, a two-liquid-phase (TLP) bioreactor was conducted to enhance the biodegradation efficiency and rate of PAH. Phenanthrene was degraded efficiently irrespective of the type and the amount of water-immiscible liquid (WIL). The degradation efficiency of anthracene was much higher in paraffine oil than in silicone oil because the mass transfer of anthracene was different in the two WILs. Pyrene was only transferred from soil to WIL during 5 days. It seemed that the degradation of PAH in the TLP bioreactor was mainly dependent on the mass transfer of PAH.

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Reactive Dyeing in Immiscible Two-phase System of Water/Organic Solvent(Ⅱ) - The Dyeing of Silk with C. I. Reactive Blue 203 - (물/유기용매 불혼합 이성분계에서의 반응염색(Ⅱ) - C. I. Reactive Blue 203을 이용한 견섬유의 염색 -)

  • Kim, Tae Gyeong;Kim, Mi Gyeong;Im, Yong Jin;Jo, Gwang Ho
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.42-42
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    • 2001
  • Following the prior studs regarding that 1.0g of cotton fabric cound be dyed uniformly with a reactive dye in the solvent mixture of 2㎖ of water and 23㎖ of dichloromethane, silk fabric was dyed with C. I. Reactive Blue 203 in the water/dichloromethane two-phase immiscible solvent media. In order to minimize dye loss due to its hydrolysis, the reactive dyeing was carried out in dichloromethane containing a small amount of water. With only 3㎖ of water in 22㎖ of dichloromethane, 1.0g of silk fabric could be dyed perfectly. The uptake ratio was increased greatly, compared with that of normal reactive dyeing in a water medium. It would seem that the one of hydrophobic solvents, dichloromethane, can assist the even dyeing as it disperses a small amount of dye-dissolved water phase and conveys this water phase to the fabric entirely and uniformly.

Reactive Dyeing in Immiscible Two-phase System of Water/Organic Solvent (II) - The Dyeing of Silk with C. I. Reactive Blue 203 - (물/유기용매 불혼합 이성분계에서의 반응염색(II) - C. I. Reactive Blue 203을 이용한 견섬유의 염색 -)

  • 김태경;김미경;임용진;조광호
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.128-134
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    • 2001
  • Following the prior studs regarding that 1.0g of cotton fabric round be dyed uniformly with a reactive dye in the solvent mixture of $2m\ell$ of water and $23m\ell$ of dichloromethane, silk fabric was dyed with C. I. Reactive Blue 203 in the water/dichloromethane two-phase immiscible solvent media. In order to minimize dye loss due to its hydrolysis, the reactive dyeing was carried out in dichloromethane containing a small amount of water. With only $3m\ell$ of water in $22m\ell$ of dichloromethane, 1.0g of silk fabric could be dyed perfectly. The uptake ratio was increased greatly, compared wish that of normal reactive dyeing in a water medium. It would seem that the one of hydrophobic solvents, dichloromethane, can assist the Even dyeing as it disperses a small amount of dye-dissolved phase and conveys this water phase to the fabric entirely and uniformly.

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Removal of Pollutants and Recovery of Toxic Heavy Metals from Wastewater Using Microporous Hollow Fiber Modules

  • Yun, Chang-Han
    • Proceedings of the Membrane Society of Korea Conference
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    • 1993.04a
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    • pp.25-27
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    • 1993
  • Multiphase equilibrium-based processes for separation and purification generally utilize dispersed systems in which one phase is dispersed in the other as bubbles or drops or thin films. Using microporous membranes, novel techniques have been developed such that multiphase processes can now be carried out in a nondispersive fashion for gas-liquid (Sirkar, 1992) and liquid-liquid (Prasad and Sirkar, 1992) contacting processes. Among such processes, only nondispersive solvent extraction of pollutants using microporous membranes will be of concern here. These processes employ immobilized immiscible phase interfaces at the pore mouths in a microporous membrane. Through such interfaces, solutes are extracted into the solvent as two immiscible phases flow on two sides of a microporous membrane. Many advantages of such a technique over conventional dispersion-based extractors have been summarized (Prasad and Sirkar, 1992).

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Mechanical Alloying Effect in Immiscible Cu-Based Alloy Systems.

  • Lee, Chung-Hyo;Lee, Seong-Hee;Kim, Ji-Soon;Kwon, Young-Soon
    • Journal of Powder Materials
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    • v.10 no.3
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    • pp.164-167
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    • 2003
  • The mechanical alloying effect has been studied on the three Cu-based alloy systems with a positive heat of mixing. The extended bcc solid solution has been formed in the Cu-V system and an amorphous phase in the Cu-Ta system. However, it is round that a mixture of nanocrystalline Cu and Mo Is formed in the Cu-Mo system. The neutron diffraction has been employed at a main tool to characterize the detailed amorphization process. The formation of an amorphous phase in Cu-Ta system can be understood by assuming that the smaller Cu atoms preferentially enter into the bcc Ta lattice during ball milling.

The Compatibilizing Effect of Maleic Anhydride in Ethylene-Vinyl Acetate (EVA)/Ethylene-${\alpha}$-Olefin Copolymers Blends

  • Park, Soo-Chul;Choe, Soon-Ja
    • Macromolecular Research
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    • v.13 no.4
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    • pp.297-305
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    • 2005
  • The compatibilizing effect of maleic anhydride (MA) in the immiscible blends of EVA22 (vinyl acetate content 22%)/ethylene-${\alpha}$-olefin copolymers with 1-butene (EtBC) and 1-octene (EtOC)) comonomers was studied. By adding 1, 2, and 3 phr of MA in the presence of dicumylperoxide, the morphology, tensile strength at break, and 100 and 300 % modulus of EVA22/EtBC and EVA22/EtOC blends were significantly enhanced. The melting point and crystallization point depression were observed upon the addition of MA. The changes in the ${\beta}$ transition and glass transition temperature of ethylene-${\alpha}$-olefin copolymers and ethylene-vinyl acetate copolymers, respectively, indicate that MA plays a role of compatibilizer for these immiscible blends. The TGA thermograms, measured from the blends with MA, show that thermal stability is slightly enhanced with MA, indicating that MA acts as a reinforcing agent either by grafting or crosslinking with other copolymers.

Fabrication and Characterization of Immiscible Fe-Cu Alloys using Electrical Explosion of Wire in Liquid

  • Phuc, Chu Dac;Thuyet, Nguyen Minh;Kim, Jin-Chun
    • Journal of Powder Materials
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    • v.27 no.6
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    • pp.449-457
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    • 2020
  • Iron and copper are practically immiscible in the equilibrium state, even though their atomic radii are similar. As non-equilibrium solid solutions, the metastable Fe-Cu alloys can be synthesized using special methods, such as rapid quenching, vapor deposition, sputtering, ion-beam mixing, and mechanical alloying. The complexity of these methods (multiple steps, low productivity, high cost, and non-eco-friendliness) is a hinderance for their industrial applications. Electrical explosion of wire (EEW) is a well-known and effective method for the synthesis of metallic and alloy nanoparticles, and fabrication using the EEW is a simple and economic process. Therefore, it can be potentially employed to circumvent this problem. In this work, we propose the synthesis of Fe-Cu nanoparticles using EEW in a suitable solution. The powder shape, size distribution, and alloying state are analyzed and discussed according to the conditions of the EEW.

MHD Pulsatile Flow and Heat Transfer of Two Immiscible Couple Stress Fluids Between Permeable Beds

  • Kumar, Deepak;Agarwal, Manju
    • Kyungpook Mathematical Journal
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    • v.61 no.2
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    • pp.323-351
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    • 2021
  • The present paper addresses magnetohydrodynamic pulsating flow and heat transfer of two immiscible, incompressible, and conducting couple stress fluids between two permeable beds. The flow between the permeable beds is assumed to be governed by Stokes' [28] couple stress fluid flow equations, whereas the dynamics of permeable beds is determined by Darcy's law. In this study, matching conditions were used at the fluid-fluid interface, whereas the B-J slip boundary condition was employed at the fluid-porous interface. The governing equations were solved analytically, and the expressions for velocity, temperature, mass flux, skin friction, and rate of heat transfer were obtained. The analytical expressions were numerically evaluated, and the results are presented through graphs and tables.