• Bulletin of the Korean Chemical Society
• /
• v.31 no.11
• /
• pp.3190-3194
• /
• 2010

Mixed electrolytes formed by the combination of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP-TFSI) ionic liquid and standard liquid electrolyte are prepared and characterized. Linear sweep voltammetry measurements demonstrate that these mixed systems exhibit a wide electrochemical stability window, allowing them to be suitable electrolyte for carbonaceous anode-based lithium-ion batteries. Lithium-ion cells composed of graphite anode and $LiCoO_2$ cathode are assembled using the mixed electrolytes, and their cycling performances are evaluated. The cell containing proper content of BMP-TFSI shows good cycling performance comparable to that of a cell assembled with organic electrolyte. The presence of BMP-TFSI in the mixed electrolyte contributes to the reduction of the flammability of electrolyte solution and the improvement of the thermal stability of charged $Li_{1-x}CoO_2$ in the electrolyte solution.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2004.05b
• /
• pp.188-191
• /
• 2004

Carbon molecular sieve (CMS) membranes have superior gas permeation and separation performance compared with polymeric membranes$^{1.3}$ . Up to now, CMS membranes mostly have been mostly focused on the kinds of precursor and pyrolysis condition (pyrolysis temperature, heating rate, pyrolysis atmosphere).(omitted)

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.338-338
• /
• 2011

최근 FPD (Flat Pannel Display) 시장이 커짐에 따라 고효율, 저비용 제작 공정이 화두로 떠오르고 있다. ELA (Excimer Laser Annenling)을 이용한 LTPS (Low Temperature Poly Silicon) 공정은 mobility와 전류 점멸비 등에서 장점을 가지지만, 고비용, 대면적과 short-range에서 uniformity가 어렵다는 단점이 있다. 이를 극복하기 위한 방법으로 dLTA (diode Laser Thermal Annealing) 공정에 대한 연구가 진행되고 있다. 본 연구에서는 Flexible Display을 만들기 위한 방법으로 dLTA 공정을 진행하였다. 이 방법은 PI (Poly imide) 기판 위에 a-Si을 ICP CVD로 증착시킨 후, Diode Laser (980 nm)를 이용한 annealing을 통하여 a-Si이 poly-Si으로 결정화가 되는 것을 확인하였고, 에너지 조사량에 따른 grain boundary와 grain size을 통하여 비교 분석하였다. 실험 결과 ELA 공정을 이용한 것과 버금가는 실험 결과를 얻을 수 있었다.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1994.03a
• /
• pp.1-21
• /
• 1994

There are growing needs to produce relatively high purity (99.0% or higher) oxygen at low cost. For small scale production, both pressure swing adsorption (PSA) and membrane process are competitve and less expensive or more convient than well known crygenic fractionation technology. A continuous membrane colume (CMC) combined with a PSA oxygen generator can be employed to produce high purity oxygen continuosly. The oxygen-enriched gas generated by a PSA unit, with a concentration of 93-94%, is fed to the CMC that consists of three modules of poly(imide) hollow fibers. Several experiments were conducted by varying parameters, such feed flow rate, transmenbrane pressure drop, stage cut, and feed location in order to obtain a high oxygen concentration above 99.0%. A two-series unit mode was also employed with CMC operation to optimize the given membrane area.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.1
• /
• pp.105-108
• /
• 2011

The cycling behavior of $Li_4Ti_5O_{12}$ electrode in the ionic liquid (IL)-based electrolytes containing 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and a small amount of additive (vinylene carbonate, ethylene carbonate, fluoroethylene carbonate) was investigated. The $Li_4Ti_5O_{12}$ electrode in the IL electrolyte with an additive exhibited reversible cycling behavior with good capacity retention. Electrochemical impedance spectroscopy and FTIR studies revealed that an electrochemically stable solid electrolyte interphase was formed on the $Li_4Ti_5O_{12}$ electrode in the presence of vinylene carbonate and ethylene carbonate during cycling.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.146-147
• /
• 2008

Poly(3,4-ethylenedioxythiophene) (PEDOT) / poly(1-vinyl-3-ethylimidazolium bis(trifluoromethane sulfonyl)imide) (poly(ViEtIm $^+TFSI^-$) complex was prepared for organic solvent dispersible conductive nano particles. By molar ratio, PEDOT / poly(ViEtIm $^+TFSI^-$) complex was polymerized and dispersed in propylene carbonate by 1 wt%. The maximum conductivity of the complexes was $1.2\times10^{-1}$ S/cm.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2007.08a
• /
• pp.564-566
• /
• 2007

Synthesis of two photoactive compounds containing core imide moiety was carried out for an application to interdielectric layer in TFTLCD array. An aqueous alkaline developable polymer matrix was synthesized by free radical copolymerization. A positive photoresist formulation was developed utilizing synthesized UV monomers, photoactive compound, binder polymer, sulfactant and alkali developable polymer matrix. It was found that via-holes with good resolution, high transmittance and thermal resistance could be obtained by photolithographic process utilizing the new positive interdielectric material with high thermal stability.

• Archives of Pharmacal Research
• /
• v.19 no.3
• /
• pp.248-250
• /
• 1996

In conclusion, a series of N-Cbz-.alpha.-amono-glutarimides (1a-f), combining common structures such as N-CO-C-N and cyclic imide in a single molecule, were prepared from the (R)- or (S)-N-Cbz-glutamic acid and evaluated for their anticonvulsant activities in MES and PTZ tests in order to develope new and broad spectrum anticonvulsant. In this study, N-Cbz-.alpha.-aminoglutarimides (1) except ac and af, showed significant anticonvulsant activity in both MES and PTZ tests enough to be recommended as promising new anticonvulsant drug candidates. Now we are continuing to investigate further anticonvulsant test (quantification)for these compounds and synthesize their analogues in order to develop more active anticonvulsant and define the structure activity relationship more precisely.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2003.07a
• /
• pp.87-89
• /
• 2003

Thermoplastic polyurethane(PU)-based blend membranes were prepared by the solvent evaporation process. The gas sorption, diffusion, and permeation properties of PU-based blend membranes have been studied. The morphology of PU-based blend membranes was investigated by SEM. The result showed that phase separation occurred with increasing blend ratio. $CO_2$ permeation behaviors of blend membranes were affect by blend composition. Thermoplastic polyurethane(PU)-based membranes showed high $CO_2$ permeation and $CO_2$/$N_2$ selectivity of the blend membrane was improved with increasing the blend ratio.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1994.05a
• /
• pp.99-102
• /
• 1994

The use of preformed polymers and their cross-linking have been a attempted in order to improve the intrinsic fraqility of monolayers and Langmuir-Blodgett (LB)films and to make their technological applications possible. It has shown that an imidization followed a polyion-complexation can stabilize the LB films against heat and solvents. And when the polymer structure was properly designed concurrent removal of the alkyl tails together with imide formation could be accomplished. In this paper we present a characteristic monolayer behavior of polymer with pendent polythers and carboxyls it’s polyion-complexed LB film with subphase polymer PAA and a possible skeletonization of the LB film by thermal imidization. Also deposition status of LB films are evaluated by using QCM