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CO and C3H8 Oxidations over Supported Co3O4, Pt and Co3O4-Pt Catalysts: Effect on Their Preparation Methods and Supports, and Catalyst Deactivation (Co3O4, Pt 및 Co3O4-Pt 담지 촉매상에서 CO/C3H8 산화반응: 담체 및 제조법에 따른 영향과 촉매 비활성화)

  • Kim, Moon-Hyeon;Kim, Dong-Woo;Ham, Sung-Won
    • Journal of Environmental Science International
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    • v.20 no.2
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    • pp.251-260
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    • 2011
  • $TiO_2$- and $SiO_2$-supported $Co_3O_4$, Pt and $Co_3O_4$-Pt catalysts have been studied for CO and $C_3H_8$ oxidations at temperatures less than $250^{\circ}C$ which is a lower limit of light-off temperatures to oxidize them during emission test cycles of gasoline-fueled automotives with TWCs (three-way catalytic converters) consisting mainly of Pt, Pd and Rh. All the catalysts after appropriate activation such as calcination at $350^{\circ}C$ and reduction at $400^{\circ}C$ exhibited significant dependence on both their preparation techniques and supports upon CO oxidation at chosen temperatures. A Pt/$TiO_2$ catalyst prepared by using an ion-exchange method (IE) has much better activity for such CO oxidation because of smaller Pt nanoparticles, compared to a supported Pt obtained via an incipient wetness (IW). Supported $Co_3O_4$-only catalysts are very active for CO oxidation even at $100^{\circ}C$, but the use of $TiO_2$ as a support and the IW technique give the best performances. These effects on supports and preparation methods were indicated for $Co_3O_4$-Pt catalysts. Based on activity profiles of CO oxidation at $100^{\circ}C$ over a physical mixture of supported Pt and $Co_3O_4$ after activation under different conditions, and typical light-off temperatures of CO and unburned hydrocarbons in common TWCs as tested for $C_3H_8$ oxidation at $250^{\circ}C$ with a Pt-exchanged $SiO_2$ catalyst, this study may offer an useful approach to substitute $Co_3O_4$ for a part of platinum group metals, particularly Pt, thereby lowering the usage of the precious metals.

The effect of starvation on the characteristics of morphometric measurement and body-sectioned shape in Far Eastern catfish (Silurus asotus) (메기(Silurus asotus) 기아 시 외부형태 및 체 절단면 변화)

  • Park, In-Seok;Goo, In Bon;Gil, Hyun Woo
    • Korean Journal of Environmental Biology
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    • v.39 no.1
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    • pp.55-67
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    • 2021
  • A 210-day experiment was conducted to examine the effects of starvation on survival, external morphometric traits, and sectioned morphometric traits in Far Eastern catfish(Silurus asotus). The survival rate decreased to 92.2±0.47% in the fed group and to 74.4±2.59% in the starved group. Eight dimensions of Ls, DALPO/Ls, DADOP/Ls, ED/Ls, CH/Ls, BDAA/Ls, BDMA/Ls, and BWAA/Ls showed significant differences (p<0.05), and 16 other dimensions of DALAD/Ls, DPDPL/Ls, HPLAA/Ls, HALAV/Ls, HALOP/Ls, DAUPO/Ls, DADAV/Ls, DADAA/Ls, Max BL/Ls, Man BL/Ls, LD/Ls, HWOP/Ls, DAUF/HL, DAUS/HL, IW/HL, and DAUE/HL were not significantly different among the initial, fed, and starved groups (p>0.05). The fed group showed higher total height (THX), wider width (WX), and larger area (AX) than those of the starved group in each body section. This research provides information on the morphometric traits and body sections of starved Far Eastern catfish. These results can be used as a basic guide to indicate nutritional status and assist in aquaculture methods for Far Eastern catfish. Moreover, the methods used in this study were considered helpful because the survey analysis method can be used to investigate information on the nutritional status of other fish species.

The Influences of Small Group Discussion and Students' Visual Learning Style on Learning with Multiple Representations Using Drawing and Writing: Focused on Chemical Concepts (소집단 토론과 시각적 학습 양식이 그리기와 쓰기를 활용한 다중 표상 학습에 미치는 영향: 화학 개념을 중심으로)

  • Kang, Hun-Sik;Sung, Da-Yeon;Noh, Tae-Hee
    • Journal of The Korean Association For Science Education
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    • v.27 no.1
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    • pp.28-36
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    • 2007
  • This study investigated the influences of small group discussion and students' visual learning style in learning chemical concepts with drawing and writing as methods to assist students in connecting and integrating multiple external representations. Seventh graders (N=449) at a coed middle school were assigned to individual drawing (ID), pair drawing (PD), individual writing (IW), and pair writing (PW) groups. All students learned "Boyle's Law" and "Charles's Law" for two class periods. Analyses of the results revealed that the students in the PD group, regardless of students' visual learning style, scored significantly higher than those in the ID group in a conception test. The scores of the students with strong visual learning preference in the PW group were significantly higher than those in the IW group in the conception test, while the scores of the students with weak visual learning preference were not significantly different between the two groups. Although the conception test scores of the PD group were higher than those of the PW group, the difference was relatively small. It was found that most students in both PD and PW groups perceived pair drawing and pair writing positively upon cognitive and motivational aspects.

Seismic Performance Evaluation of Masonry Infilled Wall With Non-seismic Detail (비내진 상세를 가진 조적채움벽의 내진성능평가)

  • Park, Byung Tae;Kwon, Ki Hyuk
    • Journal of the Korean Society of Safety
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    • v.32 no.1
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    • pp.66-74
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    • 2017
  • Masonry walls which are commonly used for partitions in low-rise reinforced concrete (RC) structures, can be easily exposed to high risks under strong earthquakes. Since the strength degradations cannot be protected under the ground motions, their applications cannot be recommended for building structures which are designed to possess high seismic performances. However, masonry-infilled walls are typically considered as non-structural elements in evaluating the seismic performance of building structures. In order to figure out this problem, this study performed experiments using two specimens-only RC frame and RC frame infilled with masonry walls- under static loading. Also, the study established analytical models representing fully infilled frames and bare frame, and compared their structural behavior with test results. In addition, analytical model representing partially infilled frames was established and analyzed. Test results indicated that strength and energy dissipating capacity were increased for IW-RN(fully infilled frames) compared to the NW(bare frame). The nonlinear static analysis of the three specimens was also conducted using the inelastic plastic hinge frame element and diagonal strut models, and the analytical results successfully simulated the nonlinear behaviour of the specimens in accordance with the test results.

Utilization of biofilter/photo-catalytic reactor system for the simultaneous treatment of hydrogen sulfide and toluene from waste-air

  • Lim, Kwang-Hee;Ping, Wang Zhi;Lim, Dong-Joon;Lee, Eun-Ju
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.287-292
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    • 2005
  • Transient behavior of biofilter/photo-catalytic reactor system was observed to eliminate both hydrogen sulfide and toluene from waste air at its four sampling ports. The biofilter was packed with a equivolume mixture of granular activated carbon(GAC) and compost as packing media on which Thiobacillus sp. IW and Burkholderia cepacia G4 were inoculated and were fixed. The biofilter/photo-catalytic reactor system was run for eight stages of operation under various operating conditions. As a result the removal efficiencies of hydrogen sulfide and toluene began to decrease from 100% after the inlet loads of hydrogen sulfide and toluene surpassed ca. 100 $S-g/m^{3}/h$ and $161g/m^{3}/h$, respectively, and were rapidly decreased to 60% after the inlet loads of hydrogen sulfide and toluene were increased to 200 $S-g/m^{3}/h$ and $644g/m^{3}/h$, respectively.

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Isolation of Cryphonechia parasitica from Cankers on Chestnut Trees in ]Korea

  • Ju, Young-Jik;Kim, Dae-Hyuk;Cha, Byeong-Jin
    • The Plant Pathology Journal
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    • v.18 no.1
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    • pp.23-29
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    • 2002
  • A total of 672 Cryphonectria parasitica was isolated from 2,536 blight lesions on chestnut twigs, which were collected from major chestnut plantations all over Korea. Isolation rates of each province ranged from 13.5% in Jeonbuk-ds to 37.4% in Gyeongnam-do, with an average rate of 25.6%. The isolates were classified into six groups according to color and shape of colony on PDA: smooth margin (S), irregular margin (I), yellow to brown (Y), white (W), and white with yellow center (C). Among these groups, IY was the most abundant with an isolation rate of 65%. On the other hand, SW, SC, IW, and SY were quite rare, with isolation rates ranging from 1.5% to 5.8%. When the 672 isolates were inoculated on the chestnut twigs,380 isolates (56.5%) caused lesions larger than the standard virulent isolate EPISS-2, while 158 isolates (23.4%) caused smaller lesions than the standard hypovirulent isolate UEP-1. However, 87.4% of the isolates belonged to the virulent group and only 12.6% belonged to the hypovirulent group based on Bavendamm test. In the provinces of Jeonnam-do, Jeonbuk-do, and Gyeongnamdo, which have high density of chestnut trees, the rates of hypovirulent-like isolates were over 20%.

Inverted exponentiated Weibull distribution with applications to lifetime data

  • Lee, Seunghyung;Noh, Yunhwan;Chung, Younshik
    • Communications for Statistical Applications and Methods
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    • v.24 no.3
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    • pp.227-240
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    • 2017
  • In this paper, we introduce the inverted exponentiated Weibull (IEW) distribution which contains exponentiated inverted Weibull distribution, inverse Weibull (IW) distribution, and inverted exponentiated distribution as submodels. The proposed distribution is obtained by the inverse form of the exponentiated Weibull distribution. In particular, we explain that the proposed distribution can be interpreted by Marshall and Olkin's book (Lifetime Distributions: Structure of Non-parametric, Semiparametric, and Parametric Families, 2007, Springer) idea. We derive the cumulative distribution function and hazard function and calculate expression for its moment. The hazard function of the IEW distribution can be decreasing, increasing or bathtub-shaped. The maximum likelihood estimation (MLE) is obtained. Then we show the existence and uniqueness of MLE. We can also obtain the Bayesian estimation by using the Gibbs sampler with the Metropolis-Hastings algorithm. We also give applications with a simulated data set and two real data set to show the flexibility of the IEW distribution. Finally, conclusions are mentioned.

The Effects of Ikwitang Extract on Indomethacin-induced Gastric Mucosal Lesions (익위탕(益胃湯)의 Indomethacin유발 위점막 손상에 대한 효과)

  • Baik, Tae-Hyun;Shin, Hye-Seung
    • The Journal of Internal Korean Medicine
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    • v.25 no.3
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    • pp.497-507
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    • 2004
  • This study was carried out to investigate the effects of Ikwitang extract on indomethacin-induced gastric mucosal lesions in mice. Experimental groups were classified into a non-treated group(NM group), a non-administered group(CON group), the Misoprostol-administered group(MI group) and the Ikwitang-extract-administered group(IW group). This study examined the morphological change, distribution of mast cells, mucous surface cells, acid mucose secreted cells, and apoptic cells, BrdU, COX-1, Hsp70, $NF-{\kappa}B\;p50$, PKC, COX-2 and IL-12B of gastric mucosa. Results : The results of this study were as follows: 1. In the Misoprostol-administered group and the Ikwitang-extract-administered group, the hemorrhagic erosion of gastric mucous and infiltrated mast cells decreased. 2. Mucous surface cells and acid mucose secreted cells abserved in the Misoprostol-administered group and the Ikwitang-extract administered group. 3. The distribution of apoptic cells, Hsp70, $NF-{\kappa}B\;p50$, PKC, COX-2, and IL-12B increased in the Control group, but decreased in the Misoprostol-administered group and Ikwitang-extract-administered group. 4. Cells proliferation of gastric mucosa and the COX-l positive cells decreased in the Control group, but increased in the Misoprostol-administered group and the Ikwitang-extract -administered group. The above results suggest the lkwitang extract had beneficial effects on indomethacin induced gastric mucosal lesions.

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An Iterative Method for Natural Frequency and Mode Shape Sensitivities (고유진동수와 모우드의 민감도를 구하기 위한 반복법)

  • JUNG, GH;JUNG, HJ;OH, JW;LEE, IW
    • Journal of Korean Society of Steel Construction
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    • v.8 no.3 s.28
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    • pp.21-34
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    • 1996
  • A numerical method is presented for computation of eigenvector derivatives used an iterative procedure with guaranteed convergence. An approach for treating the singularity in calculating the eigenvector derivatives is presented, in which a shift in each eigenvalue is introduced to avoid the singularity. If the shift is selected properly, the proposed method can give very satisfactory results after only one iteration. A criterion for choosing an adequate shift, dependent on computer hardware is suggested ; it is directly dependent on the eigenvalue magnitudes and the number of bits per numeral of the computer. Another merit of this method is that eigenvector derivatives with repeated eigenvalues can be easily obtained if the new eigenvectors are calculated. These new eigenvectors lie "adjacent" to the m (number of repeated eigenvalues) distinct eigenvectors, which appear when the design parameter varies. As an example to demonstrate the efficiency of the proposed method in the case of distinct eigenvalues, a cantilever plate is considered. The results are compared with those of Nelson's method which can find the exact eigenvector derivatives. For the case of repeated eigenvalues, a cantilever beam is considered. The results are compared with those of Dailey's method which also can find the exact eigenvector derivatives. The design parameter of the cantilever plate is its thickness, and that of the cantilever beam its height.

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Association of the 94 KDa Glucose-regulated Protein with Immunoglobulin Heavv Chain Binding Protein (BiP) (94 KDa Glucose-regulated Protein의 BiP과의 결합)

  • 강호성;김한도
    • The Korean Journal of Zoology
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    • v.35 no.4
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    • pp.456-465
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    • 1992
  • The 94 KDa glucose-resulsted Protein (SH 94), one of stress Proteins, is a Ca2+-binding protein in the endoplasmic reticulum (ER). In this study, the possible effect of Ca2+ on the native conformation of grp 94 was examined. When the purified grp 94 was analyzed by Sel filtration in the presence of either EGTA or CaCl2, it was eluted with apparent molecular weight (MW) of 100 KDa in both cases. When similarly analyzed with microtome or cell Ivsate, however, srp 94 was eluted with apparent IW of 200 KDa in the presence of E6TA, while with apparent MW of 100 KDa in the presence of CaCl2, indicating possible association of grp 94 with one or more other proteins in the absence of CaCl2. Consequently, immunoprecipitation with anti-grp 94 was carried out to determine which proteins specifically interact with grp 94. It is sho%un that srp 94 may interact, in a Ca2+_dependent manner. with other proteins including BiP (grp 78) which is also a stress protein in the ER.

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