• Analytical Science and Technology
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• v.22 no.1
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• pp.92-100
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• 2009

Azacrown resins were synthesized by mixing 1-aza-12-crown-4 macrocyclic ligand into styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslinkage of 1%, 2%, 5% and 10% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermogravimetric analysis (TGA), surface area (BET), and IR-spectroscopy. The effects of pH, time, crosslinkage of resins and dielectric constant of solvent on adsorption of metal ions by resin adsorbent were investigated. Metal ions showed a great adsorption over pH 3 and adsorption equilibrium of metal ions was about two hours. In addition, adsorptive selectivity of metals on the resin in ethanol solvent was increased in the order of ${UO_2}^{2+}$ > $Ca^{2+}$ > $Sm^{3+}$ ion and adsorption of uranium ion was decreased with increase of crosslinkage such as 1%, 2%, 5% and 10% and was inversely proportional to the order of dielectric constant of solvents.

• Journal of the Korean Chemical Society
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• v.32 no.4
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• pp.358-370
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• 1988

Several new ion exchange resins have been synthesized from chloromethyl styrene-1,4-divinylbenzene(DVB) with 1%, 2%, 4%, and 10%-crosslinking and macrocyclic ligands of cryptand type by interpolymerization method. The adsorption characteristics and the pH, time, solvents and concentration dependence of the adsorption of metal ions by this resin were studied. The correlation between the separation characteristics of uranium, rare earths and transition metal on the resins and the stability constants of complexes with macrocyclic ligands have been examined. The resins were very stable in both acidic and basic media and have good resistance to heat at $280^{\circ}C$. The $UO_2^{+2}$ aqueous solution are not adsorbed on the resins below pH 3.0, but the power of adsorption of $UO_2^{2+}$ increased rapidly above pH 4.0. The optimum equilibrium time for adsorption of metallic ions was twenty minutes and adsorptive power decreased in proportion to crosslinking size of the resins and order of dielectric constants of solvents used and the selective sequence for metal cations is in the order of $UO_2^{2+},\;Cu^{2+}\;and\;Nd^{3+}$.

• Journal of Chest Surgery
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• v.28 no.11
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• pp.963-966
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• 1995

Ischemia reperfusion injury occurs in various diseases. The role of oxygen free radicals in IR injury of the lung has been spotlighted and many studies have been performed. In this study, we tried to prepare a stable rat lung model for IR injury, focusing on surrounding conditions as hilar stripped left lung, clamped left pulmonary artery and bronchus,and declamped after determined period was passed, and right main pulmonary aretery was clamped. Arterial blood gas analyes were performed at 1, 10, 20, 30, minutes after reperfusion. Before clamping, PaO2 was 95 to 120 mmHg in all animals. There were six groups; Group I : temperature 15o C, and 120 minutes clamping, Group II: 20 oC, and 120 minutes clamping, Group III : 25 oC, and 120 minutes clamping, Group IV : 15oC, 90 minutes clamping, Group V : 20 oC, 90 minutes clamping,Group VI: 20 oC, 75 minutes clamping. Each groups contained 10 Sprague Dayley rats. The humidity was maintained 100 % as circulation imerged isotonic Hartmann`s solution of the pleural cavity. In group IV, V, and VI, PaO2 decreased significantly in all animals immediately after reperfusion, but 43 % survived till 10 minutes after reperfusion, it was 74.0$\pm$5.7, 73.3$\pm$10.8,and 88.2$\pm$17.7 mmHg. Pulmonary edema was observed histologically in 2/10 animals in group IV, 6/10 in group V , 3/10 in group VI, 9/10 in group I, and the other lungs showed all edema. We established a stable model by setting ischemic time,and temperature, between 75 to 90 minutes,15 to 20o C, and isotemperature Hartmann`s solution immersion of the pleural cavity.

• Journal of Sericultural and Entomological Science
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• v.33 no.1
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• pp.6-8
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• 1991

The study was carried out to investigate the effect of ethrel (2-chloroethylphosophonic acid, 39%) on the graftages quality. Ethrel was sprayed 5 days interval from October 10 to October 30 at 6 places (Suwon (I), (II), Chungju, Kongju, Wanju, Jangsong). Spraying conentration was 1, 000 ppm (400 times dilution). 1. Spray took 3.3 hrs and 500 m of ethrel on 10a eara. 2. The passed rate of graftages decreased 5-8% on the treatments earlier spray than on October 20. 3. New shoot length and number of shoot of the ethrel treatments were the same as the natural leaf falling.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.143-146
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• 2004

Natural zeolites have exhibited high sorption capacity for inorganic cations including heavy metals and ammonium. Moreover, they were proven to be effective for environmental applications such as permeable barriers for controlling the spread of cation-contaminated groundwater. However zeolites have little or no affinity for anionic species like chromium, as they possess a net negative structural charge. To achieve the simultaneous sorption for anionic contaminants, surfactant-modified zeolite (SMZ) has been employed as the possible sorbents. Current study focuses on simultaneous removal of heavy metals having different ionic form in aqueous solution, cadmium (C $d^{2+}$) and chromium (Cr $O_{4}$$^{2-}$), using newly developed materials, ZanF. ZanF, a potential alternative to SMZ, was derived from zeolite modified by Fe(II) chloride followed by reduction with sodium borohydride. Batch experiments were performed to estimate the removal efficiency of ZanF at different conditions. Under different pH ranging from 2 to 6, removal efficiency was investigated. And C $d^{2+}$ removal efficiency was estimated by varying background concentration of Cr $O_{4}$$^{2-}$, and vice versa. With the test results, ZanF was expected to be a possible reactive materials alternative to SMZ in permeable reactive barriers (PRBs) for treating the contaminated groundwater with cationic and anionic heavy metals.als.

• Journal of Korean Neurosurgical Society
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• v.52 no.4
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• pp.288-292
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• 2012

Objective : Microvascular decompression (MVD) for hemifacial spasm (HFS) is a safe and effective treatment with favorable outcomes. The purpose of this study was to evaluate the incidence of delayed cranirve (VI, VII, and VIII) palsy following MVD and its clinical courses. Methods : Between January 1998 and December 2009, 1354 patients underwent MVD for HFS at our institution. Of them, 100 patients (7.4%) experienced delayed facial palsy (DFP), one developed sixth nerve palsy, and one patient had delayed hearing loss. Results : DFP occurred between postoperative day number 2 and 23 (average 11 days). Ninety-two patients (92%) completely recovered; however, House-Brackmann grade II facial weakness remained in eight other patients (8%). The time to recovery averaged 64 days (range, 16 days to 9 months). Delayed isolated sixth nerve palsy recovered spontaneously without any medical or surgical treatment after 8 weeks, while delayed hearing loss did not improve. Conclusion : Delayed cranial nerve (VI, VII, and VIII) palsies can occur following uncomplicated MVD for HFS. DFP is not an unusual complication after MVD, and prognosis is fairly good. Delayed sixth nerve palsy and delayed hearing loss are extremely rare complications after MVD for HFS. We should consider the possibility of development of these complications during the follow up for MVD.

• Journal of the Korean Institute of Landscape Architecture
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• v.39 no.4
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• pp.83-97
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• 2011

In this study, space allocation with an assessment system for improving the function of the ecological use and function of each space was undertaken to suggest appropriate goals and directions. Ogeum Park, used as the study site, is a stronghold green zone located in the fan-shaped area of the Songpa-gu green zone on a 22ha area site. The assessment system for this study consisted of a total of 3 steps: Step 1 includes the division of the spatial block, Step 2 assesses the proper functioning of each spatial block, while Step 3 includes space allocation and presents improvements for function by space. This study performed a basin analysis with the consideration that Ogeum Park is a forest area and divided the site into a total of 8 areas according to how the sections of land are used. The function of wildlife habitat included an analysis of plant ecology(vegetation type, vegetation layer, potential vegetation), animal ecology(wild birds), and waterways. The function of leisure and use included an analysis of gradients, noise, paths, status of use, and status of facilities. The evaluation of the function of habitat sorted items into native vegetation, vegetation diversification, vegetation potential, animal diversification and potential of animal habitats. The results of grading the evaluation scores by space in the function of habitat showed that the Areas IV and VII, which were 90% of the maximum point, were Grade A, Areas II and V were Grade B at 70% and Area I and VI were Grade C at 50%. Areas III and VIII, which were not found to be beyond the standard of 50%, were excluded. The evaluation of the functions of leisure and use classified items into use potential, use preference, use concentration, use diversification and use convenience. The results of the graded evaluation scores by space in use function, showed areas V and VI as Grade A, or 90% of the maximum score. Grade B, 70% of the maximum score, was given to Areas I and VII. Grade C, 50% of the maximum score, included Areas II, IV and VIII. Area III, graded lower the standard of 50%, was excluded. The study evaluated areas according to a common standard, classified spaces by proper functions into ecological spaces, environmentally-friendly use spaces and use spaces according to the standard of spatial distribution on the basis of the above results through a synthesis of grades of habitat function, leisure function and use. This offers ideas for the improvement of wildlife habitat and environment-friendly use functions by space.

• The Journal of Korean Academy of Prosthodontics
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• v.52 no.2
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• pp.105-112
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• 2014

Purpose: The aim of present investigation was to find out the influence of several times iatrogenic mobilization in the initial stage of implant installation on bone-implant osteointegration. Materials and methods: The experimental implants (3.75 mm in diameter, 8.0 mm in length) were made of commercially pure (Grade IV) titanium, and were treated with RBM ($MegaGen^{(R)}$: Ca-P) on lower 4.0 mm part. Only lower part of implant was inserted to bone and the implants were nonsubmerged. The 130 implants (two in each tibia) were inserted into the monocortical tibias of 33 rabbits which each weighed more than 3.5 kg (Female, New Zealand White). According to the removal torque interval, the groups were divided into 13 groups, group I (1 day), group II (1 day + 2 days), group III (1 day + 2 days + 3 days), group IV (1 day + 2 days + 3 days + 4 days), group V (2 days), group VI (2 days + 4 days), group VII (2 days + 4 days + 6 days), group VIII (2 days + 4 days + 6 days + 8 days), group IX (4 days), group X (4 days + 7 days), group XI (4 days + 7 days + 10 days), group XII (4 days + 7 days + 10 days + 14 days) and control group. In the control group, the removal torque was measured at 8 weeks with a digital torque gauge (Mark-10, USA). In the experimental groups, the removal torque was given once, twice, three times or four times by experiment design before the final removal torque and the value was measured each time. The implants were then screwed back to their original positions. All the experimental groups were given a final healing time of 8 weeks after placement, in which values were compared with the control groups and the 1st, 2nd, 3rd or 4th removal torque values in each experimental group. Results: In comparison of the final removal torque tests among experimental groups, the removal torque value of experimental groups except group XII were not statistically different that of control group. And the values of group I and II were significantly higher than the values of group VI, VIII, X, XI, and XII. In addition, the values of group III, IV, and V were significantly higher than group XI and XII. In comparison of the removal torque in the each experimental group, the final removal torque were significantly higher in all groups except group VIII, X, XI, and XII. Conclusion: If sufficient healing time was allowed, a few mobilization of fixture at the very early stage after the implant placement in the rabbits didn't interrupt the final bone to implant osseointegration.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.18 no.4
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• pp.29-41
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• 2015

Abandoned paddy field provides an excellent opportunity to improve the species diversity and habitat quality. Ecological characteristic on the changing of plant communities at different seral stages is a major basis data for ecological restoration. In this study, we investigated changes of the species composition and community indices on the plant community associated with abandonment of cultivated rice paddies. The ecological stability of the habitat was evaluated by using eco-floristic characters(Di; Disturbance index, AUI; Actual urbanization index). Survey sites were grouped into six stages(stageI (${\leq}3years$), stageII(3-5years), stageIII(5-7years), stageIV(7-10years), stageV(10-15years), stageVI(${\geq}20years$). Vegetation investigation was done from May 2009 to October 2012 and carried out phytosociological approach. The total flora were summarized as 176 taxa including 58 families, 127 genera, 157 species, 3 subspecies, 15 varieties and 1 forms. At each of successional stages, 64 taxa in stage I, 34 taxa in stage II, 84 taxa in stage III, 83 taxa in stage IV, 92 taxa in stage V, 23 taxa in stage VI were identified. Of the occurrence plants, the species with the highest r-NCD value were Alopecurus aequalis, Juncus effuusus var. decipiens, Persicaria thunbergii, Artemisia princeps, Salix koreensis and Alnus japonica at each stages. Herbaceous annual plants were dominated in the early stage, but its r-NCD value declined in the middle stage and the late stage. On the other hand, herbaceous perennial plants and Persicaria thunbergii, annual hydrophytes, increases in the middle stage. Woody plant and herbaceous plant which appeared in the forest edge increases in the late stage. Community indices correlate with successional stages. Richness and diversity index increase along the successional gradient. But dominance index decrease along the successional gradient. Evenness index was correlated with lower. In the ecological stability analysis of the habitat that evaluated by eco-floristic characters, stage I was the most unstable habitat. And the stability of the habitat has improved according to the successional stage.

• Korean Journal of Environment and Ecology
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• v.35 no.1
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• pp.68-80
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• 2021

This study aimed to provide basic data such as the structure of the Carpinus turczaninowii community and characteristics of the habitat environment for ex situ conservation by analyzing the plant community structure of Carpinus turczaninowii, an island plant resource. For the community structure analysis, this study established 29 plots, sized 100㎡ each, in Seokmo, Yeongjong, Yeongheung, and Daebu islands. TWINSPAN was used for the classification of communities. The classification identified six communities. Group I was the C. turczaninowii-Quercus serrata community, group II was the C. turczaninowii-Pinus densiflora community, group III was the C. turczaninowii-Quercus mongolica community, group IV was the C. turczaninowii-Sorbus alnifolia community, group V was the C. turczaninowii typical community, and group VI was the C. turczaninowii-Quercus variabilis community. The species diversity was 0.90008~1.12868, the dominance was 0.17536~0.25665, and the similarity index was 17.1429~38.2979%. The result of correlation analysis of 7 environmental factors for 6 communities by RDA ordination showed a positive correlation between the crown density and litter layer and a negative correlation between the bare rock, soil hardness, and altitude on the 1st axis. On the 2nd axis, the bare rock and crown density showed a positive correlation, and the slope showed a negative correlation. In the C. turczaninowii-Quercus serrata community (I), the crown density and the litter layer were the environmental factors affecting the vegetation distribution. In the C. turczaninowii-Pinus densiflora (II) and C. turczaninowii-Quercus mongolica (III) communities, the slope was the factor affecting vegetation distribution. In the C. turczaninowii-Sorbus alnifolia (IV), C. turczaninowii typical (V), and C. turczaninowii-Quercus variabilis (VI) communities, the bare rock, altitude, and soil hardness were the factors affecting vegetation distribution.