• Title/Summary/Keyword: ICP monitoring

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Arsenic Speciation and Risk Assessment of Miscellaneous Cereals by HPLC-ICP-MS (HPLC-ICP-MS를 활용한 잡곡의 비소 화학종 및 위해 분석)

  • An, Jae-Min;Hong, Kyong-Suk;Kim, Sung-Youn;Kim, Dae-Jung;Lee, Ho-Jin;Shin, Hee-Chang
    • Korean Journal of Environmental Agriculture
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    • v.36 no.2
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    • pp.119-128
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    • 2017
  • BACKGROUND: Miscellaneous cereal have been largely consumed in Korea as due to their physiological functions beneficial to human health. The cereals are currently a social concern because they have been found to contain heavy metals. Thus, monitoring heavy metals in the cereals is an important requirement for food safety analysis. In this study, we determined arsenic concentration in the cereals randomly harvested from different markets. METHODS AND RESULTS: Inorganic arsenic was determined by ICP-MS coupled with HPLC system. The HPLC-ICP-MS analysis was optimized based on the limit of detection and recover test to reach $0.13-1.24{\mu}g/kg$ and 94.3-102.1%, respectively. The concentrations of inorganic arsenic equivalent to daily exposure were levels of $19.91{\mu}g/day$ in mixed grain, $1.07{\mu}g/day$ in glutinous rice, $0.77{\mu}g/day$ in black brown rice, $0.13{\mu}g/day$ in barley and $0.11{\mu}g/day$ in soybeans. CONCLUSION: The levels of arsenic in miscellaneous cereals were found lower than the recommended The Joint FAO/WHO Expert Committee on Food Additives (JECFA) levels, suggesting that the cereals marketed in Korea are not potential concern in risk assessment.

Dynamic 3D Worker Pose Registration for Safety Monitoring in Manufacturing Environment based on Multi-domain Vision System (다중 도메인 비전 시스템 기반 제조 환경 안전 모니터링을 위한 동적 3D 작업자 자세 정합 기법)

  • Ji Dong Choi;Min Young Kim;Byeong Hak Kim
    • IEMEK Journal of Embedded Systems and Applications
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    • v.18 no.6
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    • pp.303-310
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    • 2023
  • A single vision system limits the ability to accurately understand the spatial constraints and interactions between robots and dynamic workers caused by gantry robots and collaborative robots during production manufacturing. In this paper, we propose a 3D pose registration method for dynamic workers based on a multi-domain vision system for safety monitoring in manufacturing environments. This method uses OpenPose, a deep learning-based posture estimation model, to estimate the worker's dynamic two-dimensional posture in real-time and reconstruct it into three-dimensional coordinates. The 3D coordinates of the reconstructed multi-domain vision system were aligned using the ICP algorithm and then registered to a single 3D coordinate system. The proposed method showed effective performance in a manufacturing process environment with an average registration error of 0.0664 m and an average frame rate of 14.597 per second.

A Feasibility Study for Application of On-Line Wear Condition Monitoring Technique to the High-powered Diesel Engine (고출력 디젤 엔진의 On-Line 마모상태진단 기술 적용을 위한 기초연구)

  • 윤민호;정동윤;공호성
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.10a
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    • pp.59-65
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    • 1997
  • The calibration of O.M.D is carried out experimentally and is analysed theoretically. O.M.D experimentally measures the change in optical density of artificially contaminated oil which contains Fe powder of 5, 10, 20, 30, 40, 50, 70, 100, 200 ppm. The change in optical density, D$_1$ means the logarithmic transmittance of I$_0$ over $I_1 D_2$ denotes the logarithmic transmittance I$_2$ over I$_1$ on electromagnetic force which arranges the ferrous particles along the line of magnetic force. The theoretical D$_1$ which increases linearly as increasing Fe concentrations, is analysed by light attenuation theory. The difference between theoretical D$_1$ and experimental D$_1$ is due to the attenuation of micro bubbles and the agglomeration of fine particles in the sample oil. The calibrated O.M.D is applied to the sample oil from the high-powered diesel engine. Also the results are compared with those out of the off-line techniques such as JOAP and ICP.

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Plasma Uniformity Analysis of Inductively Coupled Plasma Assisted Magnetron Sputtering by a 2D Voltage Probe Array

  • Joo, Junghoon
    • Applied Science and Convergence Technology
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    • v.23 no.4
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    • pp.161-168
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    • 2014
  • A real-time monitoring of immersed antenna type inductively coupled plasma (ICP) was done with a homemade 2 dimensional voltage probe array to check the uniformity of the plasma. Measured voltage values with a high impedance voltmeter are close to the floating potential of the plasma. As the substrate carrier was moving into a magnetron sputtering plasma diffusive from a $125mm{\times}625mm$ size cathode, measured results showed reliably separation of plasma into the upper and lower empty space over the carrier. Infra red thermal imaging camera was used to observe the cross corner effect in situ without eroding a target to the end of the usage. 3 dimensional particle trace model was used to analyze the magnetron discharge's behavior.

Laser Thomson Scattering for Measuring Plasma Temperature and Density in ICP

  • Seo, Byeong-Hun;Yu, Sin-Jae;Kim, Jeong-Hyeong;Jang, Hong-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.144-144
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    • 2011
  • Diagnostics of plasma density and temperature play an important role for monitoring plasma processing and Laser Thomson scattering is a one of the most accurate diagnostic technique for measuring plasma density and temperature because of none-perturbation to plasma among various diagnostic techniques invented to measure plasma density and temperature. I will briefly review Laser Thomson scattering experiment performed in KRISS and difficulties for measuring the electron velocity distribution such as Gaussian due to low signal-to-noise ratio with showing results that we got until now. This work is an intermediate step in a process that we will get a reliable data which shows physical phenomenon of plasma compared with other diagnostic techniques and results.

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Monitoring Research for Heavy Metals as Endocrine Disruptors in Sibjeonaebotang and Its Ingredients Herbal Medicines(II) (한약재와 탕액(십전대보탕) 중 내분비계 장애물질로서의 개별 중금속 함량분석(II))

  • 김진숙;황성원;김종문;마진열
    • YAKHAK HOEJI
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    • v.45 no.5
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    • pp.448-454
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    • 2001
  • The contents of heavy metals in boiled Sibjeonaebotang with those in its herbal ingredients are compared. The herbal medicines of Sibjeonaebotang were bought at 10 defferent markets. The contents of 14 heavy metals (Ag, As, Ba, Cd, Cr Cu, Fe, Hg, Mn, Ni, Pb, Sb, Sn, Zn) were analysed using ICP It was found out that 5 heavy metals (Pb, As, Ba, Fe, Sb) were detected in only one boiled Sibjeonaebotang But they were detectable in all Sibjeonaebotang and its herbal before boiling. For example the content of Hg in one pack of Sibjeonaebotang before boiling was 0.064$\pm$0.016 me and Hg in boiled one was 0.002$\pm$0.005mg. These results suggest that boiled Sibjeonaebotang which we take is less harmful than herbal medicine itself by heavy metals.

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Real time monitoring of In-Line type sputtering system using an in-vacuo wireless camera (내장형 무선 카메라를 이용한 In-Line type 스퍼터링 시스템 내부의 실시간 모니터링)

  • Choi, Ji-Seong;Do, Woo-Ri;Hong, Kwang-Gi;Ju, Jeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.243-244
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    • 2009
  • 진공 chamber 내부 plasma를 외부에서 view port를 통한 확인 및 촬영보다 효율을 높이기 위하여 chamber 내부에 무선 camera (IVC : internal vacuum camera)를 삽입하여 더 세밀하게 plasma를 촬영하였고 view port로 확인이 불가능한 부분을 촬영 및 녹화하였다. 외부 view port로 확인할 수 없는 원거리 플라즈마 소스 (remote plasma source, RPS)와 in-line type의 chamber에서 동적 (dynamic) 증착이 이루어지는 substrate에 camera를 부착하여 이동 중 target 위쪽에 방전된 plasma, ICP (inductively coupled plasma) antenna를 진공 중 chamber 내부에서 촬영 및 녹화하였다.

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Study of silicon deep via etching mechanism using in-situ temperature monitoring of silicon exposed to $SF_6/O_2$ plasma discharge

  • Im, Yeong-Dae;Lee, Seung-Hwan;Yu, Won-Jong;Jeong, Oh-Jin;Lee, Han-Chun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.10a
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    • pp.116-117
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    • 2009
  • 식각 공정변화 즉 상부 ICP 파워, 반응기 압력, 실리콘 기판 온도변화에 따른 실리콘 딥 비어 (deep via) 의 형상 변화 메커니즘을 연구하였다. 메커니즘을 연구하기 위해 $SF_6/O_2$ 플라즈마에 노출된 실리콘 기판의 공정변화에 따른 표면 온도변화를 실시간으로 측정하여 플라즈마 내 positive ions의 거동을 분석하였다. 실리콘 기판의 표면온도를 상승시키는 주된 요인은 positive ions임을 확인할 수 있었으며 이는 기판에 적용된 negative voltage로 인하여 나타난 이온포격이 그 원인임을 알 수 있었다. 상대적으로 radical은 실리콘 표면온도 상승에 큰 역할을 하지 못하였다. 기판 표면온도가 상승 할수록 실리콘 딥 비어 구조에 undercut, local bowing과 같은 측벽 식각이 활성화됨을 확인할 수 있었으며 이는 기판에 들어오는 positive ions가 측벽식각을 유도하는 것으로 해석할 수 있었다.

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A Study on the Electrodeposition of NiFe Alloy Thin Films Using Chronocoulometry and Electrochemical Quartz Crystal Microgravimetry

  • Myeong, No Seung
    • Bulletin of the Korean Chemical Society
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    • v.22 no.9
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    • pp.994-998
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    • 2001
  • Ni, Fe and NiFe alloy thin films were electrodeposited at a polycrystalline Au surface using a range of electrolytes and potentials. Coulometry and EQCM were used for real-time monitoring of electroplating efficiency of the Ni and Fe. The plating efficiency of NiFe alloy thin films was computed with the aid of ICP spectrometry. In general, plating efficiency increased to a steady value with deposition time. Plating efficiency of Fe was lower than that of Ni at -0.85 and -1.0 V but the efficiency approached to the similar plateau value to that of Ni at more negative potentials. The films with higher content of Fe showed different stripping behavior from the ones with higher content of Ni. Finally, compositional data and real-time plating efficiency are presented for films electrodeposited using a range of electrolytes and potentials.

Application of a Membrane Desolvator to the Analysis of Organic Solvents in Inductively Coupled Plasma Atomic Emission Spectrometry

  • Lee, J. S.;Lim, H. B.
    • Bulletin of the Korean Chemical Society
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    • v.20 no.9
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    • pp.1040-1044
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    • 1999
  • A micro porous PTFE membrane desolvator (MMD) was built and evaluated for the on-line removal of organic solvents to facilitate the determination of trace metal contaminants in the solvents by ICP-AES. Three organic solvents, isopropyl alcohol (IPA), methanol, and dimethy sulfoxide (DMSO) were studied. The MMD reduced organic solvent concentration in the sample aerosol stream by 82% to 89%, as indicated by monitoring C(I) emission. Net signal intensity of Fe, Al, and Cu was increasing with higher organic solvent concentration, with the rate of increase being solvent dependent. The signal intensities for Mg and Pb followed the trend with the C(I) signal. Changing the sweep gas flow rate affected the optimum signal intensity. Wine samples were analyzed by the method of standard addition. The concentrations of B, Al, and Mg were determined with a relative precision of less than 2.3%.