• Title/Summary/Keyword: ICP

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Sulfur Dioxide, Heavy Metal and Curcumin Contents in Market-Available Turmeric (Curcuma longa L.) (유통 강황의 이산화황, 중금속 및 쿠르쿠민 함량)

  • Lee, Young Ju;Kim, Ae Kyung;Kim, Ouk Hee;Lee, Chun Young;Lee, Hyun Kyung;Jung, Sun Ok;Lee, Sae Ram;Kim, Hee Sun;Kim, Il Young;Yu, In Sil;Jung, Kweon
    • Korean Journal of Medicinal Crop Science
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    • v.24 no.2
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    • pp.121-128
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    • 2016
  • Background: Turmeric (Curcuma longa L.) that is used as a food material has antioxidant, anticancer and anti-inflammatory properties. Recently the demand for functional foods and drugs has increased. The present study was carried out to determined of contents of residual sulfur dioxide, heavy metals, ash, acid insoluble ash and curcuminoids in turmeric from the Seoul Yak-ryeong market. Methods and Results: A total of 31 samples were obtained. Residual sulfur dioxide was not detected in any samples. Heavy metals (arsenic, cadmium, lead and mercury) were analyzed by ICP-MS (Inductively Coupled Plasma Mass Spectrometer) and a mercury analyzer and were detected in the ranges of 0.00 - 0.28, 0.00 - 0.07, 0.00 - 0.29 and 0.002 - 0.027mg/g respectively. No significant difference were observed between the average heavy metal contents of domestic and imported tumeric. However, average content of ash in domestic samples (7.8%) were significantly higher than that in imported samples (6.1%), whereas that of curcuminoids was significantly higher in imported samples (47.6mg/g) than in domestic samples (11.2mg/g). The average content of acid insoluble ash was not significantly different between two sample types (0.9% in each). Conclusions: There are no specific standards for turmeric used as food materials. Therefore, this study can be provided as basic data for the establishment of quality standards for turmeric.

Comparision of Chemical Components of Angelica gigas Nakai and Angelica acutiloba Kitagawa (토당귀와 일당귀의 화학성분 비교)

  • Hwang, Jin-Bong;Yang, Mi-Ok
    • Korean Journal of Food Science and Technology
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    • v.29 no.6
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    • pp.1113-1118
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    • 1997
  • Chemical components of domestic Angelica gigas Nakai and Angelica acutiloba Kitagawa were analyzed. Proximate analysis of each species showed crude protein 18.1% and 13.4%, crude lipid 8.9% and 4.3%, crude fiber 8.6% and 9.4%, crude ash 7.4% and 8.2%, and carbohydrate 57.0% and 64.7%, respectively. Contents of potassium which was found to be the most abundant mineral in both species were 2,740.0 mg% and 2,582.8 mg%, and those of sucrose were 0.4 % and 0.3% respectively while neither fructose nor glucose were detected in each species. Major fatty acids in Angelica gigas Nakai and Angelica acutiloba Kitagawa were linoleic acid (60.8% and 59.5%), palmitic acid (17.4% and 15.3%), oleic acid (8.8% and 7.7%) (respectively) but there was no significant difference between two species. Arginine was revealed as the most abundant amino acid in both species with 2,599.8 mg% in Angelica gigas Nakai and 1,543.4 mg% in Angelica acutiloba Kitagawa. Angelica gigas Nakai and Angelica acutiloba Kitagawa also were shown to contained 10.5 mg% and 12.2 mg% $vitamin\;B_1$, 0.1 mg% and 0.04 mg%, $vitamin\;B_2$, 4.3% and 0.8% decursin, and 988.0 mg% and 900.0 mg% tannin, respectively.

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A study on the evaluation of metal component in automatic transmission fluid by vehicle driving (차량 운행에 따른 자동변속기유(ATF) 금속분 분석평가 연구)

  • Lee, Joung-Min;Lim, Young-Kwan;Doe, Jin-Woo;Jung, Choong-Sub;Han, Kwan-Wook;Na, Byung-Ki
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.28-34
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    • 2014
  • Automatic transmission fluid (ATF) is used for automatic transmissions in the vehicle as the characterized fluid. Recently, the vehicle manufacture usually guarantee for fluid change over 80000~100000 km mileage or no exchange, but most drivers usually change ATF below every 50000 km driving in Republic of Korea. It can cause to raise environmental contamination by used ATF and increase the cost of driving by frequently ATF change. In this study, we investigate the various physical properties such as flash point, fire point, pour point, kinematic viscosity, cold cranking simulator, total acid number, and metal component concentration for fresh and used ATF after driving (50000 km, 100000 km). The result showed that the total acid number, pour point, Fe, Al and Cu component had increased than fresh ATF, but 2 kind of used oil (50000 km and 100000km) had similar physical values and metal component concentration.

Geochemical Study of the Jigunsan Shale: A Sequence Stratigraphic Application to Defining a Middle Ordovician Condensed Section, Taebacksan (Taebaeksan) Basin (직운산 세일층의 지화학적 연구: 태박산분지 오오도비스 중기 응축층 규명을 위한 시퀀스층서학적 적용)

  • Ryu, In-Chang;Ryu, Sun-Young;Son, Byeong-Kook
    • Economic and Environmental Geology
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    • v.42 no.1
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    • pp.27-53
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    • 2009
  • A 30-m-thick Middle Ordovician Jigunsan Shale exposed along the southern limb of the Backunsan (Baekunsan) Syncline, Taebacksan (Taebaeksan) basin, has been simply considered as a transgressive shale sequence onlapped the underlying Maggol platform carbonates. Results of this study, however, suggest that majority of the Jigunsan Shale be interpreted as a regressive shale sequence downlapped onto a thin (ca. 240 cm) marine stratigraphic unit consisting of organic-rich (>3 wt.% of TOC) black shales in the lower Jigunsan Shale, which was accumulated at the time of maximum regional transgression. Detailed stratigraphic analysis in conjunction with XRD, XRF, and ICP-MS as well as Rock-Eval pyrolysis allows the thin marine stratigraphic unit in the Jigunsan Shale to define a condensed section that was deposited in a distinctive euxinic zone formed due to expansion of pycnocline during the early highstand phase. As well, a number of stratigraphic horizons of distinctive character that may have sequence stratigraphic or environmental significance, such as transgressive surface, maximum flooding surface, maximum sediment starvation surface, and downlap surface, are identified in the lower Jigunsan Shale. In the future, these stratigraphic horizons will provide very useful information to make a coherent regional stratigraphic correlation of the Middle Ordovician strata and to develop a comprehensive understanding on stratigraphic response to tectonic evolution as well as basin history of the Taebacksan Basin.

A Study on the Measurement of Activity Concentrations of Pu and Am and Their Isotopic Ratios in the Radioactively Contaminated Soil (방사능으로 오염된 토양에 대한 Pu 및 Am 방사능 농도 및 동위원소비 측정에 대한 연구)

  • Lee, Myung Ho;Song, Byoung Chul;Park, Young Jai;Kim, Won Ho
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.514-519
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    • 2004
  • Soil samples collected from around the BOMARC Missile Site were measured for their activity concentrations and isotopic ratios of Pu and Am isotopes with particle sizes. The activity concentrations of Pu and Am in the BOMARC soil were remarkably higher than the fallout levels, and the activities decreased nearly exponentially with an increasing particle size of the soil due to a decreasing surface area. The activity ratios of Pu-238 / Pu-239, 240, Pu-241 / Pu-239, 240 and Am-241 / Pu-239, 240 observed in the BOMARC soil were much lower than those attributed to the nuclear reprocess plants and the Chernobyl fallout. Also, the atomic ratio of Pu-240 / Pu-239 in the BOMARC soil was remarkably lower than the fallout value influenced by the nuclear weapons testing and the Chernobyl accident. The atomic ratio of Pu-240 / Pu-239 was so close to the value of the weapons grade Pu released from the crash of a B52 plane in the Thule of the Greenland, such that the Pu isotopes detected in the BOMARC soil could have originated from the weapons grade plutonium.

A Study on the Preparation of Powder Coatings Containing Halogen-Free Flame Retardant and Fire Safety (Halogen-Free 난연제를 포함하는 파우더 코팅소재 제조 및 화재안전성 연구)

  • Lee, Soon-Hong;Chung, Hwa-Young;Kim, Dae-In;Noh, Tae-Joon
    • Journal of the Korean Society of Safety
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    • v.26 no.4
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    • pp.47-58
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    • 2011
  • Halogen free intumescent flame retardants(IFRS), such as the mixture of melamine phosphate(MP) and char forming agents(pentaerythritol(PER), di-pentaerythritol(DiPER), tris(2-hydroxyethyl) isocyanurate(THEIC)), were prepared and characterized. Polypropylene(PP)/$IFR_S$ composites were also prepared in the presence of ethylene diamine phosphate(EDAP) as a synergist and used into flame retardant PP powder coatings. Thermoplastic PP powder coatings at 20 wt% flame retardant loading were manufactured by extruded and then mechanical cryogenic crushed to bring them in fine powder form. These intumescent flame retardant powder coatings($IFRPC_S$) were applied on mild steel surface for the purpose of protection and decorative. It is a process in which a $IFRPC_S$ particles coming in contact with the preheated mild steel surface melt and form a thin coating layer. The obtained MP flame retardant was analyzed by utilizing FTIR, solid-state $^{31}P$ NMR, ICP, EA and PSA. The mechanical properties as tensile strength, melt flow index(MFI) and the thermal property as TGA/DTA and the fire safety characteristics as limiting oxygen index(LOI), UL94 test, SEM were used to investigate the effect of $IFRPC_S$. The experimental results show that the presence of $IFR_S$ considerably enhanced the fire retardant performances as evidenced by the increase of LOI values 17.3 vol% and 32.6 vol% for original PP and $IFRPC_S$-3(PP/MP-DiPER/EDAP), respectively, and a reduction in total flaming combustion time(under 15 sec) in UL94 test of $IFRPC_S$. The prepared $IFRPC_S$-3 have good comprehensive properties with fire retardancy 3.2 mm UL94 V-0 level, LOI value 32.6%, tensile strength $247.3kg/cm^2$, surface roughness Ra $0.78{\mu}m$, showing a better application prospect. Through $IFRPC_S$-2(PP/MP-PER/EDAP) and $IFRPC_S$-3 a better flame retardancy than that of the $IFRPC_S$-1(PP/MP/EDAP) was investigated which was responsible for the formed more dense and compact char layer, improved synergy effect of MP and PER/DiPER.

A LAN Protocol Analyzer including Simulation Function for PC Environment (PC 환경에서 시뮬레이션 기능을 포함한 LAN 프로토콜 분석장비)

  • Chung, Joong-Soo;Lee, Jun-Won
    • Journal of KIISE:Computing Practices and Letters
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    • v.8 no.5
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    • pp.583-589
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    • 2002
  • The Internet is absolutely contributed to information telecommunication revolution nowadays. Realizing local network at the various type of buildings such as a company and a university, ethernet is used for subnet and FDDI, ATM are used for backbone mainly in order to get internet services. Processing TCP/IP protocol suite and analyzing the protocol exactly is essential to detecting the problem occurring in the network and developing communication equipment. This paper presents implementation of ethernet LAN protocol analyser which monitors and simulates ICP/IP protocol suite carrying the Internet and non-Internet protocol such as Netware and NetBIOS. MS window98 and visual C are used for development environment and application program operates on the NDIS firmware. The performance analysis on the proposed system is carried out as monitoring and simulating the traffic over LAN of a university. In the result of monitoring the system, the processing time of a packet captured over the LAN is about 1.5ms. In case of simulating the system, the processing time to be taken carrying out TCP connection and disconnection once is packet is about 8.6ms. The performance analysis of monitoring and simulation results satisfies with 10 Mbps ethernet LAN environment.

Investigation on Growth Characteristic of ZnO Nanostructure with Various O2 Pressures by Thermal Evaporation Process (열증착법으로 성장된 ZnO 나노구조물의 산소유량 변화에 대한 성장 변화)

  • Kim, Kyoung-Bum;Jang, Yong-Ho;Kim, Chang-Il;Jeong, Young-Hun;Lee, Young-Jin;Jo, Jeong-Ho;Paik, Jong-Hoo;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.10
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    • pp.839-843
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    • 2011
  • ZnO nanostructures were developed on a Si (100) substrate from powder mixture of ZnO and 5 mol% Pd (ZP-5) as reactants by ${\times}$ sccm oxygen pressures(x= 0, 10, 20, 40). DTA (differential thermal analysis) result shows the Pd(5 mol%)+ZnO mixtured powder(PZ-5) is easily evaporated than pure ZnO powder. The PZ-5 mixtured powder was characterized by DTA to determine the thermal decomposition which was found to be at $800^{\circ}C$, $1,100^{\circ}C$. Weight loss(%) and ICP (inductively coupled plasma) analysis reveal that Zn vaporization is decreased by increased oxygen pressures from the PZ-5 at $1,100^{\circ}C$ for 30 mins. Needle-like ZnO nanostructures array developed from 10 sccm oxygen pressure, was well aligned vertically on the Si substrate at $1,100^{\circ}C$ for 30 mins. The lengths of the Needle-like ZnO nanostructures is about 2 ${\mu}m$ with diameters of about 65 nm. The developed ZnO nanostructures exhibited growth direction along [001] with defect-free high crystallinity. It is considered that Zn vaporization is responsible for the growth of Needle-like ZnO nanostructures by controlling the oxygen pressures. The photoluminescence spectra of ZnO nanostructures exhibited stronger 376.7 nm NBE (near band-edge emission) peak and 529.3 nm DLE (deep level energy) peak.

Etching properties of $Na_{0.5}K_{0.5}NbO_2$ thin film using inductively coupled plasma (유도결합 플라즈마를 이용한 $Na_{0.5}K_{0.5}NbO_2$ 박막의 식각 특성)

  • Kim, Gwan-Ha;Kim, Kyoung-Tae;Kim, Jong-Gyu;Woo, Jong-Chang;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.116-116
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    • 2007
  • 21 세기에 접어들면서 인터넷을 통한 정보 통신의 발달과 개인 휴대용 이동 통신기기의 활발한 보급에 따라 휴대형 전자기기들의 소형화와 고성능화로 나아가고 있다. 이러한 전자기기에 사용될 IC의 내장 메모리 또한 집적화 및 고속화, 저 전력화가 이루어져야 한다. 이러한 전자기기들에 필수적인 압전 세라믹스 부품 중 압전 부저 및 기타 음향 부품등을 각종 전자기기와 무선 전화기에 채택함으로써 압전 부품에 대한 수요와 생산이 계속 증가할 것으로 전망된다. 이처럼 압전 세라믹스를 이용한 그 응용 범위는 대단히 방대하며, 현재 모든 압전 부품들은 PZT 계열 재료로 만들어지고 있고, 차후 모두 비납계열 재료로 대체될 것이 확실시된다. Pb의 환경오염은 이미 오래전부터 큰 문제점으로 인식되고 있었으며 그 일례로 미국의 캘리포니아 주에서는 1986년부터 약 800종의 유해물질, 그 중에서도 Pb 사용을 300ppm 이하로 규제하는 Proposition 65를 제정하여 실행하고 있다. 그리고 2003년 2월에 EU (European Union) 에서 발표한 전자산업에 관한 규제 사항중 하나인 위험물질 사용에 관한 지칭 (Restriction of Hazardous Substance, RoHS) 에 의하면, 2006 년 7월부터 전기 전자 제품에 있어서 위험 물질인 Pb을 포함한 중금속 물질(카드늄, 수은, 6가 크롬, 브롬계 난연재)의 사용을 금지한다고 발표하였다. 비록 전자세라믹 부품에 함유된 Pb는 예외 사항으로 두었지만 대체 가능한 물질이 개발되면 전자세라믹 부품에서도 Pb의 사용을 금지한다고 규정하였다. 더욱이 일본은 2005 년부터 Pb 사용을 금지시켰다. 이와 같이 Pb가 환경에 미치는 영향 때문에 비납계 강유전 물질 및 압전 세라믹스 재료에 대한 연구가 전 세계적으로 활발히 진행되고 있다. 본 연구에서는 비납계 강유전체의 patterning을 위해서, NKN 박막을 고밀도 플라즈마원인 ICP를 이용하여 식각 mechanism을 연구하고, 식각변수에 따른 식각 공정을 최적화에 대하여 연구하였다. 가스 혼합비에 따라 식각 할때 700 W의 RF 전력과 - 150 V의 직류 바이어스 전압을 인가하였고, 공정 압력은 2 Pa, 기판 온도는 $23^{\circ}C$로 고정하였다. 식각 속도는 Tencor사의 Alpha-step 500을 이용하여 측정되었으며 식각 시 NKN 박막 표면과 라디칼과의 화학적인 반응을 분석하고 식각 메커니즘을 규명하기 위하여 XPS(x-ray photoelectron spectroscopy)를 사용하였다.

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The Study of Radon Activity and Uranium Concentration of Ground Water and Surface Water (지하수와 지표수에서의 라돈 및 우라늄의 실태 조사)

  • Oh, Youngmi;Lee, Jongbok;Shin, Kyungjin;Kim, Hakchul;Lee, Jaehee;Hwang, Sangchul;Jung, Sanggi;Lee, Sangtae
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.201-205
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    • 2007
  • This paper reports the amount of $^{222}Rn$ and $^{238}U$ in 18 sites of ground water and 30 sites of surface water. The instrument used to count $^{222}Rn$ activity was the liquid scintillation counter (LSC) which could resolute ${\alpha}$ and ${\beta}$ radiations. And $^{238}U$ was analyzed by the inductively coupled plasma (ICP). Radon and Uranium were not detected in raw and treated water which were sampled in a water treatment plant. However, radon ($^{222}Rn$) was high concentration in ground water from Jeon-la, Gang-won. So was uranium ($^{238}U$) in case of ground water from Gang-won, Choong-chung. Radon ($^{222}Rn$) activities were detected less than 15 pCi/L at 5 sampling points, 15~300 pCi/L at 7 sampling points, 300~4000 pCi/L at 6 sampling points. However, Radon ($^{222}Rn$) activities of all ground water samples were less than 4,000 pCi/L, which was bellow American Alternative Maximum Contamination Level (AMCL). Uranium ($^{238}U$) concentrations were less than $0.1{\mu}g/L$ at 5 sampling points, from $0.1{\mu}g/L$ to $20{\mu}g/L$ at 13 sampling points. Uranium was not detected in about 30% of the whole samples, but the concentration ranged from relatively low to high concentrations depending on the sampling point. The minimum detectable activity (MDA) of radon was 15 pCi/L. and the detection limit of uranium was $0.1{\mu}g/L$.