• 제목/요약/키워드: I-kBa

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Structural and electrical properties of perovskite Ba(Sm1/2Nb1/2)O3-BaTiO3 ceramic

  • Nath, K. Amar;Prasad, K.
    • Advances in materials Research
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    • 제1권2호
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    • pp.115-128
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    • 2012
  • The structural and electrical properties of $(1-x)Ba(Sm_{1/2}Nb_{1/2})O_3-xBaTiO_3$; ($0{\leq}x{\leq}1$) ceramics were prepared by conventional ceramic technique at $1375^{\circ}C$/7 h in air atmosphere. The crystal symmetry, space group and unit cell dimensions were derived from the X-ray diffraction (XRD) data using FullProf software whereas crystallite size and lattice strain were estimated from Williamson-Hall approach. XRD analysis of the compound indicated the formation of a single-phase cubic structure with the space group Pm m. Dielectric study revealed that the compound $0.75Ba(Sm_{1/2}Nb_{1/2})O_3-0.25BaTiO_3$ is having low and ${\varepsilon}^{\prime}$ and ${\varepsilon}^{{\prime}{\prime}}$ a low $T_{CC}$ (< 5%) in the working temperature range (up to+$100^{\circ}C$) which makes this composition suitable for capacitor application and may be designated as 'Stable Low-K' Class I material as per the specifications of the Electronic Industries Association. The correlated barrier hopping model was employed to successfully explain the mechanism of charge transport in the system. The ac conductivity data were used to evaluate the density of states at Fermi level, minimum hopping length and apparent activation energy of the compounds.

MOD-TFA공정에 의한 YBCO박막 제조 시 cerium첨가효과에 관한 연구 (Effect of Cerium Doping on Superconducting Properties of YBCO Film Prepared by TFA-MOD Method)

  • 이금영;권연경;김병주;안지현;이종범;김호진;이희균;홍계원;유재무;이형철
    • Progress in Superconductivity
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    • 제8권1호
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    • pp.87-92
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    • 2006
  • The effects of Ba and Ce addition has been investigated in YBCO prepared by trifluoroacetate(TFA) metalorganic depostition(MOD) method. Precursor solutions with cation ratios of Y:Ba:Cu:Ce=1:2+x:3:x(x=0, 0.05, 0.1 and 1.5) have been prepared by adding an excess amount of cerium and barium. Coated film was calcined at lower temperature under a moisture-containing oxygen atmosphere. Superconducting YBCO films have been obtained by performing conversion heat treatment at temperature of $780{\sim}810^{\circ}C$ under a moisture-containing Ar(1,000 ppm oxygen) atmosphere. It has been shown that the critical current($I_c$) of YBCO film was degraded by doping of Ba and Ce atoms. But $I_c$ was increased as the amount of doped Ba and Ce content increased from 5% to 15 %. It was observed that there was little increase of a flux pinning force with Ba and Ce addition in YBCO film prepared by TFA-MOD process.

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$BaTiO_{3}$ 의 광굴절 현상을 이용한 실시간 광연상 메모리에 관한 연구 (A Study on the Real-time Optical Associative Memory Using Photorefractive Effects in $BaTiO_{3}$)

  • 임종태;오창석;김성일;박한규
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1988년도 전기.전자공학 학술대회 논문집
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    • pp.410-413
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    • 1988
  • In this paper, the real-time optical associative memory using multiple hologram which is generated with two angular multiplexed reference beams and Fourier transformed object beam in the $BaTiO_{3}$ crystal based on DFWM mechanism. When one image is recorded in the $BaTiO_{3}$ crystal, complete image can be recalled by 9 % partial input of the stored original image without any additional thresholding and optical feedback process. As an experimental result of multiple Fourier hologram which is recorded with two binary images, OHCHAS and PARKHK, we can obtain complete image recalled by 1/6 partial input of the stored image.

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Novel Interface-engineered Junction Technology for Digital Circuit Applications

  • Yoshida, J.;Katsuno, H.;Inoue, S.;Nagano, T.
    • Progress in Superconductivity
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    • 제3권1호
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    • pp.1-4
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    • 2001
  • Interface-engineered junctions with $YbBa_2$$Cu_3$$O_{7}$ as the counter electrode were demonstrated. The junctions exhibited excellent Josephson characteristics with a Josephson critical current ($I_{c}$) ranging from 0.1 mA to 8 mA and a magnetic field modulation of the $I_{c}$ exceeding 80% at 4.2 K while maintaining complete c-axis orientation of the counter-electrode layer. The$ 1\sigma$ spreads in $I_{c}$ for junctions with an average $I_{c}$ of 1-2 mA were 5-8% for 16 junctions within a chip, and 9.3% for a 100-junction array. Our dI/dV measurements suggest that a theoretical approach taking into account both a highly transparent barrier and the proximity effect is required to fully understand the Junction characteristics.ristics.

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Base-Identity Effects in Some Morphophonemic Alternations in English

  • Kim, Heeyong
    • 한국영어학회지:영어학
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    • 제2권2호
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    • pp.185-205
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    • 2002
  • Within the framework of Generalized Sympathy (GS) (Jun 1999), this paper investigates the reasons why phonological rules such as Cluster Simplification, Closed Syllable ${\ae}$-Tensing, and Belfast Dentalization overapply or underapply in Class 2 affixed words in English. According to GS, a morphologically independent word can be treated as a derived word in that it is assumed to have any possible outputs as bases to resemble. As a result, a correspondence relation is triggered between a morphologically independent word being represented as Derived (D) and any possible outputs represented as Base (B), i.e., BD-Faith. In analyses of affixed words, BA-Faith is evoked, instead of BD-Faith. Furthermore, as Benua (1997) suggests, BA-Faith is classified into two correspondence relations; $BA_1$-Faith between Base and Class 1 affixed words, and $BA_2$-Faith between Base and Class 2 affixed words. When the $BA_1$-Faith takes precedence over phonological constraints three rules misapply in Class 2 affixed words. In other words, the misapplications are driven by base-identity effects.

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Smart Solid State Syntheses of Well-Crystallized Phase Pure Mixed Oxides for Electroceramics

  • Sennat, Mamoru
    • 한국세라믹학회지
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    • 제43권11호
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    • pp.680-687
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    • 2006
  • An overview is given to optimize the solid state processes toward phase pure and well-crystallized fine particulates of mixed oxides, serving as electroceramic materials in various genres. Elevation of the reactivity and preservation of stoichiometry of the starting mixture are of universal importance. Mechanical activation is versatile for these purposes, particularly when an oxygen atom as a hinge promotes formation of hetero-bridging bonds between dissimilar cationic species prior to calcination. Case studies carried out recently in the author's laboratory are displayed and compared for ferroelectric materials, i.e. $PbMg_{1/3}Nb_{2/3}O_3$ $xPbTiO_3$(PMN-PT), $(1-y)Pb(Zn_xMg{1-x})_{1/3}$ $yNb_{2/3}O_3$ (PZN-PMN), $BaBi_2Ta_2O_9$ (BBT), $Ba(Mg_{1/3}Ta_{2/3})O_3$ (BMT), and ferromagnetics, i.e. M-, Y-, and Z-phases of Ba-hexaferrites.

Immunomodulatory Activity of Betulinic Acid by Producing Pro-Inflammatory Cytokines and Activation of Macrophages

  • Yun, Yun-Ha;Han, Shin-Ha;Park, Eun-Jung;Yim, Don-Sool;Lee, Sook-Yeon;Lee, Chong-kil;Cho, Kyung_Hae;Kim, Kyung_Jae
    • Archives of Pharmacal Research
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    • 제26권12호
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    • pp.1087-1095
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    • 2003
  • Betulinic acid (BA), a pentacyclic triterpene isolated from Lycopus lucidus, has been reported to be a selective inducer of apoptosis in various human cancer and shown anti-inflammatory and immunomodulatory properties. We postulated that BA modulates the immunomodulatory properties at least two groups of protein mediators of inflammation, interlukin-1$\beta$ (IL-1$\beta$) and the tumor necrosis factor- $\alpha$ (TNF-$\alpha$) on the basis of the critical role of the monocytes and tissue macrophages in inflammatory and immune responses. TNF-$\alpha$ and IL-1$\beta$ were produced by BA in a dose dependent manner at concentration of 0.625 and 10 $\mu$g/mL. The production of NO associated with iNOS was inhibited when treated with LPS at the concentration of 2.5 to 20 $\mu$g/mL of BA whereas COX-2 expression was decreased at 2.5 to 20 $\mu$g/mL. These modulations of inflammatory mediators were examined in LPS-stimulated RAW 264.7 cells and peritoneal macrophages. The morphology of macrophage was also examined and enhanced surface CD 40 molecule was expressed when treated BA at 0.625∼5 $\mu$g/mL with or without LPS. Furthermore, BA (20 $\mu$g/mL) enhanced apoptosis by producing DNA ladder in the RAW 264.7 cells. Our results indicated that BA induced activation of macrophage and pro-inflammatory cytokines. This may provide a molecular basis for the ability of BA to mediate macrophage, suppress inflammation, and modulate the immune response.

티탄산 바륨 스트론튬 (BaxSr1-xTiO3) 후막의 상전이온도와 가변 유전특성 (Curie Temperature and Tunable Dielectric Properties of Barium Strontium Titanate Thick Films)

  • 전소현;김인성;민복기;송재성;윤존도
    • 한국세라믹학회지
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    • 제43권7호
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    • pp.421-426
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    • 2006
  • [ $(BaSr)TiO_3$ ] thick films were prepared by tape casting method, using $BaTiO_3\;and\;SrTiO_3$ powder slurry in order to investigate dielectric properties i.e. dielectric constant, ${\varepsilon}_r$, Curie temperature, $T_c$. Grain growth within $(BaSr)TiO_3$ thick films was observed with increasing weight ratio of $BaTiO_3$. This observation can be explained by phenomena of substitution of $Sr^{2+}$ ion for $Bi^{2+}$ ion in the $BaTiO_3$ system. Also, the Curie temperature in $(BaSr)TiO_3$ thick films was shifted to lower temperature range with increasing $ SrTiO_3$. Furthermore, Curie temperature having maximum dielectric constant was in the range of $-40^{\circ}C\;to\;30^{\circ}C$, and hence sharper phase transformation occurred at Curie temperature. There occurred decrease in tunability and k-factor of $(Ba_{0.6}Sr_{0.4})TiO_3$ calculated from the dielectric constant, ${\varepsilon}_r$ above Curie temperature. In addition, above the $60^{\circ}C$, phase fixation was observed. This means that internal stress relief occurred with increasing $90^{\circ}$ domains.

LPS로 유도된 RAW264.7 염증모델에서 미후등의 항염증효과 (Anti-Inflammatory Effect of Bower Actinidia in LPS-Stimulated RAW264.7 Cells)

  • 김영준;송춘호
    • Korean Journal of Acupuncture
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    • 제30권4호
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    • pp.243-251
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    • 2013
  • Objectives : Bower Actinidia has been widely used for treatment of inflammatory diseases, such as jaundice, cystolithiasis. However, the mechanism of its anti-inflammatory activity has not been clarified. In this study, we investigated the inhibitory effect of Bower Actinidia pharmacopuncture extract(BA) on LPS-induced inflammation. Methods : The effect of BA was analyzed by ELISA, RT-PCR and Western blotting in LPS-stimulated RAW264.7 cells. Results : We found that BA suppressed not only the mRNA expression of pre-inflammatory cytokines, cyclooxygenase-2(COX-2) and inducible nitric oxide synthase(iNOS), but also the phosphorylation of ERK, JNK and p38. Conclusions : These results suggest that BA exerts an anti-inflammatory effect through the regulation of the mitogen-activated protein kinase(MAPK) pathway, thereby decreasing production of pre-inflammatory cytokines.

Development of Gradient Centrifugal Partition Chromatography Method and Its Application for the Isolation of 3,5-Dimethoxyphenanthrene-2,7-diol and Batatasin-I from Dioscorea opposita

  • Yoon, Kee-Dong;Yang, Min-Hye;Chin, Young-Won;Kim, Yoen-Jun;Kim, Hye-Ryung;Choi, Ki-Ri;Park, Ju-Hyun;Kim, Jin-Woong
    • Natural Product Sciences
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    • 제15권3호
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    • pp.144-150
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    • 2009
  • Gradient centrifugal partition chromatography (GCPC) method was developed and applied to isolate 3,5-dimethoxyphenanthrene-2,7-diol (DMP) and batatasin-I (BA-I) from the dichloromethane soluble extract of Dioscorea opposita. In this method, the lower phase of n-hexane-methanol-water system (HMW, 10 : 9 : 1, v/v) was used as a mobile phase A (MpA) and water was used as a mobile phase B (MpB). This gradient CPC method is comparable to that of reversed-phase HPLC method in that the stationary upper-phase of HMW (10 : 9 : 1 v/v) works as if it were reversed-phase silica gel due to its hydrophobic property, while the lower phase (MpA) and water (MpB) functioned as hydrophilic mobile phases. The initial condition of the mobile phase was 20% MpA/80% MpB and maintained for 150 min to obtain DMP (1.2 mg), and then MpA was increased up to 50% to elute BA-I (1.7 mg). The purities of DMP and BA-I were 94.1% and 98.3% with the recovery yields of 83% and 86%, respectively. Similar results were obtained by linear-gradient CPC. The CPC peak fractions were identified by comparing their retention time to those of authentic samples of DMP and BA-I and their spectroscopic data ($^1$H NMR and $^{13}$C NMR) to those of literature values.