• Title/Summary/Keyword: Hydrothermal conditions

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Morphological changes of $BaCO_3$ microcrystal with the synthetic conditions (합성조건에 따른 $BaCO_3$ 마이크로 결정의 형태 변화)

  • Choi, Eun-Jee;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.5
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    • pp.223-227
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    • 2009
  • $BaCO_3$ crystals with various morphology were prepared using precipitation, hydrothermal and ligand-assisted methods. An irregular structure of $BaCO_3$ microparticle was obtained by simple precipitation method from $Ba(NO_3)_2$ and $Na_2CO_3$ in aqueous solution. Hexagonal pyramidals of $BaCO_3$ were synthesized using a hydrothermal method between $Ba(NO_3)_2$ and urea. Hexagonal rods of $BaCO_3$ were also synthesized using the ligand-assisted hydrothermal method. The aspect ratio of $BaCO_3$ hexagonal rods was increased with the concentration of ligand.

Synthesis and Surface Modification of Magnesium Hydroxide by Hydrothermal Method (수열법에 의한 수산화 마그네슘의 합성과 표면개질)

  • Lee, Hae-Young;Kang, Kuk-Hyoun;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.149-158
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    • 2012
  • Magnesium hydroxide[$Mg(OH)_2$] was prepared by hydrothermal method using oleic acid as surface modifier. $Mg(OH)_2$ particles exhibit flake morphology with micrometer in size and the surface modification starts from the reaction of $C_{17}H_{33}COO^-$ group, derived from oleic acid molecule in alkaline environments. It is found that hydrothermal treatment conditions such as pH, temperature and reaction time are important for the control of the morphology and properties of surface modified magnesium hydroxide. The obtained magnesium hydroxide groups were characterized by FE-SEM, XRD, FT-IR, TGA. The dispersion in organic solution was determined by sedimentation test and compared with the result of raw $Mg(OH)_2$.

Photocatalytic and Adsorption Properties of WO3 Nanorods Prepared by Hydrothermal Synthesis (수열합성법으로 제조된 나노막대 구조 WO3의 광촉매 효과 및 염료 흡착 반응)

  • Yu, Su-Yeol;Nam, Chunghee
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.483-488
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    • 2017
  • Transition-metal oxide semiconductors have various band gaps. Therefore, many studies have been conducted in various application fields. Among these, methods for the adsorption of organic dyes and utilization of photocatalytic properties have been developed using various metal oxides. In this study, the adsorption and photocatalytic effects of $WO_3$ nanomaterials prepared by hydrothermal synthesis are investigated, with citric acid added in the hydrothermal process as a structure-directing agent. The nanostructures of $WO_3$ are studied using transmission electron microscopy and scanning electron microscopy images. The crystal structure is investigated using X-ray diffraction patterns, and the changes in the dye concentrations adsorbed on $WO_3$ nanorods are measured with a UV-visible absorption spectrophotometer based on Beer-Lambert's law. The methylene blue (MB) dye solution is subjected to acid or base conditions to monitor the change in the maximum adsorption amount in relation to the pH. The maximum adsorption capacity is observed at pH 3. In addition to the dye adsorption, UV irradiation is carried out to investigate the decomposition of the MB dye as a result of photocatalytic effects. Significant photocatalytic properties are observed and compared with the adsorption effects for dye removal.

Ore Minerals and Mineralization Conditions of Magnetite Deposits in the Janggun Mine, Korea (장군광산(將軍鑛山)의 자철석광상(磁鐵石鑛床)에서 산출(産出)되는 광석광물(鑛石鑛物)과 생성조건(生成條件))

  • Lee, Hyun Koo;Lee, Chan Hee;Song, Suckhwan
    • Economic and Environmental Geology
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    • v.29 no.1
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    • pp.1-11
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    • 1996
  • Magnetite ores of the Janggun mine are embedded in dolomitic limestone of the Janggun Limestone Formation contacting with Chunyang granite, and are closely associated with skarn minerals. Mineralization of magnetite deposits can be divided into two stages as deep-seated skarn stage and shallow hydrothermal replacement stage. Mineralogies of skarn stage consist of magnetite, pyrrhotite and base-metal sulfides, and those of hydrothermal stage is base-metal sulfides, native bismuth, bismuthinite, tetrahedrite, boulangerite, bournonite and stannite. The FeS mole % in sphalerite and As atom % in arsenopyrite range from 22.47 to 26.30 and from 31.39 to 31.66 in skarn stage, and are from 17.54 to 32.54 and 28.87 to 30.70 in hydrothermal stage, respectively. Based on mineralization characteristics, mineral assemblages, chemical compositions and thermodynamic considerations, formation temperatures, sulfur fugacities ($-logf_2$), pH and oxygen fugacity ($-logfo_2$) estimated to be from 345 to $382^{\circ}C$, from 8.1 to 9.7atm, from 6.5 to 7.2 and from 30.5 to 31.2atm in the skarn stage, respectively, and temperature and $-logfs_2$ are from 245 to $315^{\circ}C$ and from 10.4 to 13.2atm in the hydrothermal stage.

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Hydrothermal synthesis, structure and sorption performance to cesium and strontium ions of nanostructured magnetic zeolite composites

  • Dran'kov, Artur;Shichalin, Oleg;Papynov, Evgeniy;Nomerovskii, Alexey;Mayorov, Vitaliy;Pechnikov, Vladimir;Ivanets, Andrei;Buravlev, Igor;Yarusova, Sofiya;Zavjalov, Alexey;Ognev, Aleksey;Balybina, Valeriya;Lembikov, Aleksey;Tananaev, Ivan;Shapkin, Nikolay
    • Nuclear Engineering and Technology
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    • v.54 no.6
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    • pp.1991-2003
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    • 2022
  • The problem of water contamination by long-living cesium and strontium radionuclides is an urgent environmental issue. The development of facile and efficient technologies based on nanostructured adsorbents is a perspective for selective radionuclides removal. In this regard, current work aimed to obtain the nanostructured magnetic zeolite composites with high adsorption performance to cesium and strontium ions. The optimal conditions of hydrothermal synthesis were established based on XRD, SEM-EDX, N2 adsorption-desorption, VSM, and batch adsorption experiment data. The role of chemical composition, textural characteristics, and surface morphology was demonstrated. The monolayer ionexchange mechanism was proposed based on adsorption isotherm modeling. The highest Langmuir adsorption capacity of 229.6 and 105.1 mg/g towards cesium and strontium ions was reached for composite obtained at 90 ℃ hydrothermal treatment. It was shown that magnetic characteristics of zeolite composites allowing to separate spent adsorbents by a magnet from aqueous solutions.

Analysis of Earth Design Parameter and Geothermal Heat Exchanger Length in Geothermal System (지열시스템의 지중 설계요소와 지중열교환기 길이 분석)

  • Park, Jong-II;Park, Kyung Soon
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.11 no.3
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    • pp.1-6
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    • 2015
  • In this study, we analyzed t he design condition for appropriate design factor at geothermal system design documents. It is intended to provide the proper information of geothermal system design condition when construct new building, designer can use design conditions more efficiently. Therefore, it is possible to plan for domestic geothermal system, through utilization at design element, to provide as a good information that can predict the approximate underground condition. Thus, provided the basic design conditions that can predict the capacity of the geothermal system. It will be the first step to solve the problem.

Analysis of City Gas Consumption by Borough and Usage in Busan (부산시 구별 용도별 도시가스 소비 특성 분석)

  • Park, Yool;Park, Jong-Il
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.7 no.1
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    • pp.65-71
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    • 2011
  • Recently, central and local governments of Korea have established and implemented various energy policies such as making energy map of city level and establishment of environment friendly city plan to materialize low carbon green city. To implement effectively these policies, however, conditions of energy consumption by each administrative district and each usage have to be verified exactly. This study is aimed to suggest a basic data for planing energy policy and energy demand prediction of city level by analyzing energy consumption unit and conditions of city gas by borough and usage in Busan.

The Effects of Operational Conditions of Cooling Water System on Energy Consumption for Central Cooling System (냉각수 계통의 운전변수가 중앙냉방시스템의 에너지소비량에 미치는 영향)

  • Ahn, Byung-Cheon
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.13 no.4
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    • pp.8-13
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    • 2017
  • The effects of operational conditions of cooling water system on energy consumption for central cooling system are researched by using TRNSYS program. Cooling tower water pump flow rate, cooling tower fan flow rate, and condenser water temperature with various dry-bulb and wet-bulb temperatures are varied and their effects on total and component power consumption are studied. If the fan maximum flow rates of cooling tower is decreased, cooling tower fan and total power consumptions are increased. If the cooling tower water pump maximum flow rates is decreased, chiller and total power consumptions are increased. If condenser water set-point temperature is increased, chiller power consumption is increased and cooling tower fan power consumption is decreased, respectively.

The Characteristics of Energy Consumption with Operational Conditions for the Central Cooling System (냉방시스템의 운전조건에 따른 에너지 소비특성 연구)

  • Park, Gi-Tae;Ahn, Byung-Cheon
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.15 no.4
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    • pp.39-45
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    • 2019
  • The operational conditions such as cooling tower water pump flow rate, cooling tower fan flow rate, and chiller capacity in heat source equipment, and supply air temperature and chilled water temperature in air conditioner are considered to study the effects on energy consumption for central cooling system by using TRNSYS program. As a result, the optimal values of supply air temperature and chilled water temperature for minimal total energy consumption are 12℃ and 8℃. And if maximum values of cooling tower water pump and fan flow rate is decreased from 100% to 40%, energy consumptions are increased 170MJ/day and 63.2MJ/day, respectively.

Study on the Performance of a Variable Speed Cascade Heat Pump under Various Operating Conditions (운전조건에 따른 가변속 캐스케이드 열펌프의 성능 특성 연구)

  • Jeong, Kwangmoo;Choi, Jong Min
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.9 no.2
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    • pp.1-7
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    • 2013
  • Most researches done on heat pumps have been on heat pumps for refrigeration, cooling and heating. There is therefore the need for more research on hot water heat pumps, especially for high temperature. Even though the cascade heat pump cycle has a great potential more efficient hot water generation even at low evaporating temperatures, it has been researched least for this purpose. In this study, the heating performance of a variable speed cascade heat pump was investigated by varying operating conditions. For the same heating capacity values, it was found that increasing the low stage compressor speed was more suitable for enhancing the performance of the system to get a higher temperature.