• Korean Journal of Materials Research
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• v.21 no.8
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• pp.415-418
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• 2011

Tin (IV) dioxide ($SnO_2$) has attracted much attention due to its potential scientific significance and technological applications. $SnO_2$ nanoparticles were prepared under low temperature and pressure conditions via precipitation from a 0.1 M $SnCl_4{\cdot}5H_2O$ solution by slowly adding $NH_4OH$ while rapidly stirring the solution. $SnO_2$ nanoparticles were obtained from the reaction in the temperature range from 130 to $250^{\circ}C$ during 6 h. The microstructure and phase of the synthesized tin oxide particles were studied using XRD and TEM analyses. The average crystalline sizes of the synthesized $SnO_2$ particles were from 5 to 20 nm and they had a narrow distribution. The average crystalline size of the synthesized particles increased as the reaction temperature increased. The crystalline size of the synthesized tin oxide particles decreased with increases in the pH value. The X-ray analysis showed that the synthesized particles were crystalline, and the SAED patterns also indicate that the synthesized $SnO_2$ nanoparticles were crystalline. Furthermore, the morphology of the synthesized $SnO_2$ nanoparticles was as a function of the reaction temperature. The effects of the synthesis parameters, such as the pH condition and reaction temperature, are also discussed.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.635-635
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• 2013

We report three-dimensional polycrystalline anatase TiO2 structures (3D a-TiO2) for environmental and bio-medical applications. The 3D a-TiO2 was synthesized without thermal treatment by the growth of rod-like polycrystals on Degussa P25 (P25) via low temperature (< $85^{\circ}C$) modified alkali hydrothermal processing. X-ray diffraction and high-resolution transmission electron microscopic results showed that the rod-like polycrystals of 3D a-TiO2 possessed the highly anatase nanostructures. The photocatalytic activity of 3D a-TiO2 was found to be 2.2 times higher than that of P25. The recyclability of the 3D a-TiO2 was found to be high: the decolorization rate was 94.8% of the initial value after fifteen cycles. In addition, 3D a-TiO2 exhibited excellent antibacterial activities for the sterilization of gram-negative Escherichia coli (E. coli) and gram-positive Staphylococcus aureus (S. aureus). Even at the 10th recycled use, more than 98.4% of E. coli and S. aureus can be killed. These results indicated that 3D a-TiO2 might have utility in several promising applications such as photocatalytic water/air purification and bactericidal agents.

• Journal of Soil and Groundwater Environment
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• v.19 no.1
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• pp.1-7
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• 2014

When processing the biomass by Hydrothermal carbonization (HTC), a slow pyrolysis process, it produces bio-gas, biooil, and biochar. Among these end products, biochar is known for isolating or storing carbon and being used as a soil amendment. In this study, the characteristics of biochar generated by HTC at $250^{\circ}C$ for 1 hour, 2 hours, 3 hours, and 20 hours with synthetic food wastes and wood wastes were analyzed for potential uses in soil contaminated with heavy metals. The yield of biochar (weight %) increased when the ratio of wood wastes increased and showed a decreasing tendency as reaction time increased. Elemental analysis of biochar based on various conditions showed a maximum of 70% carbon (C) content. The carbon content showed an increasing tendency with the increase of wood wastes. Iodine adsorption test was peformed to determine the optimum reaction condition, which was 15% wood waste for mixing ratio and 2 hours for reaction time. Using biochar generated at the optimum condition, its capability of adsorbing heavy metals (Cd, Cu, Pb, Zn, Ni) was evaluated. It was concluded that lead (Pb) was removed efficiently while zinc (Zn) and nickel (Ni) were hardly adsorbed by biochar.

• Economic and Environmental Geology
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• v.37 no.3
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• pp.277-290
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• 2004

The trench exploration was carried out on the quartz veins of the Tanggung area of Java, Indonesia. The chemical values of quartz vein samples for hydrothermal alteration zones in this area are defined such as over values of Ag : 2∼190ppm(Celak); 2∼41 ppm(Cilangkap), Au : 21∼17,400 ppb(Celak); 24∼91,100 ppb(Cilangkap), Cu : 9∼3,340 ppm(Celak); 2∼l,600 ppm(Cilangkap), Pb : 60∼52,900 ppm(Celak); 16∼2,960 ppm(Cilangkap), Zn : 12∼13,950 ppm(Celak); 14∼1,520 ppm(Cilangkap), respectively. Two drilling areas, Mt. Subang area(Celak area) and Mt. Cilangkap area(Cilangkap area), have been chosen based on the factors such as, geologic settings associated with gold mineralizations, highly anomalous areas revealed by geochemical survey such as chemical analysis of ore and soil, trench exploration, statistical processing of the chemical analysis, and petrographic studies of igneous rocks related to its mineralization, and graphic presentation of anomalous areas.

• Transactions on Electrical and Electronic Materials
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• v.11 no.1
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• pp.1-10
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• 2010

This is an overview paper reporting our most recent work on processing and microstructure of nano-structured oxides and their photoluminescence and photo-catalysis properties. Zinc oxide and related transition metal oxides such as vanadium pentoxide and titanium dioxide were produced by a combination of magnetron sputtering, hydrothermal growth and atmosphere controlled heat treatment. Special morphology and microstructure were created including nanorods arrays, core-brushes, nano-lollipops and multilayers with very large surface area. These structures showed special properties such as much enhanced photoluminescence and chemical reactivity. The photo-catalytic properties have also been promoted significantly. It is believed that two factors contributed to the high reactivity: the large surface area and the interaction between different oxides. The transition metal oxides with different band gaps have much enhanced photoluminescence under laser stimulation. Use of these complex oxide structures as electrodes can also improve the energy conversion efficiency of solar cells. The mixed oxide complex may provide a promising way to high-efficiency photo emitting materials and photo-catalysts.

• Korean Journal of Remote Sensing
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• v.2 no.2
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• pp.79-94
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• 1986

TM data, which have better resolution in spatial and spectral than MSS data, were used for this study, and several Image Processing Techniques (IPT) were examined for finding the best IPT to fit to lineament extraction and mineralized zone mapping. The Ryeongnam area was selected as test area, because the area is one of major mineralized zones in Korea and its hydrothermal alteration zone is wider and deeper than other areas. The spatial filtering method is most optimum one for limeament extraction: that is, the directional spatial filtering is most efficient to detect N-S, E-W direction lineaments on the image, and the high boost filtering can be applied for mapping all direction lineaments. The ratio method was selected for detecting altered zone. It is possible to make several tens combinations in ratio with 7 bands of TM data, but considering spectral characteristics of each band of TM to the geological meterials and vegetation, the band 4/band 3(A), band 5/band 7(B), and B/A ratio methods were chosen among them. The 5/7 ratio image did not show clearly the altered area due to noise from vegetation cover, so the 4/3 ratio imae was used for trying to decrease the effect of vegetation. As a result the B/A ratio image showed quite nicely the altered zone of the test area. In conclusion, the spatial filtering is the best image processing techniques for lineament mapping, and the B/A ratio image in TM data is useful for the mineralized zone mapping.

• Korean Journal of Materials Research
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• v.21 no.2
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• pp.111-114
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• 2011

As a growth-template of ZnO nanorods (NR), a hexagonal $\beta-Ni(OH)_2$ nanosheet (NS) was synthesized with the low temperature hydrothermal process and its microstructure was investigated using a high resolution scanning electron microscope and transmission electron microscope. Zinc nitrate hexahydrate was hydrolyzed by hexamethylenetetramine with the same mole ratio and various temperatures, growth times and total concentrations. The optimum hydrothermal processing condition for the best crystallinity of hexagonal $\beta-Ni(OH)_2$ NS was determined to be with 3.5 mM at $95^{\circ}C$ for 2 h. The prepared $Ni(OH)_2$ NSs were two dimensionally arrayed on a substrate using an air-water interface tapping method, and the quality of the array was evaluated using an X-ray diffractometer. Because of the similarity of the lattice parameter of the (0001) plane between ZnO (wurzite a = 0.325 nm, c = 0.521 nm) and hexagonal $\beta-Ni(OH)_2$ (brucite a = 0.313 nm, c = 0.461 nm) on the synthesized hexagonal $\beta-Ni(OH)_2$ NS, ZnO NRs were successfully grown without seeds. At 35 mM of divalent Zn ion, the entire hexagonal $\beta-Ni(OH)_2$ NSs were covered with ZnO NRs, and this result implies the possibility that ZnO NR can be grown epitaxially on hexagonal $\beta-Ni(OH)_2$ NS by a soluble process. After the thermal annealing process, $\beta-Ni(OH)_2$ changed into NiO, which has the property of a p-type semiconductor, and then ZnO and NiO formed a p-n junction for a large area light emitting diode.

• Journal of Ocean Engineering and Technology
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• v.31 no.1
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• pp.69-79
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• 2017

This paper presents the operations of a multi-beam echo sounder (MBES) installed on the deep-sea remotely operated vehicle (ROV) Hemire. Hemire explored hydrothermal vents in the Forecast volcano located near the Mariana Trench in March of in 2006. During these explorations, we acquired profiling points on the routes of the vehicle using the MBES. Information on the position, depth, and attitude of the ROV are essential to obtain higher accuracy for the profiling quality. However, the MBES installed on Hemire does not have its own position and depth sensors. Although it has attitude sensors for roll, pitch, and heading, the specifications of these sensors were not clear. Therefore, we had to merge the high-performance sensor data for the motion and position obtained from Hemire into the profiling data of the MBES. Then, we could properly convert the profiling points with respect to the Earth-fixed coordinates. This paper describes the integration of the MBES with Hemire, as well as the coordinate conversion between them. Bathymetric maps near the summit of the Forecast volcano were successfully collected through these processes. A comparison between the bathymetric maps from the MBES and those from the Onnuri Research Vessel, the mother ship of the ROV Hemire for these explorations, is also presented.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.32 no.5
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• pp.537-541
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• 1999

Fish heads of the main by-product is fishery processing were treated to extract nutrients by heating the fish heads with 1.5 or 3.0 times added water during 9, 12 or 15 hours. The yield, chemical compositions and physical properties of the hydrothermal extracts were studied. The yield was increased with the amount of water added and the extracting hours. The extract contained about $80\%$ protein in solid basis, but has no lipid. In essential amino acid, glutamic acid was most abundant and Iysine was abundant. In free amino acid, $\delta$-hydroxylysine and L-histidine in Cypyrinus carpio linnaeus had 5 times more than those in Onchorhynchus keta, The solution of the extracts was known as Newtonian fluid and the color of the extracts showed lower whiteness, higher redness and higher yellowness.

• Nano
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• v.13 no.12
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• pp.1850141.1-1850141.11
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• 2018

Sodium ion batteries based on the more sodium source reserve than that of lithium have been designed as promising alternatives to lithium ion batteries. However, several problems including unsatisfied specific capacity and serious cyclic stability must be solved before the reality. One of the effective approaches to solve the abovementioned problems is to search for suitable anode materials. In this work, we designed and prepared $FeSe_2$ nanoflakes via a simple hydrothermal method which can be adjusted in composition by Fe precursor. As a potential anode for sodium storage, the optimized $FeSe_2$ electrode was further evaluated in different electrolytes of $NaClO_4$ in propylene carbonate/fluoroethylene carbonate and $NaCF_3SO_3$ in diethylene glycol dimethyl ether. The capacity was about $470mAh\;g^{-1}$ and $535mAh\;g^{-1}$ at $0.5A\;g^{-1}$, respectively, in the voltage between 0.5 V and 2.9 V in the cycle of stabilization phase. Superior performance both in capacity and in stability was obtained in ether-based electrolyte, which affords the property without plugging the intermediates of transition metal dichalcogenides during charge/discharge processes.