• Journal of Hydrogen and New Energy
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• v.22 no.4
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• pp.520-526
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• 2011

In recent years, it is very important that hydrogen storage system is safe for user in any circumstances in case of crash and fire. Because the hydrogen vehicle usually carry high pressurized cylinders, it is necessary to do safety design for fire. The Global Technical Regulation (GTR) has been enacted for localized and engulfing fire test. High pressure hydrogen storage system of fuel cell electrical vehicles are equipped with Thermal Pressure Relief Device (TPRD) installed in pressured tank cylinder to prevent the explosion of the tank during a fire. TPRDs are safety devices that perceive a fire and release gas in the pressure tank cylinder before it is exploded. In this paper, we observed the localized and engulfing behavior of tank safety, regarding the difference of size and types of the tanks in accordance with GTR.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.1
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• pp.65-73
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• 2012

Nowadays, the concern on the environmental load of bleaching process gave rise to the process of ECF(elemental chlorine free) and TCF(total clorine free). These sequences are based on oxygen-derived compounds such as oxygen, ozone, and hydrogen peroxide which is used as a typical eco-friendly bleaching agent. In this study, paper mulberry pulp was bleached with hydrogen peroxide and some bleaching process were accompanied with ultrasonication in order to increase the bleaching efficiency. The best bleaching efficiency of paper mulberry pulp was obtained in the condition of hydrogen peroxide and ultrasonication(20 kHz) bleaching system at $45^{\circ}C$ for 30 min. The brightness and kappa number of paper mulberry pulp were gained to 5.09% and 3.52 respectively. and yield was slightly loosed to 2%. Therefore, the efficiency of hydrogen peroxide and ultrasonication bleaching system of paper mulberry pulp was superior to the conventional hydrogen peroxide bleaching system. Magnesium sulfate acted as a bleaching stabilizer for the increasement of yield. As a result, the yield and viscosity were increased to 2.2% and 12% respectively.

• Journal of Electrochemical Science and Technology
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• v.10 no.3
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• pp.302-312
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• 2019

The voltage produced from the salinity gradient in reverse electrodialysis (RED) increases proportionally with the number of cell pairs of alternating cation and anion exchange membranes. Large-scale RED systems consisting of hundreds of cell pairs exhibit high voltage of more than 10 V, which is sufficient to utilize water electrolysis as the electrode reaction even though there is no specific strategy for minimizing the overpotential of water electrolysis. Moreover, hydrogen gas can be simultaneously obtained as surplus energy from the electrochemical reduction of water at the cathode if the RED system is equipped with proper venting and collecting facilities. Therefore, RED-driven water electrolysis system can be a promising solution not only for sustainable electric power but also for eco-friendly hydrogen production with high purity without $CO_2$ emission. The RED system in this study includes a high membrane voltage from more than 50 cells, neutral-pH water as the electrolyte, and an artificial NaCl solution as the feed water, which are more universal, economical, and eco-friendly conditions than previous studies on RED with hydrogen production. We measure the amount of hydrogen produced at maximum power of the RED system using a batch-type electrode chamber with a gas bag and evaluate the interrelation between the electric power and hydrogen energy with varied cell pairs. A hydrogen production rate of $1.1{\times}10^{-4}mol\;cm^{-2}h^{-1}$ is obtained, which is larger than previously reported values for RED system with simultaneous hydrogen production.

• Applied Chemistry for Engineering
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• v.34 no.3
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• pp.307-312
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• 2023

In this study, a catalytic oxidation-heat recovery system was designed that can remove unreacted with a concentration of about 1% to 6% in the exhaust gas of hydrogen fuel cells and recover heat to ensure safety in the hydrogen economy. The safety system was devised by filling hydrogen oxidation catalysts at room temperature that can remove unreacted hydrogen without any energy source, and an exhaust-heat recovery device was integrated to efficiently recover the heat released from the oxidation reaction. Through CFD analysis, variations in pressure and fluid within the system were shown depending on the filling conditions of the hydrogen oxidation system. In addition, it was found that waste heat could be recovered by optimizing the temperature of the exhaust gas, flow rate, and pressure conditions within the heat recovery system and securing hot water above 40 ℃ by utilizing the exhaust gas oxidation heat source above 300 ℃. Through this study, it was possible to confirm the potential of utilizing hydrogen processes, which are applied in small to medium-sized systems such as hydrogen fuel cells, as a safety system by evaluating them at a pilot scale. Additionally, it could be a safety guideline for responding to unexpected hydrogen safety accidents through further pilot-scale studies.

• Journal of Hydrogen and New Energy
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• v.34 no.3
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• pp.297-306
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• 2023

The frequency of fatal accidents that can occur at hydrogen refueling station was compared with the risk criterion for the general public suggested by the health and safety executive. If hydrogen refueling station meets the accident prevention facility standards presented in KGS Code FP216/217, it was confirmed that the risk of hydrogen refueling station was not at an unacceptable (intolerable) risk level. However, the risk of hydrogen refueling station due to small leak was analyzed as low as reasonably practicable. Therefore, methods for improving the safety instrumented function of hydrogen refueling station were reviewed. It was confirmed that the risk of hydrogen refueling station can be affected by the number of installed safety instrumentation system components, redundant architecture, mission time, proof test interval, etc. And methods for maintaining the risk of hydrogen refueling station at an acceptable risk level have been proposed.

• Journal of the Korea Computer Graphics Society
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• v.15 no.2
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• pp.35-40
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• 2009

In this paper, we present the web3D-based virtual reality(VR) system for the safety education of the hydrogen station. Currently, hydrogen is considered the next generation energy, and hydrogen station is a part of core infrastructure in hydrogen industry. However, the experience of safety equipment in the hydrogen station is limited to the non-experts, because it is a restricted area in general industry. Therefore, using the event driven method, we develop the VR system to transfer the information of hydrogen station to the non-experts. Using our system, user experiences the safety concerns in the hydrogen station, and also learn the informations of hydrogen energy.

• Journal of Hydrogen and New Energy
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• v.24 no.2
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• pp.128-135
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• 2013

The nuclear fuel cycle plant is composed of various subsystems such as a fuel storage and delivery system (SDS), a tokamak exhaust processing system, a hydrogen isotope separation system, and a tritium plant analytical system. Korea is sharing in the construction of the International Thermonuclear Experimental Reactor (ITER) fuel cycle plant with the EU, Japan, and the US, and is responsible for the development and supply of the SDS. Hydrogen isotopes are the main fuel for nuclear fusion reactors. Metal hydrides offer a safe and convenient method for hydrogen isotope storage. The storage of hydrogen isotopes is carried out by absorption and desorption in a metal hydride bed. These reactions require heat removal and supply respectively. Accordingly, the rapid storage and delivery of hydrogen isotopes are enabled by a rapid cooling and heating of the metal hydride bed. In this study, we designed and manufactured a vertical-type hydrogen isotope storage bed, which is used to enhance the cooling performance. We present the experimental details of the cooling performances of the bed using various cooling parameters. We also present the modeling results to estimate the heat transport phenomena. We compared the cooling performance of the bed by testing different cooling modes, such as an isolation mode, a natural convection mode, and an outer jacket helium circulation mode. We found that helium circulation mode is the most effective which was confirmed in our model calculations. Thus we can expect a more efficient bed design by employing a forced helium circulation method for new beds.

• Journal of the Korean Institute of Gas
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• v.25 no.6
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• pp.85-91
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• 2021

In January 2019, the Korean government announced the 「Hydrogen Economy Activation Roadmap」 to be a world-class leading country in Hydrogen economy. Korea has established a strategy that can lead the hydrogen economy with its strong points of 'hydrogen car' and 'fuel cell'. As a part of that, a target of supplying hydrogen vehicle charging stations to 310 by 2022 and 1,200 by 2040 was established. In line with this, Korea Gas Safety Corporation will operate a pre-consulting system of hydrogen vehicle charging station in February 2021 to solve in advance construction delays due to various on-site problems according to safety standards during the construction stage to build a hydrogen refueling station with a sense of speed. This paper is to find out about the pre-consulting system and to analyze its effects.

• Journal of Navigation and Port Research
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• v.44 no.4
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• pp.283-290
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• 2020

BOG (Boil Off Gas) generation is unavoidable in the liquefied hydrogen carrier, and proper measures are necessary to prevent pressure problems inside the cargo tank. The BOG can be used as propulsion fuel for ships, and the remaining parts used for propulsion must be effectively managed, such as in the form of reliquefying or burning. This study proposes an BOG reliquefaction system optimized for a 160,000 m3 liquefied hydrogen carrier with a hydrogen propulsion system. The system comprises a hydrogen compression and helium refrigerant section, and increases the efficiency by effectively using the cold energy of the BOG discharged from the cargo tank. In this study, the system was evaluated through the exergy efficiency and SEC (Specific Energy Consumption) analysis according to the rate of the reliquefaction of the BOG while the hydrogen BOG with a supply temperature of -220℃ entered the reliquefaction system. As a result, it showed SEC of 4.11 kWh/kgLH2 and exergy efficiency of 60.1% at the rate of reliquefaction of 20%. And the parametric study of the effects of varying the hydrogen compression pressure, inlet temperature of the hydrogen expander, and the feed hydrogen temperature was conducted.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2005.06a
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• pp.239-245
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• 2005

The reduction of heat transfer rate to the stored liquid hydrogen from outside condition is extremely important to keep the liquid hydrogen longer. In this paper the highly efficient support system for the liquid hydrogen storage vessel was newly developed and analysed. The support system was composed of a spherical ball in the center of supporter to reduce the heat transfer area, with its above and below supporting blocks which are the SUS and PTFE blocks inserted in the SUS tube. The heat transfer rate and temperature distribution of the support system were evaluated by FLUENT, and the thermal stress and strain were estimated by ANSYS software. The results showed that the heat transfer rate from outer vessel to inner one was extremely decreased compared with the common method which is simply SUS tubes inserted between inner and outer tanks. The thermal stress and strain were obtained well below the limited values. As a result, it was the most efficient support system of storage vessel for liquid hydrogen and most cryogenic fluids.