• Title/Summary/Keyword: Hydrogen mixtures

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Prediction of Damage Area due to Explosion of LNG-Hydrogen Mixed Gas (도시가스-수소 혼합가스의 누출사고 영향범위 분석)

  • Chan-sik, Yoon;Jin-du, Yang;Gil-soo, Na;Sung-Hyun, Im;Ki-young, Kim;Eun-ki, Choi
    • Explosives and Blasting
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    • v.40 no.4
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    • pp.27-34
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    • 2022
  • The government is promoting various policies to reduce greenhouse gas emissions for carbon neutrality, one of the key tasks is to revitalize the hydrogen economy. As one of these policies the government has formulated a plan to incorporate hydrogen into existing city gas pipes, and aims to commercialize 20% hydrogen mixing by 2026. In preparation for the commercialization of city gas and hydrogen mixture, this study quantitatively predicts the scale of damage and the range of impact in the event of leakage of these two gas mixtures. The quantitative damage prediction method is to calculate the damage conversion distance through the calculation of the TNT equivalent by setting the leakage amount of the gas mixture in the event of an accident under a virtual scenario.

Structure and Mechanical Properties of Si Incorporated Diamond-like Carbon Films Prepared by PACVD

  • Kim, Myoung-Geun;Park, Jun-Youp;Lee, Kwang-Ryeol;Eun, Kwang-Yong
    • The Korean Journal of Ceramics
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    • v.3 no.2
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    • pp.101-104
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    • 1997
  • Although tribological behavior of Si incorporated DLC films have been intensely investigated, their mechanical properties were not consistent among previous publications. The present work reported the structural change by adding Si, and their effects on the mechanical properties. Si incoporated DLC films were deposited using mixtures of benzene and diluted silane with hydrogen of various volume fractions. We could obtain the films of $X_{si}$ (defined by the Si fraction without considering hydrogen) ranging from 0.01 to 0.21, and found that the mechanical properties of the films changed significantly in the range less than $X_{si}=0.06$. In this range, the hardness and stress increased with Xsi. For higher content of Si, the hardness and stress showed saturated behavior with $X_{si}$. This behavior was discussed in terms of the changes in atomic bond structures.

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Synthesis of Nanostructured Fe-Co Alloy Powders from Metal Salts

  • Lee, Young-Jung;Lee, Jea-Sung;Seo, Young-Ik;Kim, Young-Do
    • Journal of Powder Materials
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    • v.13 no.5 s.58
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    • pp.336-339
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    • 2006
  • Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as pain size (or particle size), internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary fur a significant improvement in magnetic properties. In the present work, nanostructured Fe-Co alloy powders with a grain size of 50 nm were successfully fabricated from the powder mixtures of (99.9% purity) $FeCl_2$ and $CoCl_2$ by chemical solution mixing and hydrogen reduction.

Fabrication and Magnetic Properties of Nanostructured Fe-Co Alloy Powder (나노 구조 Fe-Co 합금분말의 제조 및 자성특성)

  • 이백희;안봉수;김대건;김영도
    • Journal of Powder Materials
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    • v.9 no.3
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    • pp.182-188
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    • 2002
  • Conventional Fe-Co alloys are important soft magnetic materials that have been widely used in industry. Compared to its polycrystalline counterpart, the nanostructured materials have showed superior magnetic properties, such as higher permeability and lower coercivity due to the single domain configuration. However, magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as grain size, internal strain and crystal structure. Thus, studies on synthesis of nanostructured materials with controlled microstructure are necessary for a significant improvement in magnetic properties. In the present work, starting with two powder mixtures of Fe and Co produced by mechanical alloying (MA) and hydrogen reduction process (HRP), differences in the preparation process and in the resulting microstructural characteristics will be described for the nano-sized Fe-Co alloy particles. Moreover, we discuss the effect of the microstructure such as crystal structure and grain size of Fe-Co alloys on the magnetic properties.

Biofilter를 이용한 축산 ${\cdot}$ 분뇨 중의 암모니아와 황화수소의 동시 제거

  • Gang, Yeom-Seok;Hwang, Jae-Ung;Jang, Seok-Jin;Park, Seong-Hun
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.516-519
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    • 2000
  • Lab-scale biofilter was studied for the simultaneous removal of ammonia and hydrogen sulfide in gas mixtures. Compost and polyurethane foam were used as packing materials (50 : 50) and activated sludge from a wastewater treatment plant was innoculated initially. When tested under varying inlet concentrations and empty bed residence time(EBRT), up to 80 ppmv of ammonia and 40 ppmv of hydrogen sulfide could be removed completely at an EBRT of 30 sec. The pH was found to be the key factor governing the biofilter performance.

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Influence of Solvents on Rates of Reactions of 2,4-Dinitro Substituted Halobenzenes with Substituted Anilines (Ⅱ) (2,4-이니트로할로벤젠과 치환된 아닐린의 반응속도에 대한 용매효과 (제2보))

  • Hai Whang Lee;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.22 no.1
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    • pp.7-11
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    • 1978
  • The reactions of 2,4-dinitroiodobenzene with para subtituted anilines in acetonitrile-methanol binary solvent mixtures have been studied. Rate constants for reactions in methanol rich solvents are greater than for reactions in acetonitrile rich solvents. Kinetic results show that the bond formation step is rate determining in the solvent system studied. The solvent effect can be explained by stabilization of the transition state by formation of hydrogen bond between oxygen atom of methanol and hydrogen atom of aniline.

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Preparation of Amorphous Silicon by Sputtering in Silane (사이렌 기체속에서 스펏터한 비정질 규소의 성질)

  • Kim, Ki-Wan
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.16 no.5
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    • pp.34-41
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    • 1979
  • In the work reported here we have sputtered from silicon targets in argon-silane mixtures using undoped n-type and p-type targets. Doped films have been produced, but the doping efficiency is extremely low. It appears that the dopant atoms are able to satisfy their natural valencies and are therefore not electrically active. Infra-red absorption spectroscopy has been used to establish the hydrogen bonding in the films. No correlation has been found between the nature of the hydrogen bonding in the film and the electrical properties.

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Characterizations of Diamond-Like Carbon Films Prepared by the Plasma Enhanced Chemical Vapor Deposition Method (플라즈마 화학 기상 증착법으로 제작된 Diamond-Like Carbon 박막의 특성)

  • 김종탁
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.6
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    • pp.465-471
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    • 1998
  • Diamond-like carbon (DLC) films have been prepared by means of the plasma enhanced chemical vapor deposition (PECVD) method using vertical-capacitor electrodes. The deposition rata in our experiment is relatively small compared with that in the conventional PECVD methods, which implies that the accumulation of the neutral $CH_n$ radicals on the substrates due to the gravitational movement may not contribute to the deposition of DLC films. The hardness and the transparency were measured as a function of the ratio of the partial pressure of $CH_4-H_2$ mixtures or the hydrogen contents of specimens. The coefficients of friction between DLC films and a $Si_3N_4$ tip measured by using a lateral force microscope are in the range of 0.024 to 0.033 which depend on the hydrogen contents in DLC, and the surface roughness depends mainly on the deposition rate. The optical gaps increase with increasing the hydrogen contents. DCL films deposited on Pt-coated Si wafers show the stable emission characteristics, and the turn-on fields are in the range of 11 to 20 $V/\mu$m.

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Micro Structures and Magnetic Properties of Nanostructured Fe-Co Alloy Powders Produced by Hydrogen Reduction Process (수소환원법으로 제조된 나노구조 Fe-Co 합금분말의 미세구조 및 자성특성)

  • An, Bong-Su;Lee, Baek-Hui;Lee, Gyu-Hwan;Kim, Yeong-Do
    • Korean Journal of Materials Research
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    • v.12 no.6
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    • pp.488-492
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    • 2002
  • Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as grain size, internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary for a significant improvement in magnetic properties. It is well known that when Fe-Co alloy undergoes ordering transformation, soft magnetic properties could be obtained. There are many reports that the magnetic properties of the materials can be changed with variation of grain size. In the present work, nanostructured Fe-50at.%Co alloy powder produced by hydrogen reduction process (HRP) starting with two oxide powder mixtures of $Fe_2O_3\;and\; Co_3O_4$. The mean grain size of the HRP powders was about 40 nm and coercivity of the: powders was about 43 Oe.