• Title/Summary/Keyword: Hydrogen content

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Evaluation of Structural Safety and Leak Test for Hydrogen Fuel Cell-Based Truck Storage Systems (수소트럭 수소저장시스템에 대한 구조안전성 및 기밀성능평가)

  • Kim, Da-Eun;Yeom, Ji-Woong;Choi, Sung-Joon;Kim, Young-Kyu;Cho, Sung-Min
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.11
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    • pp.1-7
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    • 2020
  • Recently, hydrogen has gained considerable attention as an eco-friendly fuel, which helps in reducing carbon dioxide content. Specifically, there is a growing interest in vehicles powered by a hydrogen fuel cell, which is spotlighted as an environmental-friendly alternative. A hydrogen transport system, fuel cell system, fuel supply system, power management system, and hydrogen storage system are key parts of a hydrogen fuel cell truck. In this study, a hydrogen storage system is built and analyzed. The expansion length of the storage vessel at maximum operating pressure (87.5 MPa) was calculated with ABAQUS, and then the optimized system was designed and built. The leak and bubble tests were performed on the built storage system. The leakage of the system was measured to be under 5 cc/hr. Hence, it can be used as a research test for the safety evaluation of leading systems of hydrogen fuel-powered commercial vehicles.

Studies on the proteinase in Takjoo mashes during the process of brewing (탁주료중의 단백질분해효소에 관한 연구)

  • 홍순우;하영칠;민경희
    • Korean Journal of Microbiology
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    • v.7 no.3
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    • pp.115-124
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    • 1969
  • The mash of Takjoo, Korean flour wine, is fermented through two brewing processes ; the primary brewing process to saccharify and the main one to produce ethyl alcohol. The activities of acid proteinase (pH3), weak acid proteinase (pH 6), and alkaline proteinase (Ph 80 on the processes are determined with time by the Folin phenol method as a strength of casein digestion. Hydrogen ion concentration, the content of total organic acids, protein, free amino acids and oligopeptides, which effect the activities of proteinase, are also measured. The results are briefly summarized as follows : 1. In general, the activities of acid proteinase and weak acid proteinase in the mesh of primary brewing process are stronger than those in main brewing process. 2. The activities of acid proteinase are remarkably stronger than those of weak acid proteinase in both processes. It reveals that they decrease slowly through the fermentation. Activities of alkaline proteinase are weaker than others. 3. As the raw materials are mixtured, the total amount of organic acids is equivalent to 0.150 mg/ml acetic acid in the mesh of primary brewing process and 0.02 mg/ml acetic acid in the main one. They increase gradually with time. 4. Hydrogen ion concnetration shows 3.9 in the mesh of main brewing process and 3.28 in the primary one. They increase to the maximum in 60-72 hrs., and decrease since 108 hrs. 5. The content of crude protein shows 66.90mg/ml in the mesh of main brewing process, while shows 64.29mg/ml in the mesh of primary one. they decrease slowly with time. it seems that a small content of crude protein, as a substrate, converts into amino acids and soluble nitrogen compounds by proteinase. 6. The content of free amino acids and oligopeptides shows 0.36 mg/ml in the mesh of primary brewing process and 0.24mg/ml in the main brewing process. It is evident that the reason they increase continuously through the fermentation is the effect of proteinase. 7. According to the results, the strong activities of proteinase in primary brewing process has been derived from the decrease of hydrogen ion concentration due to the production of organic acids.

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Induction Effect of Biotic and Chemical Elicitors Treatment for the Increase of Essential Oil Content from Trees (수엽(樹葉) 정유함량에 미치는 생물.화학적)

  • Kang, Ha-Young;Choi, In-Gyu;Lee, Sung-Suk
    • Korean Journal of Food Science and Technology
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    • v.34 no.1
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    • pp.8-12
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    • 2002
  • In order to artificially increase the contents of essential oils from 4 different trees by inducing with elicitors, 5 kinds of chemical elicitors and 4 kinds of biotic elicitors were selected. Before treatment, the contents of essential oils from Japanese Cypress (Chamaecyparis obtusa), Sawara cypress (Chamaecyparis pisifera), Japanese Red Pine (Pinus densiflora), and Korean Pine (Pinus koraiensis) were 2.0, 1.6, 0.4, and 0.7 percent, respectively, and the maximum content of essential oils from all species were reached in July. By most of elicitors, the essential oil content was generally increased after 6 months later, but some of elicitors did not affect the content of essential oil. Finally, the appropriate inducers for artificially increasing the essential oil were respectively selected depending on each species; Schizophyllum commune Fries for Japanese Red Pine and Japanese Cypress, hydrogen peroxide for Korean Pine, and ${\beta}-pyridone$ for Sawara cypress. Especially, hydrogen peroxide and ${\beta}-pyridone$ could be wide spread inducer for all 4 species.

Time progress of dark fermentation for biological hydrogen production using Chlamydomonas reinhardtii

  • Kim, Ji-Seong;Gong, Gyeong-Taek;Park, Dae-Won;Sim, Sang-Jun;Park, Tae-Hyeon;Jo, Gyeong-Suk;Jeong, Yun-Cheol
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.162-163
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    • 2003
  • Through the experiment, process of producing hydrogen and organic compounds using C. reinhardtii has been researched. In dark fermentation, pH and dry cell weight as well as starch content decreased as time goes, while organic compounds and hydrogen were produced more in accordance with time. Still, organic compounds showed tendency to increase in accordance with time, but hydrogen reached the maximum on the third day.

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Effect of Productivity on the Hydrogen Content of Atmospheric gas in the BAF (BAF에서 분위기 가스의 수소 성분이 생산성에 미치는 영향)

  • 김순경;전언찬;김문경
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1996.11a
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    • pp.560-564
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    • 1996
  • In recently, annealing process of cold rolled sheet tend to change to continuous annealing process for improving qualify, saving yield. In the meantime as demand for various kind and small lot of products has been increasing, batch annealing has been appreciated for its small restriction for the operation. So, we tested on the effect for a hydrogen contents of atmospheric gas at annealing furnace. As a result of several investigation. We confirmed for the following characteristics ; improved productivity, uniform heating, improved surface quality, saving energy. Therefore, the use of hydrogen instead of nitrogen as the protective gas, combined with high convection in batch annealing furnaces, has shown that considerable increases in furnace output and material quality are attainable. Owing to the low density, high diffusion and reducing character of hydrogen, a better transfer resulting in uniform material temperatures and improved coil surfaces can be achieved.

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Powder Fabrication of Nb-Ti Alloys Using Hydrogenation Process

  • Semboshi, Satoshi;Masahashi, Naoya;Konno, Toyohiko J.;Hanada, Shuji
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.165-166
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    • 2006
  • Nb-Ti alloys were hydrogenated to prepare fine and contamination-free powders. Cracks were introduced in the alloys when they were annealed at 1473 K and cooled in a hydrogen atmosphere. The fragments produced by hydrogen-induced cracking are brittle and the friability enhanced with the Ti content of the alloy, which is beneficial for further refinement of particle size. We also demonstrate that Nb-Ti powders with the average particle size less than 1 m can be produced by ball milling at a temperature lower than 203 K. Furthermore, hydrogen-free powders can then be obtained by annealing above the temperature corresponding to hydrogen desorption from Nb solid solution.

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Effects of Nafion Contents on the Performance of MEAs Prepared by Decal-Transfer Method (Nafion 함량이 데칼전사기법을 통해 제작된 고분자 전해질 연료전지의 MEA 성능에 미치는 영향)

  • Kim, Gyeong-Hee;Cho, Eun-Ae;Han, Jong-Hee;Kim, Sung-Hyun;Eom, Kwang-Sup
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.125-133
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    • 2012
  • Nafion ionomer located in electrode helps to increase the platinum utilization and proton conductivity. To achieve higher performance in PEMFCs, it is important an optimum Nafion content in the electrode. As the platinum loading and fabricated method depend on the optimum Nafion content. In this study, we have examined the interrelationship between platinum loading and Nafion content fabricated by decal transfer method. For electrodes with 0.25 and 0.4 mg/$cm^2$ Pt loading, best performance was obtained at 25 wt.% Nafion ionomer loading. It is also found that MEA with 0.25 mg/$cm^2$ Pt, the optimum Nafion content appears differently at low and high current density.

The hydrogen storage capacity of metal-containing polyacrylonitrile-based electrospun carbon nanofibers

  • Bai, Byong-Chol;Kim, Jong-Gu;Naik, Mehraj-Ud-Din;Im, Ji-Sun;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.3
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    • pp.171-176
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    • 2011
  • Polyacrylonitrile-based carbon nanofibers (CNFs) containing Ti and Mn were prepared by electrospinning. The effect of metal content on the hydrogen storage capacity of the nanofibers was evaluated. The nanofibers containing Ti and Mn exhibited maximum hydrogen adsorption capacities of 1.6 and 1.1 wt%, respectively, at 303 K and 9 MPa. Toward the development of an improved hydrogen storage system, the optimum conditions for the production of metalized CNFs were investigated by characterizing the specific surface areas, pore volumes, sizes, and shapes of the fibers. According to the results of Brunauer-Emmett-Teller analysis, the activation of the CNFs using potassium hydroxide resulted in a large pore volume and specific surface area in the samples. This is attributable to the optimized pore structure of the metal-containing polyacrylonitrile-based electrospun CNFs, which may provide better sites for hydrogen adsorption than do current adsorbates.

Anaerobic Hydrogen Fermentation and Membrane Bioreactor (MBR) for Decentralized Sanitation and Reuse-Organic Removal and Resource Recovery

  • Paudel, Sachin;Seong, Chung Yeol;Park, Da Rang;Seo, Gyu Tae
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.387-393
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    • 2014
  • The purpose of this study is to evaluate integrated anaerobic hydrogen fermentation and membrane bioreactor (MBR) for on-site domestic wastewater treatment and resource recovery. A synthetic wastewater (COD 17,000 mg/L) was used as artificial brown water which will be discharged from urine diversion toilet and fed into a continuous stirred tank reactor (CSTR) type anaerobic reactor with inclined plate. The effluent of anaerobic reactor mixed with real household grey water (COD 700 mg/L) was further treated by MBR for reuse. An optimum condition maintained in anaerobic reactor was HRT of 8 hrs, pH 5.5, SRT of 5 days and temperature of $37^{\circ}C$. COD removal of 98% was achieved from the overall system. Total gas production rate and hydrogen content was 4.6 L/day and 52.4% respectively. COD mass balance described the COD distribution in the system via reactor byproducts and effluent COD concentration. The results of this study asserts that, anaerobic hydrogen fermentation combined with MBR is a potent system in stabilizing waste strength and clean hydrogen recovery which could be implemented for onsite domestic wastewater treatment and reuse.

Effect of pH on Continuous Hydrogen Fermentation (연속반응실험에서 수소생성에 대한 pH 영향)

  • Lee, Young-Joon
    • Journal of Environmental Health Sciences
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    • v.30 no.2
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    • pp.149-153
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    • 2004
  • The influences of pH on hydrogen production were also investigated over the pH range from 4.1 to 8.0 at HRT 10 hours. The hydrogen content for the produced gas was changed from 41 to 71% with corresponding pHs throughout this experiment. The produced hydrogen/carbon dioxide ratio was not vary significantly up to 6.0, then steepenly increased with increases in the pH. The maximal hydrogen yield was found to be 3.16 $\ell$/g sucrose at pH 5.0. Acetate production yield increased with increased pH, but butyrate production yield decreased with increased pH. Biomass yield increased with increased pH.