• Journal of Electrochemical Science and Technology
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• v.4 no.2
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• pp.71-80
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• 2013

The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

• Proceedings of the KIEE Conference
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• 2004.11c
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• pp.178-180
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• 2004

In this work, we propose new method of sigma filtering for efficient filtering and preserving edge regions in DCT Domain. In block-based image compression technique, the image is first divided into non-overlapping $8{\times}8$ blocks. Then, the two-dimensional DCT is computed for each $8{\times}8$ block. Once the DCT coefficients are obtained, they are quantized using a specific quantization table. Quantization of the DCT coefficients is a lossy process, and in this step, noise is added. In this work, we combine IDCT matrix and filter matrix to a new matrix to simplify filtering process to remove noise after IDCT in spatial domain, for each $8{\times}8$ DCT coefficient block, we determine whether this block is edge or homogeneous region. If this block is edge region, we divide this $8{\times}8$ block into four $4{\times}4$ sub-blocks, and do filtering process for sub-blocks which is homogeneous region. By this process, we can remove blocking artifacts efficiently preserving edge regions at the same time.

• Journal of the Korean Society for Precision Engineering
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• v.15 no.6
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• pp.124-138
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• 1998

Particles reinforced MMCs have many advantages over monolithic metals including a higher specific modulus, higher specific strength, better properties at elevated temperatures and better wear resistance. SiC$_p$/A16061 composites have good results in its mechanical properties. This work investigates SiC$_p$/A16061 composites in the microscopic view and compares the analytical results with the experimental ones. The discrepancy of the material properties between the reinforced particle, SiC$_p$, and the matrix material, A16061 appears to be so significant. Especially the coefficient of thermal expansion(CTE) of A16061 is 5 times larger than that of SiC$_p$. Thermal residual stress in MMCs is induced at high temperatures. The shape of particle is various but the theoretical model is not able to consider the nonuniform shape. Particle distribution is not homogeneous in experimental specimen. However, it is assumed to be homogeneous in simulation model. The shapes of particles are assumed to be not only perfect global but hexahedral shapes. The types of particle distribution are two - simple cubic array(SC array) and face-centered cubic array(FCC array).

• Journal of the Korean Chemical Society
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• v.11 no.4
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• pp.159-164
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• 1967

An exact expression of the titration fraction as a function of the potential is derived for the cases where the coefficients of the both half reactions involved in the titration are homogeneous. It shows that the potential is independent of the concentration of the reagents not only at the equivalence point but also at all titration fractions. The sharpness of the end point detection by potentiometric method is shown to depend not only on the difference of the normal potentials involved but also strongly on the number of electrons transferred in each half reaction. The inflexion point of the potentiometric titration curve is shown to be slightly off from the equivalence point, including the cases where the number of electrons involved are equal. Completeness of the reaction in the course of titration is analyzed, too, mostly in terms of equilibrium constant, thus most of the results are applicable to any type of equilibrium in a single phase with particular relationship of coefficients of chemical equation.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.13 no.1
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• pp.87-93
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• 2002

The previous RST postulates that the scattering field, within each modal partial wave, comprise of the resonance and the background components. The new RST is recently developed by the product expansion of the scattering functions in the field of acoustics. The new formulation suggests that the scattering coefficients consist of resonance, non-resonance, and their interactional portions. In the scattering problems of acoustic waves, the moduli and phase of the resonance coefficient are obtained correctly by the new RST. In our recent works the new RST was successfully applied to the scattering problem of electromagnetic waves for coated conducting cylinder and sphere. In this paper, the new RST is extended to the 2-dimensional scattering problem of electromagnetic waves for a homogeneous dielectric cylinder, and the numerical results are compared with the previous RST.

• Korean Journal of Materials Research
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• v.24 no.7
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• pp.375-380
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• 2014

Solar cells exhibit different power outputs in different climates. In this study, the temperature dependence of open-circuit voltage(V-oc), short-circuit current(I-sc), fill factor(FF) and the efficiency of screen-printed single-crystal silicon solar cells were studied. One group was fabricated with homogeneously-doped emitters and another group was fabricated with selectively-doped emitters. While varying the temperature (25, 40, 60 and $80^{\circ}C$), the current-voltage characteristics of the cells were measured and the leakage currents extracted from the current-voltage curve. As the temperature increased, both the homogeneously-doped and selectively-doped emitters showed a slight increase in I-sc and a rapid degradation of V-oc. The FF and efficiency also decreased as temperature increased in both groups. The temperature coefficient for each factor was calculated. From the current-voltage curve, we found that the main cause of V-oc degradation was an increase in the intrinsic carrier concentration. The temperature coefficients of the two groups were compared, leading to the idea that structural effects could also affect the temperature dependence of current-voltage characteristics.

• The KIPS Transactions:PartB
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• v.17B no.5
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• pp.363-374
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• 2010

In this paper, we propose the method for extracting Homogeneity Threshold($H_T$) and for segmenting homogeneous regions by USRG(Unseeded Region Growing) with $H_T$. The $H_T$ is a criterion to distinguish homogeneity in neighbor pixels and is computed automatically from the original image by proposed method. Theoretical background for proposed method is based on the Otsu's single level threshold method. The method is used to divide a small local part of original image int o two classes and the sum($\sigma_c$) of standard deviations for the classes to satisfy special conditions for distinguishing as different regions from each other is used to compute $H_T$. To find validity for proposed method, we compare the original image with the image that is regenerated with only the segmented homogeneous regions and show up the fact that the difference between two images is not exist visually and also present the steps to regenerate the image in order the size of segmented homogeneous regions and in order the intensity that includes pixels. Also, we show up the validity of proposed method with various results that is segmented using the homogeneity thresholds($H^*_T$) that is added a coefficient ${\alpha}$ for adjusting scope of $H_T$. We expect that the proposed method can be applied in various fields such as visualization and animation of natural image, anatomy and biology and so on.

• Korean Journal of Remote Sensing
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• v.25 no.1
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• pp.21-30
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• 2009

The purposes of this paper are to present a selection method of neighboring pixels whose local statistics are similar to the center pixel and combine the selection result with mean curvature diffusion filter to reduce noises in remote sensed imagery. The order of selection of neighboring pixels is critical, especially for finding a pixel belonging to the homogeneous region, since the statistics of the homogeneous region vary according to the selection order. An effective strategy for selecting neighboring pixels, which uses rank-order differences vector obtained by computing the intensity differences between the center pixel and neighboring pixels and arranging them in ascending order, is proposed in this paper. By using region growing method, we divide the elements of the rank-ordered differences vector into two groups, homogeneous rank-ordered differences vector and outlier rank-ordered differences vector. The mean curvature diffusion filter is combined with a line process, which chooses selectively diffusion coefficient of the neighboring pixels belonging into homogeneous rank-ordered differences vector. Experimental results using an aerial image and a TerraSAR-X satellite image showed that the proposed method reduced more efficiently noises than some conventional adaptive filters using all neighboring pixels in updating the center pixel.

• The Korean Journal of Nuclear Medicine
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• v.32 no.1
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• pp.32-49
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• 1998

For estimation of regional myocardial blood flow with O-15 water PET, a few modifications considering partial volume effect based on single compartment model have been proposed. In this study, we attempted to quantify the degree of heterogeneity and to show the effect of tissue flow heterogeneity on partition coefficient(${\lambda}$) and to find the relation between perfusable tissue index(PTI) and ${\lambda}$ by computer simulation using two modified models. We simulated tissue curves for the regions with homogeneous and heterogeneous blood flow over a various flow range(0.2-4.0ml/g/min). Simulated heterogeneous tissue composed of 4 subregions of the same or different size of block which have different homogeneous flow and different degree of slope of distribution of blood flow. We measured the index representing heterogeneity of distribution of blood flow for each heterogeneous tissue by the constitution heterogeneity(CH). For model I, we assumed that tissue recovery coefficient ($F_{MME}$) was the product of partial volume effect($F_{MMF}$) and PTI. Using model I, PTI, flow, and $F_{MM}$ were estimated. For model II, we assumed that partition coefficient was another variable which could represent tissue characteristics of heterogeneity of flow distribution. Using model II, PTI, flow and ${\lambda}$ were estimated. For the simulated tissue with homogeneous flow, both models gave exactly the same estimates, of three parameters. For the simulated tissue with heterogeneous flow distribution, in model I, flow and $F_{MM}$ were correctly estimated as CH was increased moderately. In model II, flow and ${\lambda}$ were decreased curvi-linearly as CH was increased. The degree of underestimation of ${\lambda}$ obtained using model II, was correlated with CH. The degree of underestimation of flow was dependent on the degree of underestimation of ${\lambda}$. PTI was somewhat overestimated and did not change according to CH. We conclude that estimated ${\lambda}$ reflect the degree of tissue heterogeneity of flow distribution. We could use the degree of underestimation of ${\lambda}$ to find the characteristic heterogeneity of tissue flow and use ${\lambda}$ to recover the underestimated flow.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.11 no.4
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• pp.325-330
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• 2018

This paper, following the shape parameters of the minimax distribution, describes the special form of the beta distribution, the Minimax distribution, as a function of the shape parameters for the software reliability model based on the non-homogeneous Poisson process. Characteristics and usefulness were discussed. As a result, the case of the shape parameter 1 of Minimax distribution than less than and greate in mean squared error is the smallest, in determination coefficient, appears to be high, the shape parameter 1 of Minimax distribution regard as an efficient model. The estimated determination coefficient of the proposed model is estimated to be more than 95%, which is a useful model in the field of software reliability. Through this study, software design and users can identify the software failure characteristics using mean square error, decision coefficient, and confidence interval can be used as a basic guideline.