• 제목/요약/키워드: Homogeneous coefficient

검색결과 217건 처리시간 0.028초

열분해와 Hot Injection법을 이용한 CoSb3 나노분말합성 (Thermal Decomposition Synthesis of CoSb3 Nanoparticle by Hot Injection Method)

  • 김민숙;안종필;김경자;박주석;김경훈;김형순
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.476-479
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    • 2013
  • $CoSb_3$ with its high electrical conductivity, Seebeck coefficient and rather low thermal conductivity is quite a promising material for thermoelectric conversion applications. A potentially high figure of merit (ZT) can be achieved by a nanostructure evolution of thermoelectric materials. In this work, $CoSb_3$ nanoparticles were synthesized through a thermal decomposition method in cooperation with a hot injection technique. Nano-sized $CoSb_3$ particles were obtained through the thermal decomposition reaction between the pre-heated cobalt-oleate at $320^{\circ}C$ and the injected antimony oleate with room temperature. The results showed that the particle size was increased with increasing synthesis temperature and the crystallinity of particles was improved with temperature but the decomposition of $CoSb_3$ was observed at $320^{\circ}C$. The $CoSb_3$ particles synthesized at $300^{\circ}C$ showed a high purity and an homogeneous shape with average particle size of 26 nm.

노인부양행위의 결정요인 II : 인과모형 개발 (Determinants of Housewives' Caregiving Behavior to Elderly Parents-in-Law (II) : Development of a Causal Model)

  • 김상욱
    • 한국사회복지학
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    • 제38권
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    • pp.33-67
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    • 1999
  • This study is the second phase of the author's larger attempt to investigate the factors affecting housewives' caregiving behavior to their elderly parents-in-law. Specifically, it revises and expands the previous model (1998) and develops a new one by rectifying the three major problems inherent in the previous study: (1) misspecification error; (2) non-equivalent comparison of results between the father-in-law model and mother-in-law model that stems from the inclusion of heterogeneous group of caregivers; (3) measurement problems for the two endogenous variables of eldercare attitude and behavior. To do this, the current study proposes a more comprehensive model by additionally incorporating other salient exogenous variables, renders the comparison of results between the father-in-law and mother-in-law models equivalent by including only homogeneous group of caregivers (i. e., only those housewives whose parents-in-law are both alive), and introduces standardized measurement scales for the endogenous variables. Estimation of the model in terms of maximum likelihood procedures in LISREL8 attests to a better overall performance over the previous model when judged from several criteria such as coefficient of determination, model fit statistics, proportion of significant causal paths, and measurement properties of reliability and validity for the variables. Interpretation of the findings suggests several salient theoretical implications that concern such crucial issues as the inconsistency between eldercare attitude and behavior, patterns of association among the subdimensions of eldercare, and the difference in the antecedents explaining attitude as opposed to behavior of eldercare. In particular, the finding that indicates almost no differences in the determinants between the father-in-law and mother-in-law models suggests a strong case to argue that caregiving behavior to fathers-in-law and mothers-in-law, respectively, is likely to be a uniform phenomenon sharing virtual1y the same antecedents, and that a unified single model is sufficient to account for caregiving behavior to both parties.

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다층지반 하에서 수평하중을 받는 말뚝의 회전점 (Rotation Point of Laterally Loaded Pile Under Multi Layered Soil)

  • 강병준;경두현;홍정무;이준환
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2008년도 추계 학술발표회
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    • pp.708-712
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    • 2008
  • Piles and pile foundations have been in common use since very early times. Usually function of piles is to carry load to a depth at which adequate support is available. Another important use of piles is to furnish lateral support and nowadays it is getting highlighted due to the wind load, lateral action of earthquake, and so on. After Broms (1964), many researchers have been suggested methods for estimating lateral capacity of pile. But each method assumes different earth pressure distribution and lateral earth pressure coefficient and it gives confusion to pile designers. Lateral earth pressure, essential in lateral capacity estimation, influenced by pile's behavior under lateral load. Prasad and Chari (1999) assumed the rotation point of pile and suggested an equation of ultimate lateral load capacity. In this study, we investigate the depth of rotation point in both homogeneous soil and multi layered soil, and compare to the estimation value by previous research. To model the pile set up in the sand, we use the chamber and small scale steel pile, and rain drop method. Test results show the rotation point is formed where the Prasad and Chari's estimation value, and they also show multi layered condition affects to location of rotation point to be scattered.

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single phase-vanadium dioxide 박막을 이용한 온도센서에 관한 연구 (A temperature sensor using single phase-vanadium dioxide thin films)

  • 김지홍;홍성민;곽연화;박순섭;황학인;문병무
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.109-110
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    • 2006
  • In bio applications, high temperature coefficient of resistance (TCR) at $30^{\circ}C{\sim}40^{\circ}C$ is especially important for a temperature sensor. In this work, single phase-vanadium dioxide ($VO_2$) thin films for temperature sensor were fabricated by reactive DC magnetron sputtering and post-annealing method. VOx thin films deposited by reactive sputtering in a controlled $Ar/O_2$ atmosphere can be transformed into single phase-$VO_2$ films by post-annealing in $N_2$ atmosphere. The grown $VO_2$ thin films have a moderate resistance at room temperature and very high TCR at room temperature and transition temperature, respectively 2.88%/K and 15.8%/K. A detailed structural characterization is performed by SEM, XRD and RBS. SEM morphology image indicates that grains of fabricated $VO_2$films are homogeneous and ball-like in shape. A fact that the films contain only single phase-$VO_2$ is obtained by XRD and RBS analysis. After deposition, the sensors were fabricated by micromachining technology. Silicon nitride membrane and black nickel were used for a thermal isolation structure and absorption layer. In the vicinity of room temperature, the TCR of sensors was enough high to apply for bio sensors.

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다단계 냉간 압연된 고탄소강 와이어의 미세조직 및 기계적 특성에 미치는 패스스케줄의 영향 (Effect of Pass Schedule on the Microstructures and Mechanical Properties of Multi-step Cold Rolled High Carbon Steel Wires)

  • 우동혁;이욱진;박익민;박용호
    • 한국재료학회지
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    • 제21권6호
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    • pp.320-326
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    • 2011
  • Flat rolling of wire is an industrial process used to manufacture electrical flat wire, medical catheters, springs, piston segments and automobile parts, among other products. In a multi-step wire flat rolling process, a wire with a circular crosssection is rolled at room temperature between two flat rolls in several passes to achieve the desired thickness to width ratio. To manufacture a flat wire with a homogeneous microstructure, mechanical and metallurgical properties with an appropriate pass schedule, this study investigated the effect of each pass schedule (1stand ~ 4stand) on the microstructures, mechanical properties and widths of cold rolled high carbon steel wires using four-pass flat rolling process. The evolutions of the microstructures and mechanical properties of the widths of cold rolled wires during three different pass schedules of the flat rolling process of high carbon wires were investigated, and the results were compared with those for a conventional eight-pass schedule. In the width of cold rolled wires, three different pass schedules are clearly distinguished and discussed. The experimental conditions were the same rolling speed, rolling force, roll size, tensile strength of the material and friction coefficient. The experimental results showed that the four-pass flat cold rolling process was feasible for production of designed wire without cracks when appropriate pass schedules were applied.

대수 선형 위험함수 학습효과에 근거한 NHPP 신뢰성장 소프트웨어 모형에 관한 비교 연구 (The Comparative Study for NHPP Software Reliability Model based on the Property of Learning Effect of Log Linear Shaped Hazard Function)

  • 김희철;신현철
    • 융합보안논문지
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    • 제12권3호
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    • pp.19-26
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    • 2012
  • 본 연구에서는 소프트웨어 제품을 개발하여 테스팅을 하는 과정에서 소프트웨어 관리자들이 소프트웨어 및 검사 도구에 효율적인 학습기법을 이용한 NHPP 소프트웨어 모형에 대하여 연구 하였다. 적용모형은 로그 형 위험함수 모형을 적용한 유한고장 NHPP에 기초하였다. 소프트웨어 오류 탐색 기법은 사전에 알지 못하지만 자동적으로 발견되는 에러를 고려한 자동에러탐색요인과 사전 경험에 의하여 세밀하게 에러를 발견하기 위하여 테스팅 관리자가 설정해놓은 요인인 학습효과의 특성에 대한 문제를 비교 제시 하였다. 그 결과 학습요인이 자동 에러 탐색요인보다 큰 경우가 대체적으로 효율적인 모형임을 확인 할 수 있었다. 본 논문의 소프트웨어 고장 자료 분석에서는 고장 간격 시간 자료를 적용하고 모수추정 방법은 최우추정 법을 이용하고 추세분석을 통하여 자료의 효율성을 입증한 후 평균제곱오차와 $R^2$(결정계수)를 이용하여 효율적인 모형을 선택 비교하였다.

저온연소조건에서 급속압축기를 이용한 n-heptane/n-butanol 혼합연료의 착화지연에 관한 연구 (The investigation on the Ignition Delay of n-heptane/n-butanol Blend Fuel Using a Rapid Compression Machine at Low Temperature Combustion Regime)

  • 송재혁;강기중;;;최경민;김덕줄
    • 한국연소학회지
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    • 제18권2호
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    • pp.32-41
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    • 2013
  • This study presents both experimental and numerical investigation of ignition delay time of n-heptane and n-butanol binary fuel. The $O_2$ concentration in the mixture was set to 9-10% to make high exhaust gas recirculation( EGR) rate condition which leads low NOx and soot emission. Experiments were performed using a rapid compression machine(RCM) at compressed pressure 20bar, several compressed temperature and three equivalence ratios(0.4, 1.0, 1.5). In addition, a numerical study on the ignition delay time was performed using CHEMKIN codes to validate experimental results and predict chemical species in the combustion process. The results showed that the ignition delay time increased with increasing the n-butanol fraction due to a decrease of oxidation of n-heptane at the low temperature. Moreover, all of the binary fuel mixtures showed the combustion characteristics of n-heptane such as cool flame mode at low temperature and negative-temperature-coefficient(NTC) behavior. Due to the effect of high EGR rate condition, the operating region is reduced at lean condition and the ignition delay time sharply increased compared with no EGR condition.

RuO2-유리 복합분말을 이용하여 제조된 후막 저항의 전기적 특성 연구 (Electrical Properties of Thick-Film Resistor Prepared by Using RuO2-Glass Composite Powder)

  • 김민식;류성수
    • 한국표면공학회지
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    • 제50권5호
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    • pp.301-307
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    • 2017
  • The purpose of this study is to investigate the electrical properties of thick-film resistor (TFR) prepared from $CaO-ZnO-B_2O_3-Al_2O_3-SiO_2$ (CZBAS) glass containing $RuO_2$ particles. $RuO_2$-glass composite powder was made by mixing and melting oxide powders of constituents. For comparison, $RuO_2$ powder was simply mixed with glass powder. $RuO_2$-40wt% glass composite and mixture were dispersed in an organic binder to obtain printable resistor paste and then thick-film was formed by screen printing, followed by sintering at the range between $750^{\circ}C$ and $900^{\circ}C$ for 10 min with a heating rate of $50^{\circ}C/min$ in an ambient atmosphere. $RuO_2$-glass composite sample showed much higher resistance compared to the simple mixed sample. This could be attributed to the difference in conducting mechanism. After sintering at $850^{\circ}C$, temperature coefficient of resistance of composite sample was lower than that of simple-mixed sample. TFR with dense and homogeneous microstructure could be obtained by using $RuO_2$-glass composite powder.

티타늄 기판 위에 강유전성 BaTiO3박막 형성과 분극처리에 의한 Eagle’s MEM 용액에서의 Calcium Phosphate 생성 (Fabrication of Ferroelectric BaTiO3Thin Film on Ti Substrate and Formation of Calcium Phosphate in Eagle’s MEM Solution)

  • 이용렬;정영화;황규석;송호준;박영준
    • 한국재료학회지
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    • 제12권7호
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    • pp.560-567
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    • 2002
  • Titanium (Ti) is a bioinert material and has lower elastic coefficient and better strength/volume property than other metals. Ferroelectric materials show alignment of positive and negative charges by poling treatment. This study was purposed to develop a new implant system by combining the advantages of Ti and ferroelectric property of $BaTiO_3$ (BTO). It was performed with the assumption that the $Ca^{2+ }$ ions would be easily attracted on negatively charged surface and the attracted cation might behave as nuclei for bone-like crystal growth in biological solutions. A ferroelectric BTO thin film on Ti was fabricated and the effect of poling treatment on the improvement of calcium phosphate (Ca-P) formation in biological solutions was evaluated. After immersion in Eagle’s minimum essential media (MEM) solution, NaCl was formed on Ti, and Ca-P layer containing NaCl was formed on Ti-O. Weak and sparse Ca-P layers were formed on BTO, while thick, homogeneous, and dense Ca-P layer was formed on negatively polarized BTO (N-BTO), which was confirmed by FE-SEM and EDX. In summary, these results demonstrate that poling the ferroelectric BTO surface negatively is effective for the formation of Ca-P layer in MEM solution, and that N-BTO coating on Ti could be used as a possible alternative method for enhancing the osseointegration of the implants.

Arthrobacter luteus가 생산(生産)하는 효모(酵母) 세포벽(細胞壁) 용해(溶解) 촉진인자(促進因子)의 정제(精製) 및 그 이화학적(理化學的) 성질(性質) (Purification and Properties of the Factor from Arthrobacter luteus, Capable of Accelerating the Lysis of Yeast Cell Walls)

  • 오홍록;아이조노 야스오;시모다 타다히사;마사루 푸나트수
    • 한국식품영양과학회지
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    • 제12권4호
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    • pp.387-394
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    • 1983
  • zymolyase(${\beta}-1$, 3-glucanase)의 효모(酵母) 세포벽(細胞壁)에 대한 용해작용(溶解作用)을 촉진(促進)시키는 인자(因子)를 zymolyase의 조효소(粗酵素)로부터 분리(分離)하여 Sephadex G-75 gel 여과(濾過) 및 조제용(調製用) PAG-전기영동법(電氣泳動法)에 의하여 전기영동적(電氣泳動的)으로 균일(均一)하게 정제(精製)하였다. SDS-PAG 전기영동법(電氣泳動法)에 의하여 측정한 정제(精製) 인자(因子)의 분자량(分子量)은 40,500이었고, 등전점(等電點)은 pH 9.6이었다. 정제(精製)된 촉진인자(促進因子)는 395개(個)의 아미노산 잔기(殘基)로 구성(構成)되는 단일(單一) polypeptide의 염기성(鹽基性) protease임이 밝혀졌으며, 이 protease의 흡광계수(吸光係數)($E_{208,cm}^{1%}$)는 11.9, 분자흡광계수(分子吸光係數)(${\varepsilon}_{280,}mole/l$)는 $4.83{\times}10^4$이었다.

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