• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3444-3450
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• 2013

Three phase hollow fiber-liquid phase microextraction (HF-LPME), which is faster, simpler and uses a more environmentally friendly sample-preparation technique, was developed for the analysis of Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) in human urine. For the effective simultaneous extraction/concentration of NSAIDs by three phase HF-LPME, parameters (such as extraction organic solvent, pH of donor/acceptor phase, stirring speed, salting-out effect, sample temperature, and extraction time) which influence the extraction efficiency were optimized. NSAIDs were extracted and concentrated from 4 mL of aqueous solution at pH 3 (donor phase) into dihexyl ether immobilized in the wall pores of a porous hollow fiber, and then extracted into the acceptor phase at pH 13 located in the lumen of the hollow fiber. After the extraction, 5 ${\mu}L$ of the acceptor phase was directly injected into the HPLC/UV system. Simultaneous chromatographic separation of seven NSAIDs was achieved on an Eclipse XDB-C18 (4.6 mm i.d. ${\times}$ 150 mm length, 5 ${\mu}m$ particle size) column using isocratic elution with 0.1% formic acid and methanol (30:70) at a HPLC-UV/Vis system. Under optimized conditions (extraction solvent, dihexyl ether; $pH_{donor}$, 3; $pH_{acceptor}$, 13; stirring speed, 1500 rpm; NaCl salt, 10%; sample temperature, $60^{\circ}C$; and extraction time, 45 min), enrichment factors (EF) were between 59 and 260. The limit of detection (LOD) and limit of quantitation (LOQ) in the spiked urine matrix were in the concentration range of 5-15 ng/mL and 15-45 ng/mL, respectively. The relative recovery and precision obtained were between 58 and 136% and below 15.7% RSD, respectively. The calibration curve was linear within the range of 0.015-0.96 ng/mL with the square of the correlation coefficient being more than 0.997. The established method can be used to analyse of NSAIDs of low concentration (ng/mL) in urine.

• Clean Technology
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• v.12 no.4
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• pp.205-210
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• 2006

In this study, polystyrene hollow microspheres were prepared via optimized purifying steps for the reuse of waste polystyrene. PS/PVA double layered hollow microspheres were prepared using the multiple emulsion ($W_1/O/W_2$) method with recycled polystyrene. The sonication treatment at the first stage of $W_1/O$ emulsion formation was very important factor of control of particle size and its distribution. When sonication was treated for 20 seconds, the average particle size and distribution were $1.35{\mu}m$ and $0.8{\mu}m{\sim}2.8{\mu}m$, respectively. The double layered hollow microspheres that have smaller and uniformed particle size distribution were manufactured when gelatin or Tween 80 was used as surfactants in the $W_2$ phase.

• Clean Technology
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• v.14 no.4
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• pp.256-264
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• 2008

In this study, using PBAST (poly(butylene adipate-co-succinate-co-terephthalate)) which was eco-friendly biodegradable aliphatic polyester, PBAST/PVA (poly(vinyl alcohol)) double-layered hollow microspheres were prepared with the water/oil/water multiple emulsion ($W_1/O/W_2$) method. The double-layered hollow microspheres were manufactured with the yield of 30.92% when the concentration of polymer PBAST in organic phase was 5 wt%, the concentration of PVA in inner aqueous phase was 5 wt%, the volume ratio of $W_1/O$ emulsion to outer aqueous phase was 1:4.5, and when co-surfactants that had large gap in HLB (hydrophile-lipophile balance) value were used. The bulk density of prepared hollow microsphere was 0.180 g/ml and particle size was $1.5{\sim}3\;{\mu}m$.

• Journal of the Earthquake Engineering Society of Korea
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• v.13 no.3
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• pp.51-65
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• 2009

The seismic design concept of RC bridges is to attain the proper ductility of piers, yielding a ductile failure mechanism. Therefore, seismic design force for moment is determined by introducing a response modification factor (R), and lateral reinforcements to confine core concrete are specified in the current design code. However, these design provisions have irrationality, which results in excessive amounts of lateral reinforcements for columns in Korea, which are generally designed with large sections. To improve on these provisions, a new design method based on seismic performance has been proposed. To apply this to hollow sectional columns, however, further investigations and improvements must be performed, due to the different seismic behaviors and confinement effects. In this study, hollow sectional columns with different lap-splice of longitudinal bars and lateral reinforcements have been tested. Seismic characteristics and performance were investigated quantitatively. These research results can be used to derive a performance-based design for hollow sectional columns.

• Korean Chemical Engineering Research
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• v.45 no.1
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• pp.81-86
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• 2007

Hollow fiber membrane G-L contactors are widely used to remove $SO_2$ emitted from industrial facilities. In this work, the mathematical modeling and computer simulation for hollow membrane G-L contactors is carried out to analyze $SO_2$ absorption behavior in hollow fiber membranes. The model is solved with the finite element method using a commercial software. Investigated is the dependency of $SO_2$ removal efficiency and mass transfer characteristics on gas velocities, membrane mass transfer coefficients and physical properties of contactors. The membrane mass transfer coefficients are estimated by fitting the experimental data with the simulated $SO_2$ removal efficiencies. In addition, a design methodology of membrane contactors is suggested.

• Food Science and Preservation
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• v.10 no.4
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• pp.482-487
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• 2003

The filtration effects of glass membrane filters and hollow fiber membranes with different pore size to prevent the haze of a commercial foxtail millet Yakju were investigated. The most particles(haze precusors) present in the Yakju were removed by using 1.2 $\mu\textrm{m}$ glass membrane filter. In case of using 0.45$\mu\textrm{m}$ hollow fiber membrane system, the permeate flux on the Yakju filtration was calculated to 342.8 lmh. During the 3 month storage at 4$^{\circ}C$ and room temperature for each 48 hrs in turn, alittle fine haze was observed from the Yakju even if it was filtered by using 0.7 $\mu\textrm{m}$ glass membrane filter. Anything of haze was, however, observed from the Yakju filtered by using all of hollow fiber membranes. Therefore, the 0.45$\mu\textrm{m}$ hollow fiber membrane system was effective as a final filtration process of the Yakju.

• Journal of the Earthquake Engineering Society of Korea
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• v.15 no.2
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• pp.35-42
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• 2011

The seismic design of solid reinforced concrete bridge columns has been committed to, based on accumulated research and design specifications. The rational confinement model and seismic performance evaluation, however, are insufficient because of the lack of domestic and foreign design specifications about the experimental and analytical difficulties in the case of circular hollow reinforced concrete columns. In this paper, the seismic behavior of circular hollow reinforced concrete columns and its dependence on design variables are understood and explained. These research results can be used to derive the rational and economical design specifications for circular hollow sectional columns based on the result from the nonlinear analysis program, named RCAHEST (Reinforced Concrete Analysis in Higher Evaluation System Technology).

• Transactions of Materials Processing
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• v.25 no.6
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• pp.379-389
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• 2016

As a stator for steam turbine diaphragm, hollow-type nozzle stator to substitute for conventional solid one is introduced in this study. This hollowed stator can be separated into two parts such as upper and lower plates with large and curved surface area. This study focuses on thick plate forming process for the upper plate of the hollow-partitioned nozzle stator. First, to reduce forming defects such as under-cut and localized thinning of the deformed plate, and to avoid tool interruption between forming punch and lower die, tool design including the position determination of forming surfaces is performed. Uni-axial tensile tests are carried out using SUS409L steel plate with initial thickness of 5.00mm, and plastic strain ratio (r-value) is also obtained. Due to the asymmetric curved configuration of the upper plate, it is hard to adopt a series of blank holder or draw-bead, so the initial plate during this thick plate forming experiences unstable and non-uniform contact. To easy this forming difficulty and find suitable tool geometry without sliding behavior of the workpiece in the die cavity, two geometric parameters with respect to each shoulder angle of the lower die and the upper punch are adopted. FE models with consideration of 21 combinations for the geometric parameters are built-up, and numerical simulations are performed. From the simulated and predicted results, it is shown that the geometric parameter combinations with ($30^{\circ}$, $90^{\circ}$) and ($45^{\circ}$, $90^{\circ}$) for the shoulder angle of the lower die and the upper punch are suitably applied to this upper plate forming of the hollow-partitioned nozzle stator used for the turbine diaphragm.

• Journal of the Korea institute for structural maintenance and inspection
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• v.25 no.5
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• pp.182-189
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• 2021

VPS(Void Plywood Slab System, VPS) has optimized the shape of the hollow material. In addition, it has a function to prevent the floating of the hollow material and the separation due to the working load. In this study, the punching shear capacity of flat plate was performed using Void Plywood Slab System with form work panel proposed in the previous study. As a result of the test, the strength of the VSPS specimen in which the hollow material was placed beyond 2.0 times the column width from the loading point was reduced by 9.4% compared to the reference specimen. However, the strength value was about 1.57 times higher than the design value suggested by KBC 2016. It was found that there was no change in stiffness compared to the reference specimen until shear failure occurred in the VSPS specimen in which the hollow material was placed. It can be seen that this experiment is being destroyed by shear as the flexural reinforcing bars are sufficiently reinforced.

• Membrane Journal
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• v.31 no.6
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• pp.456-470
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• 2021

In this study, polyetherimide-based hollow fiber membranes were manufactured using the NIPS (nonsolvent induced phase separation) method. THF, Ethanol, and LiNO₃ were used as additives to control the morphology of the PEI-hollow fiber membranes. Furthermore, for the development of a high hydrogen separation membrane, the spinning conditions were optimized through the characterization of SEM and gas permeance. As a result, as the content of THF increased, the hydrogen/carbon dioxide selectivity increased. However, the permeance decreased due to the trade-off relationship. When ethanol was added, a finger-like structure was shown, and when LiNO₃ was added, a sponge structure was shown. In particular, in the case of a hollow fiber membrane with an optimized PDMS coating layer, the permeance was 40 GPU and the hydrogen/carbon dioxide selectivity was 5.6.