• Title/Summary/Keyword: Hollow

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HOLLOW FIBER MEMBRANG을 이용한 역세형 M/F SYSTEM

  • 김건태;최광호;김재협;최기석
    • Proceedings of the Membrane Society of Korea Conference
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    • 1994.10a
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    • pp.74-75
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    • 1994
  • 부유물질을 함유한 용수$\cdot$폐수의 정밀여과시 FOULING 때문에 세정약품이 많이 들고 MEMRANE 수명이 단축되는 문제점을 해결하기 위해 HOLLOW FIBER TYPE MEMBRANE을 이용한 역세형정밀 여과시스템을 개발하여 TEST를 실시하고 역세조건에 따른 FLUX, 제거율 및 역세효율을 조사하였다.

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Electrochemical Performance of Hollow Silicon/Carbon Anode Materials for Lithium Ion Battery (리튬이차전지용 Hollow Silicon/Carbon 음극소재의 전기화학적 성능)

  • Jung, Min Ji;Lee, Jong Dae
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.444-448
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    • 2016
  • Hollow silicon/carbon (H-Si/C) composites as anode materials for lithium ion batteries were investigated to overcome the large volume expansion. H-Si/C composites were prepared as follows; hollow $SiO_2\;(H-SiO_2)$ was prepared by adding $NaBH_4$ to $SiO_2$ synthesized using $st{\ddot{o}}ber$ method followed by magnesiothermic reduction and carbonization of phenolic resin. The H-Si/C composites were analyzed by XRD, SEM, BET and EDX. To improve the capacity and cycle performance, the electrochemical characteristics of H-Si/C composites synthesized with various $NaBH_4$ contents were investigated by charge/discharge, cycle, cyclic voltammetry and impedance tests. The coin cell using H-Si/C composite ($SiO_2:NaBH_4=1:1$ in weight) in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC : DMC : EMC = 1 : 1 : 1 vol%) has better capacity (1459 mAh/g) than those of other composition coin cells. It is found that the coin cell ($SiO_2:NaBH_4=1:1$ in weight) has an excellent capacity retention from 2nd cycle to 40th cycle.

Study on Manufacturing Process of Hollow Main Shaft by Open Die Forging (자유단조공법을 통한 중공형 메인샤프트 제조공정에 관한 연구)

  • Kwon, Yong Chul;Kang, Jong Hun;Kim, Sang Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.2
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    • pp.221-227
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    • 2016
  • The main shaft is one of the key components connecting the rotor hub and gear box of a wind power generator. Typically, main shafts are manufactured by open die forging method. However, the main shaft for large MW class wind generators is designed to be hollow in order to reduce the weight. Additionally, the main shafts are manufactured by a casting process. This study aims to develop a manufacturing process for hollow main shafts by the open die forging method. The design of a forging process for a solid main shaft and hollow shaft was prepared by an open die forging process design scheme. Finite element analyses were performed to obtain the flow stress by a hot compression test at different temperature and strain rates. The control parameters of each forging process, such as temperature and effective strain, were obtained and compared to predict the suitability of the hollow main shaft forging process. Finally, high productivity reflecting material utilization ratio, internal quality, shape, and dimension was verified by the prototypes manufactured by the proposed forging process for hollow main shafts.

Preparation of Asymmetric Folyethersulfone Hollow Fiber Membranes for Flue Gas Separation (온실기체 분리용 폴리이서설폰 비대칭 중공사 막의 제조)

  • Kim Jeong-Hoon;Sohn Woo-Ik;Choi Seung-Hak;Lee Soo-Bok
    • Membrane Journal
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    • v.15 no.2
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    • pp.147-156
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    • 2005
  • It is well-known that polyethersulfone (PES) has high $CO_2$ selectivity over $N_2\;(or\;CH_4)$ and excellent pressure resistance of $CO_2$ plasticization among muy commercialized engineering plastics[1-4]. Asymmetric PES hollow fiber membranes for flue gas separation were developed by dry-wet spinning technique. The dope solution consists of PES, NMP and acetone. Water and water/NMP mixtures are used in outer and inner coagulants, respectively. Gas permeation rate (i.e., permeance) and $CO_2/N_2$ selectivity were measured with pure gas, respectively and the micro-structure of hollow fiber membranes was characterized by scanning electron microscopy. The effects of polymer concentration, ratio of NMP to acetone, length of air gap, evaporation condition and silicone coating were investigated on the $CO_2/N_2$ separation properties of the hollow fibers. Optimized PES hollow fiber membranes exhibited high permeance of $25\~50$ GPU and $CO_2/N_2$ selectivity of $30\~40$ at room temperature and have the apparent skin layer thickness of about $0.1\;{\mu}m$. The developed PES hollow fiber membranes, would be a good candidate suitable for the flue gas separation process.

Fabrication of Polysulfone Hollow Fiber Membranes for N2/NF3 Separation (N2/NF3 분리용 폴리썰폰 중공사막 제조 연구)

  • Lim, Min Su;Kim, Seong-Joong;Kang, Ha Sung;Park, Ho Bum;Nam, Seung Eun;Park, Ho Sik;Lee, Pyung Soo;Park, You In
    • Membrane Journal
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    • v.26 no.1
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    • pp.76-85
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    • 2016
  • Fabrication of polysulfone (PSf) hollow fiber membranes was investigated for the separation of $N_2/NF_3$ gas mixtures, which are emitted from the display and the semiconductor industries. A combination of the non-solvent induced phase separation (NIPS) and the vapor-induced phase separation (VIPS) technique was applied to develop high flux hollow fiber membranes. Thin polymer layers were further coated onto the surface of the hollow fiber membranes by using polydimethylsiloxiane (PDMS) or Teflon AF1600(R), which contributes to improve the $N_2/NF_3$ selectivity. The $N_2/NF_3$ separation performances of our PSf hollow fiber membranes were determined by the intrinsic properties of coating materials. Especially, the PSf hollow fiber membrane coated with Teflon AF 1600(R) exhibited a higher $N_2/NF_3$ selectivity (> 14) with a slightly lower $N_2$ permeance (4.5 GPU), as compared to the commercial PSf counterparts. This feature provides a good potential as a membrane structure to separate $N_2/NF_3$.

Progress of Nanofiltration Hollow Fiber Membrane (NF용 중공사 분리막의 발전)

  • Jang, Hanna;Kim, Seongjoong;Lee, Yongtaek;Lee, Kew-Ho
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.456-470
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    • 2013
  • Hollow-fiber membranes, is one of the new technologies that is growing rapidly in the past few decades. In addition, separation membranes using polymer materials, have attracted attentions in various fields including gas separation, fuel cells, water treatment, wastewater treatment, and organic separation. Nanofiltration (NF) membranes having the separation characteristics in the intermediate range between ultrafiltration and reverse osmosis (RO) membranes for liquid separation, with relatively low investment cost and operating pressure lower than that of RO membranes, have high permeance and rejection performance of multivalent ions as well as organic compounds of molecular weight between $200{\sim}1000gmol^{-1}$. In this paper, we would like to review the research trends on the various structure control and characterization of NF hollow fiber membranes with respect to materials and the methods of preparation (phase inversion method and interfacial polymerization method). Currently, most of NF membranes have been manufactured by plate and frame types or spiral wound types. But hollow fiber types have delayed in commercial products, because of the weak strength when to produce on the basis of the existing materials, therefore the development of new materials or improvement of existing materials will be needed. If improving manufacturing technology is available, hollow fiber types will replace spiral wound types and gradually show a higher market share.

Fire Resistance of Circular Internally Confined Hollow Reinforced Concrete Column (원형 내부 구속 중공 철근콘크리트 기둥의 내화 성능)

  • Won, Deok-Hee;Han, Taek-Hee;Lee, Gyu-Sei;Kang, Young-Jong
    • Journal of Korean Society of Steel Construction
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    • v.22 no.2
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    • pp.139-150
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    • 2010
  • Reinforced-concrete (RC) columns are frequently designed and constructed. other types of columns includes composite types such as concrete-filled tube columns (CFT). Hollow RC columns may be effective in reducing both the self weight of columns and total amount of materials used. This is due to the fact that a hollow RC column possesses larger moment of inertia than that of solid RC columns of same cross sectional area. Despite the effectiveness the hollow RC column has not been popular because of its poor ductility performance. While the transverse reinforcements are effective in controlling the brittle failure of the outside concrete, they are not capable of resisting the failure of concrete of inner face which is in unconfined state of stress. To overcome these drawbacks, the internally confined hollow reinforced concrete (ICH RC), a new column type, was proposed in the previous researches. In this study, the fire resistance performance of the ICH RC columns was analyzed through a series of extensive heat transfer analyses using the nonlinear-material model program. Also, effect of factors such as the hollowness ratio, thickness of the concrete, and thickness of the internal tube on the fire resistance performance were extensively studied. Then the factors that enhance the fire-resistant performance of ICH RC were presented and analyzed.

Hydrophilic Coating and Characterization of PVDF Membrane with Flower Type Cross-section made from Thermally Induced Phase Separation (열유도 상분리로 제조한 플라워 형태 단면을 갖는 PVDF 분리막의 친수성 코팅 및 특성평가)

  • Im, Kwang Seop;Lee, Jeong Woo;Jang, Jae Young;Nam, Sang Yong
    • Membrane Journal
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    • v.29 no.6
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    • pp.362-376
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    • 2019
  • In this study, hydrophilic coating characteristics of PVDF [poly(vinylidene fluoride)] hollow fiber membranes with flower type cross-section prepared by thermally induced phase separation were studied. The hollow fiber used in this study was provided from PureEnvitech Co. Ltd., and the hydrophilic coating experiment was performed with different concentration and number of coating of PEBAX 1657, 2533 and 3533 block copolymer solution using a dip coating method. The hydrophilic coated hollow fiber membrane was characterized to scanning microscope and contact angle measurements to determine the degree of hydrophilization. As a result of SEM characterization, it was confirmed that the thickness of the coating layer increased as the coating concentration increased and the number of coatings increased. Contact angle of surface of hollow fibers decreased as the concentration of the coating solution increased and the number of coatings increased. Gas permeance of oxygen gas was measured for the application of the hydrophilized hollow fiber to Membrane Areated Biofilm Reactor. As a result of gas permeation test, it was confirmed that gas permeance decreased with increasing coating concentration and number of coatings, and the more hydrophilized hollow fiber coated with PEBAX 1657 showed lower gas permeance than those coated with PEBAX 2533 and 3533.