• Korean Journal of Materials Research
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• v.28 no.5
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• pp.273-278
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• 2018

Lithium-ion batteries have been considered the most important devices to power mobile or small-sized devices due to their high energy density. $LixCoO_2$ has been studied as a cathode material for the Li-ion battery. However, the limitation of its capacity impedes the development of high capacity cathode materials with Ni, Mn, etc. in them. The substitution of Mn and Ni for Co leads to the formation of solid solution phase $LiNi_xMn_yCo_{1-x-y}O_2$ (NMC, both x and y < 1), which shows better battery performance than unsubstituted $LiCoO_2$. However, despite a high discharge capacity in the Ni-rich compound (Ni > 0.8 in the metal site), poor cycle retention capability still remains to be overcome. In this study, aiming to improve the stability of the physical and chemical bonding, we investigate the stabilization effect of Ca in the Ni-rich layered compound $Li(Ni_{0.83}Co_{0.12}Mn_{0.05})O_2$, and then Ca is added to the modified secondary particles to lower the degree of cationic mixing of the final particles. For the optimization of the final grains added with Ca, the Ca content (x = 0, 2.5, 5.0, 10.0 at.%) versus Li is analyzed.

• Proceedings of the KIPE Conference
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• 2017.11a
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• pp.161-162
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• 2017

배터리 팩에 사용되는 리튬이온 배터리는 셀의 양극활물질에 따라 특성이 다르다. 배터리 팩의 효율적 운용을 위해 단위 셀간 편차를 최소화 하는 것이 필요하다. 본 논문에서는 양극활물질이 다른 고출력 및 고용량 리튬이온 배터리 세 종류를 선정하여 IR 및 OCV를 측정하고, 통계적 분석 기반 셀 스크리닝을 진행하여 결과를 비교 분석하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.05c
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• pp.299-305
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• 2003

The battery industries have been developed to the implementation of lithium ion secondary cell from the cell of Ni/Cd and Ni/MH in the past to be asked of an age of high technology from low technology. Also in resent the polymeric cell to get a good high function with an age of new advanced information system is changed from the 21 century to the secondary batteries society. The properties of lithium secondary batteries have the high energy density, the long cycle time, the low self discharge area and the high active voltage. The wanted properties of secondary batteries for the motion of an apparatuses of industries of an high skill age have a small type trend of the energy density and it is become with a strong asking of the industrial society market about the storable medium of the convenience and new power energy. The electrochemical properties is researched for the cell to be synthesised and crystallized the positive active material LiMnO2 of the secondary cell at 9250C to get a new improved data of the electric discharge for that the capacitance of the LiMnO2 thin film that is improving and researching with the properties and a merit and demerit in the this kind of asking.

• Proceedings of the KIPE Conference
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• 2016.07a
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• pp.311-312
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• 2016

본 논문에서는 사이즈가 다른 고출력 원통형 리튬이온 배터리의 Remaining Useful Life(RUL)을 방전용량 기반으로 전기적 특성분석을 실시하였다. 우선, 배터리의 충/방전이 계속될 시 용량이 어떻게 변화하는지 실험해보았으며, 만충 전압(Fully Charged)에서 만방 전압(Fully Discharged) 까지의 각각의 State-Of-Charge(SOC)에서 Hybrid Pulse Power Characterization (HPPC) Test를 이용해 충전 저항과 방전 저항을 구하여, 용량과 저항의 관계를 파악하였으며, 배터리 RUL을 알기 위한 기본 정보를 확보했다.

• Proceedings of the KIPE Conference
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• 2019.07a
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• pp.424-425
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• 2019

본 논문은 1차 RC 등가회로를 이용하여 리튬이온 배터리의 저항성 발열인 비가역 발열의 파라미터를 제시하였다. 발열 추정을 위해 1 C-rate에서 HPPC(Hybrid Pulse Power Characterization) 실험을 통하여 비가역 발열의 파라미터인 SOC 5%별 내부 저항을 추출하였다. 추출된 SOC 5%별 저항을 이용하여 1C-rate에서 3C-rate로 변화하는 조건에서 열 추정 성능을 확인하였다. 높은 C-rate로 방전 전류가 변화하는 상황에서 발열 시뮬레이션과 실험값을 비교하였으며, 1C-rate의 HPPC 실험에서 얻어진 내부 저항이 부하의 변동에 따른 리튬이온 배터리의 발열 추정 파라미터로써 사용될 수 있음을 검증하였다.

• Korean Journal of Materials Research
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• v.19 no.2
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• pp.73-78
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• 2009

This study investigated the dependence of the various sputtering conditions (Ar pressure: $2{\sim}10\;mTorr$, Power: $50{\sim}150\;W$) and thickness ($50{\sim}1200\;nm$) of Si thin film on the electrochemical properties, microstructural properties and the capacity fading of a Si thin film anode. A Si layer and a Ti buffer layer were deposited on Copper foil by RF-magnetron sputtering. At 10 mTorr, the 50 W sample showed the best capacity of 3323 mAh/g, while the 100 W sample showed the best capacity retention of 91.7%, also at 10 mTorr. The initial capacities and capacity retention in the samples apart from the 50W sample at 10 mTorr were enhanced as the Ar pressure and power increased. This was considered to be related to the change of the microstructure and the surface morphology by various sputtering conditions. In addition, thinner Si film anodes showed better cycling performance. This phenomenon is caused by the structural stress and peeling off of the Si layer by the high volume change of Si during the charge/discharge process.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.6
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• pp.403-408
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• 2016

Lithium-ion batteries are commonly employed in hybrid electric vehicles (HEVs), and achieving high energy density in the battery has been one of the most critical issues in the automotive industry. Because liquid cooling containing antifreeze is important in automotive batteries to enable cold starts, an effective geometric configuration for high-cooling performance should be carefully investigated. Battery cooling with antifreeze has also been considered to realize successful cold starts. In this article, we theoretically investigate a specific property of an antifreeze cooling battery system, and we perform numerical modeling to satisfy the required thermal specifications. Because a typical battery system in HEVs consists of multiple stacked battery cells, the cooling performance is determined mainly by the special properties of antifreeze in the coolant passage, which dissipates heat generated from the battery cells. We propose that the required cooling performance can be realized by performing numerical simulations of different geometric configurations for battery cooling. Furthermore, we perform a theoretical analysis as a design guideline to optimize the cooling performance with minimum power consumption by the cooling pump.

• Korean Journal of Materials Research
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• v.33 no.6
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• pp.257-264
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• 2023

To develop a high capacity lithium secondary battery, a new approach to anode material synthesis is required, capable of producing an anode that exceeds the energy density limit of a carbon-based anode. This research synthesized carbon nano silicon composites as an anode material for a secondary battery using the RF thermal plasma method, which is an ecofriendly dry synthesis method. Prior to material synthesis, a silicon raw material was mixed at 10, 20, 30, 40, and 50 wt% based on the carbon raw material in a powder form, and the temperature change inside the reaction field depending on the applied plasma power was calculated. Information about the materials in the synthesized carbon nano silicon composites were confirmed through XRD analysis, showing carbon (86.7~52.6 %), silicon (7.2~36.2 %), and silicon carbide (6.1~11.2 %). Through FE-SEM analysis, it was confirmed that the silicon bonded to carbon was distributed at sizes of 100 nm or less. The bonding shape of the silicon nano particles bonded to carbon was observed through TEM analysis. The initial electrochemical charging/discharging test for the 40 wt% silicon mixture showed excellent electrical characteristics of 1,517 mAh/g (91.9 %) and an irreversible capacity of 133 mAh/g (8.1 %).

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.5
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• pp.298-302
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• 2016

In this work, $LiMn_2O_4$ and $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ cathode materials are mixed by some specific ratios to enhance the practical capacity, energy density and cycle performance of battery. At present, the most used cathode material in lithium ion batteries for EVs is spinel structure-type $LiMn_2O_4$. $LiMn_2O_4$ has advantages of high average voltage, excellent safety, environmental friendliness, and low cost. However, due to the low rechargeable capacity (120 mAh/g), it can not meet the requirement of high energy density for the EVs, resulting in limiting its development. The battery of $LiMn_2O_4-LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (50:50 wt%) mixed cathode delivers a energy density of 483.5 mWh/g at a current rate of 1.0 C. The accumulated capacity from $1^{st}$ to 150th cycles was 18.1 Ah/g when the battery is cycled at a current rate of 1.0 C in voltage range of 3.2~4.3 V.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.357-360
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• 2005

Hyundai Motor Company developed the second generation of fuel cell hybrid electric vehicle based on Tucson SUV in 2004. This vehicle has cold start capability below -10C and its driving performances including maximum speed and accelerating time are almost similar to conventional Tucson SUV's performances without any sacrifice in terms of cabin space. Especially. the cold start capability was realized by utilizing only internal power sources such as fuel cell power and high voltage lithium ion polymer battery. In this paper, we will briefly introduce specifications of Tucson FCEV and its driving performances based on field test and simulations.