• Title/Summary/Keyword: High-density polyethylene

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Properties of Conductive Polymer Composite Films Fabricated under High Intensity Electric Fields : Effect of CF Sizing Treatment (고전기장을 이용한 전도성 고분자 복합필름의 제조 및 특성 연구 : 탄소섬유 Sizing처리가 탄소섬유/폴리에틸렌 필름의 특성에 미치는 영향)

  • 고현협;김중현;임순호;김준경;최철림
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.293-301
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    • 2001
  • Electrically conductive carbon fiber/high density polyethylene (CF/HDPE) composite films were fabricated by new method, so called electron-ion technology (EIT) and the effects of CF epoxy sizing on the volumetric resistivity. tensile strength and interphase properties of the films were investigated. While epoxy sizing increased conductivity of composite films resulting from enhanced tunneling effect it reduced interphase adhesion between CF and HDPE because polar epoxy sizing and nonpolar HDPE are incompatible. Consequently epoxy sized CF(CF(S)) caused significant reduction in the volumetric resisitivity and tensile strength of composite films when compared with unsized CF(CF(U)). Epoxy sizing reduced nucleating efficiency of CF(S), therefore CF(S)/HDPE composite films showed nonuniform transcrystalline layer when compared with CF(U)/HDPE composite films.

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Pigment Influence in High Density Polyethylene Electrical Strength (고밀도 폴리에틸렌에 있어서 전계의 세기의 영향)

  • Yun, Ju-Ho;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.331-332
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    • 2007
  • In this work, the TiO2 pigment influence in HDPE dielectric strength was analyzed. Chemical and structural characterizations were made to identify changes during the processing and your influence in the electrical properties, formulations containing 0, 0.5, 1, 2.5, 4 and 6 of titanium dioxide were processed by extrusion and injection molding with stabilization-antioxidants, ultraviolet stabilizers and plasticizers. The electrical strength tests were analyzed by the statistical distribution of Weibull, and the maximum likelihood method. The high concentrations present lower values to electrical strength. The parameter could be using to insulator panicles dispersion. The TiO2 concentration variation shows that these incorporations implicate strength values increase has a maximum (5,35MV/cm). High pigment concentration induces a little falls in property values. Observing the parameter, minimum experiment electric field (Ebmin) and electric strength value, found that the best electric perform formulation was the formulation with 2.5% TiO2 weight.

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A Research Trend on High Density Polyethylene Electrical Strength (고밀도 폴리에틸렌의 전계 세기의 영향에 관한 연구 동향)

  • Yoon, Hee-Kwang;Kim, Chan-Ho;Her, In-Ho;Lee, Jeong-Soo;Hwang, Jong-Sun;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1982-1983
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    • 2007
  • In this work, the $TiO_2$ pigment influence in HDPE dielectric strength was analyzed. Chemical and structural characterizations were made to identify changes during the processing and your influence in the electrical properties. Formulations containing 0, 0.5, 1, 2.5, 4 and 6 of titanium dioxide were processed by extrusion and injection molding with stabilization-antioxidants, ultraviolet stabilizers and plasticizers. The electrical strength tests were analyzed by the statistical distribution of Weibull, and the maximum likelihood method. The high concentrations present lower values to electrical strength. The ${\beta}$ parameter could be using to insulator particles dispersion. The TiO2 concentration variation shows that these incorporations implicate strength values increase has a maximum (5,35MV/cm). High pigment concentration induces a little falls in property values. Observing the ${\beta}$ parameter, minimum experiment electric field (Ebmin) and electric strength value, found that the best electric perform formulation was the formulation with 2.5% TiO2 weight.

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Rheological and Debinding Properties of Al2O3/Paraffin Wax/High Density Polyethylen System Mixture by Injection Molding (사출성형에 의한 Al2O3/Paraffin Wax/High Density Polyethylen계 혼합물의 유동성 및 탈지 특성)

  • 김승겸;신대용;한상목;강위수
    • Journal of the Korean Ceramic Society
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    • v.41 no.5
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    • pp.395-400
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    • 2004
  • The effects of compositions of binders on the rheological properties of mixtures and the preparation conditions on the formation of defects and the debinding characteristics of compacts for the injection molding of ceramic powders (65 wt% aluminaㆍ35 wt% feldspar) were studied. Ceramic powders were coated with 2 wt% of stearic acid and then mixed with 15, 20, and 25 wt% of Paraffin Wax (PW) and High Density Polyethylene (HDPE) as binders at $160^{\circ}C$ for 2 h. Rheological properties were investigated by using capillary rheometer. Apparent viscosities of mixtures were 80∼300 Paㆍs at 1,000$s^{-1}$ of a shear rate, it was good for the injection molding and depending on the compositions of binders. Short shot was formed at 15H5P5 (the ratio of HDPE : PW=5 : 5 in 15 wt% of binders) compacts without injection pressures and any noticeable defects were not formed at 45 kgf/$cm^{2}$ in 20H5P5 compacts. PW and HDPE were removed by the solvent extraction and thermal debinding method. Thermal debinding of HDPE at $450^{\circ}C$ for 5 h, which followed the extraction of PW was using n-heptane solvent at $70^{\circ}C$ for 5 h. Continuous pores in compacts, which facilitate the removal of HDPE by the thermal debinding, were found to form in the compacts when PW was removed by the solvent extraction. The optimum composition of binder at which binder was removed by thermal debinding without defects while maintaining the compact strength was 20H5P5. Bulk density, porosity and 3-point bending strength of 20H5P5 compact sintered at 1,30$0^{\circ}C$ for 5 h were 2.8, < 3%, and 2,400 kgf/$cm^{2}$, respectively, and can be used as a structural materials.

Preparation and physical properties of flame retardant high density polyethylene utilizing inorganic waste shell powder (재활용(再活用) 굴 껍질 분말(粉末)을 이용(利用)한 고밀도 폴리에틸렌계 난연 소재(素材)의 제조(製造)와 물성(物性))

  • Choi, Jae-Won;Cho, Tae-Keun;Ahn, Jun-Hyung;Lee, Sung-Ho;Chung, Yong-Chan;Jeon, Ho-Seok;Chun, Byoung-Chul
    • Resources Recycling
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    • v.17 no.4
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    • pp.21-29
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    • 2008
  • Waste shell powder was added to the high density polyethylene(HDPE), and resultant mechanical properties and flame retardancy were analyzed in terms of shell content. Compatibilizer(PE-g-MA) was used to enhance the mechanical properties of the prepared HDPE/shell composites, and several flame retardant agents($Al_2O_3$, $Sb_2O_3$) were utilized to improve flame retardancy. Addition of the compatibilizer resulted in an improved mechanical properties due to the increased interfacial bonding between HDPE matrix and shell powder. In the case of impact strength, it even reached to the impact strength of pure HDPE. Also the addition of the flame retardant agents did not exhibit mechanical property decrease. UL-94 flammability test on the prepared HDPE/shell composites indicated that at 40wt% of shell only inclusion, time to ignite the flame and the total time of flame duration increased. When flame retardant agents mixed with shell powder were added to the HDPE matrix, improved flame retardancy was observed. Generally, flame retardancy effect of $Al_2O_3$ was better than $Sb_2O_3$. UL-94 V-0 classification was observed for the specimens with $Al_2O_3$ and compatibilizer at more than 40wt% shell, and also for specimens with $Sb_2O_3$ and compatibilizer at all shell content.

A Study on Flammability and Mechanical Properties of HDPE/EPDM/Boron Carbide/Triphenyl Phosphate Blends with Compatibilizer (HDPE/EPDM/Boron Carbide/Triphenyl Phosphate 블렌드의 상용화제 첨가에 따른 난연성 및 기계적 물성 연구)

  • Shin, Bum-Sik;Jung, Seung-Tae;Jeun, Joon-Pyo;Kim, Hyun-Bin;Oh, Seung-Hwan;Kang, Phil-Hyun
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.549-554
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    • 2012
  • It was known that triphenyl phosphate wasn't homogeneously dispersed in HDPE/EPDM/boron carbide blends, which caused the decrease in mechanical properties. HDPE, EPDM, boron carbide, and triphenyl phosphate were blended with PE-g-MAH(polyethylene-graft-maleic anhydride) as a compatiblizer for improving the miscibility of triphenyl phosphate. Tensile strength of HDPE/EPDM/boron carbide blends decreased with increasing the contents of triphenyl phosphate for flammability. However, the mechanical properties of HDPE/EPDM/boron carbide/triphenyl phosphate blends increased by the addition of compatiblizer because triphenyl phosphate was homogeneously mixed in the blend system. The homogeneous dispersibility of triphenyl phosphate was confirmed by using scanning electron microscopy (SEM). Increased thermal stability and flammability derived from high miscibility of triphenyl phosphate were confirmed by the results of thermogravimetric analysis (TGA) and limiting oxygen index (LOI). A self-extinguishing HDPE/EPDM/boron carbide/triphenyl phosphate blend was successfully fabricated with more than 21% LOI.

Changes in Freshness of Endive (Cichorium endivia L.) by Different Packaging Types (엔다이브 포장방법에 따른 저장 중 선도 변화)

  • Kim, Young Mi;Lee, Do Hyun;Jeong, Jae Young;Jang, Seong Ho;Lee, Youn Suk;Chang, Min-Sun;Lee, Jung-Soo
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.22 no.3
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    • pp.71-77
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    • 2016
  • The effect of packaging material in enhancing the shelf life and maintaining the postharvest quality of endive (Cichorium endivia L.) was studied. Endive were packed in three packaging materials: paper box (control); paper box with endive wrapped in high density polyethylene (HDPE) film; and plastic box container covered with high density polyethylene (HDPE) film. The quality characteristics, such as fresh weight loss, soil plant analysis development (SPAD) value, and appearance of endive were investigated during 20 days of storage at $2^{\circ}C$. The endive wrapped with HDPE film inside the paper box showed the lowest weight loss, highest SPAD value and the best appearance compared to those wrapped in other packaging types during storage. The results indicate that the marketability of endive can be optimized with proper packaging and storage.

Stress Distribution in Microvascular Anastomotic Coupler (AnaFix®) Micropins with Respect to the Fillet Radius (필렛효과에 따른 미세혈관 문합커플러(AnaFix®) 마이크로핀의 응력분포)

  • Jee, Dae-Won;Kim, Cheol-Woong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1139-1145
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    • 2011
  • An automated anastomotic ring-pin system consisting of both the anastomotic ring-pin system and the coupler device has eliminated the drawbacks of the suture method. High density polyethylene (HDPE), a material with outstanding biocompatibility and injection molding capability, was used in the ring. SUS316 stainless steel, Ti-6Al-4Nb, Ti-6Al-4V, and unalloyed titanium were used in FEM simulations of the micropin. The authors categorized the microvascular anastomotic ring micropins into short neck (SN) and long neck (LN) groups in order to evaluate the effect of the micropin's fillet radius and neck length on the von Mises stress. The micropins were further divided into those with and without fillet. On the basis of the fillet radius rate (FRR), which represents the rate of change in the von Mises stress with respect to the availability and shape of the fillet, and the neck length rate (NLR), which represents the rate of change in the von Mises stress with respect to changes in the length of the neck within the fillet shape, it can be concluded that the SN-3 neck design is the most stable.

Preparation and characterization of high density polyethylene/silane treated pulverized-phenol resin composites (고밀도 폴리에틸렌과 실란 처리된 분쇄페놀수지 복합재의 제조 및 특성)

  • Park, Jun-Seo;Han, Chang-Gue;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.27-33
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    • 2016
  • Phenolic resin has excellent heat resistance and good mechanical properties as a thermosetting resin. However, its thermosetting characteristics cause it to produce a non-recyclable waste in the form of sprue and runner which is discarded and represents up to 15~20% of the overall products. Forty thousand tons of phenolic resin sprue and runner are disposed of (annually). The (annual) cost of such domestic waste disposal is calculated to be 20 billion won. In this study, discarded phenol resin scraps were pulverized and treated by silanes to improve their interfacial adhesion with HDPE. The sizes of the pulverized pulverulent bodies and fine particles were (100um~1000um) and (1~100um), respectively. The pulverized phenol resin was treated with 3-(methacryloyloxy) propyltrimethoxysilane and vinyltrimethoxy silane and the changes in its characteristics were evaluated. The thermal properties were evaluated by DSC and HDT. The mechanical properties were assessed by a notched Izod impact strength tester. When the silane treated phenol resin was added, the heat distortion temperature of HDPE increased from $77^{\circ}C$ to $96^{\circ}C$ and its crystallinity and crystallization temperature also increased. Finally, its impact strength and tensile strength increased by 20% and 50%, respectively, in comparison with the non-treated phenol resin.

Changes in Variety and Cultural Practices of Rice Since 1962 in Korea (수도품종 및 재배기술의 1962년 이후 변천)

  • Jong-Hoon Lee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.27 no.4
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    • pp.439-451
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    • 1982
  • In fact, rice cultivation technique from 1962 to 1970 was very slight, but this technique from 1970 to now was remarkably developed in Korea, it was due to development of high fretilizer responsive and lodging resistant variety, Tongil; ie. Ind. ${\times}$ Japonica remote-cross rice variety. The main factors of this development is as follow: Firstly the most farmer (more than 90%) used newly developed seedling growth method; polyethylene film covered protected nursery bed. Secondly date of transplanting (middle or late part. of May) was earlier 10-15days than before 1970. Thirdly new varieties were highly lodging resistant at high fertilizer level $(N-P_2O_5-K_2O:15-9-11 kg/l0a)$. However, this level is 50% increased one than it for Japonica varieties. At forth planting density increased up to 75-80 hills per $3.3m^2$. Added to these factors, farm labor shortage and wage increase due to economic development gave a chance for introduction of transplanting machine to farmer in 1977. It's use increased for 100, 800 ha in 1981. The most of farmers are using herbicides and weed control system dependoing on wood composition has been established and disseminated to farmer.

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