• 제목/요약/키워드: High temperature tensile property

검색결과 139건 처리시간 0.023초

Compatibility of biodegradable poly (lactic acid) (PLA) and poly (butylene succinate) (PBS) blends for packaging application

  • Bhatia, Amita;Gupta, Rahul K.;Bhattacharya, Sati. N.;Choi, H.J.
    • Korea-Australia Rheology Journal
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    • 제19권3호
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    • pp.125-131
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    • 2007
  • Biodegradable polymeric blends are expected to be widely used by industry due to their environmental friendliness and comparable mechanical and thermal properties. Poly (lactic acid) (PLA) and poly (butylene succinate) (PBS) are such biodegradable polymers which aim to replace commodity polymers in future applications. Since cost and brittleness of PLA is quite high, it is not economically feasible to use it alone for day to day use as a packaging material without blending. In this study, blends of PLA and PBS with various compositions were prepared by using a laboratory-scale twin-screw extruder at $180^{\circ}C$. Morphological, thermal, rheological and mechanical properties were investigated on the samples obtained by compression molding to explore suitability of these compositions for packaging applications. Morphology of the blends was investigated by scanning electron microscopy (SEM). Morphology showed a clear phase difference trend depending on blend composition. Modulated differential scanning calorimetry (MDSC) thermograms of the blends indicated that the glass transition temperature ($T_g$) of PLA did not change much with the addition of PBS, but analysis showed that for PLA/PBS blend of up to 80/20 composition there is partial miscibility between the two polymers. The tensile strength and modulus were measured by the Instron Universal Testing Machine. Tensile strength, modulus and percentage (%) elongation at break of the blends decreased with PBS content. However, tensile strength and modulus values of PLA/PBS blend for up to 80/20 composition nearly follow the mixing rule. Rheological results also show miscibility between the two polymers for PBS composition less than 20% by weight. PBS reduced the brittleness of PLA, thus making it a contender to replace plastics for packaging applications. This work found a partial miscibility between PBS and PLA by investigating thermal, mechanical and morphological properties.

제어압연.제어냉각기술로 제조된 냉간성형용 비조질강의 소재특성 (Study of Material Properties of High Strength Microalloyed Steel for Cold Forming by Controlled Rolling and Cooling Technology)

  • 김남규;박상덕;김병옥;안재영;최희진
    • 소성∙가공
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    • 제15권8호
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    • pp.603-608
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    • 2006
  • The main purpose of the present study has been placed on investigating the mechanical properties and microstructures of C-Si-Mn-V steels for cold forming manufactured by controlled rolling and cooling technology. The steels were manufactured in electric arc furnace (EAF) and casted to $160{\times}160mm$ billet. The billets were reheated in walking beam furnace and rolled to coil, the stocks were rolled by Controlled Rolling and Cooling Technology (CRCT), so rolled at low temperature by water spraying applied in rolling stage and acceleratly cooled before coiling. Rolled coils were cold drawed to the degree of 16%, 27% of area reduction respectively without heat treatment. Microstructual observation, tensile test, compression test and charpy impact tests were conducted. The mechanical properties of the steels were changed by area reduction of cold drawing and it is founded that there are optimum level of cold drawing to minimize compression stress for these steels. From the result of this study, it is conformed that $80kg_{f}/mm^{2},\;90kg_{f}/mm^{2}$ grade high strength microalloyed steel for cold forming are developed by accelerated cooling and optimum cold drawing.

폴리케톤 섬유의 염색 및 후가공 처리에 따른 기계적 물성에 관한 연구 (Study on the Mechanical Properties of Polyketone Fiber according to Dyeing and Finishing Process)

  • 김상룡;김경민;이원;이득진;황순동;양성용
    • 한국염색가공학회지
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    • 제29권2호
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    • pp.97-103
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    • 2017
  • Polyketone fiber, a newly developed high strength fiber, has a tenacity and modulus similar to the p-aramid fiber, and can be used for reinforcing mechanical rubber goods(MRG), such as tires, hoses, and technical textiles. It will be expected for replacement of super fiber such as aramids and increasing the technical textile market share. This paper surveys the mechanical properties of polyketone fiber for technical textiles. For this purpose, dyed polyketone fabric is prepared, mechanical properties of coated and uncoated polyketone fabrics such as tensile strength, elongation and tear strength were examined before and after weather resistance test(temperature $63{\pm}3^{\circ}C$, humidity 60%, amount of power $0.35w/m^2$). The differences of mechanical properties between uncoated and coated fabrics for high functional technical textiles and composite materials are estimated through this study. The UV-stability of polyketone fabric showed obvious improvement after coating. After 168h(7day) of UV exposure, the coated fabric showed less deterioration in mechanical properties with the retained tensile strength and elongation at break greater than 22 and 17% of the uncoated polyketone fabrics values, respectively.

고온상태에서 Al 7075 합금의 크리이프 파단수명 예측에 대한 연구 (A study on the Creep fracture life prediction of Al7075 alloy under high temperature)

  • 강대민;구양;백남주
    • 한국안전학회지
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    • 제3권2호
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    • pp.35-48
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    • 1988
  • Modern technological progress demands the use of materials at high temperature and high pressure. One of the most critical factors in considering such applications - perhaps the most critical one - is creep behavior. In this study the stress exponents n were determined during creep over the temperature range of $90^{\circ}C\;to\;500^{\circ}C$ (0.4 - 0.85 Tm) and stress range of 0.64 kgt/$mm^2$ in order to investigate the creep hehavior. The stress dependence of rapture time (n') were determined over the temperature range of $200^{\circ}C\;to\;240^{\circ}C$ and stress range of 8.13 kgt/$mm^2$ to 9.55 kgt/$mm^2$ in order to investigate to creep rupture property. And the stress transient dip tests were also carried out for the internal stress ${\sigma}i$ over the temperature range of $90^{\circ}C\;to\;500^{\circ}C$ and stress range of 0.64kgt/$mm^2$ to 17.2 kgt/$mm^2$. The creep tests for constant temperature and stress transient dip tests were conducted in air with Al 7075 alloy under constant tensile load. At around the temperature range $200^[\circ}C\;-\;230^{\circ}C$ and the stress level 8.13 - 9.55 (kgt/$mm^2$), the temperature range $280^{\circ}C\;-\;310^{\circ}C$ and the stress level 1.85 - 2.55 (kgt/$mm^2$), the temperature range $380^{\circ}C\;-\;410^{\circ}C$ and the stress 1.53 - 0.91 (kgt/$mm^2$), the stress exponent in had the value of 6.2 - 6.65 but at around the temperature range $90^{\circ}C\;-\;120^{\circ}C$ and the stress level 10 - 17.2(kgt/$mm^2$), the value of 1.3, and at around the temperature range $470^{\circ}C\;-\;500^{\circ}C$, the stress level 0.62 - 1.02 (kgt/$mm^2$) the value of 1-1. Besides these results, at around the temperature $200^{\circ}C\;-\;240^{\circ}C$ the stress dependence of rupture time (n') had the value of 6.3. Finally, it was found that the value n calculated by considering the applied stress dependence of the internal stress were in good agreement with those obtained for the creep test. Then, it was concluded that the change in n was mainly attributed to the difference of the applied stress dependence of the internal stress and the ratio of the internal stress to the applied stress, and the creep rupture life may be represented as.

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인발가공에 의해 제조된 전선용 Al-Fe-Mg-Cu-B계 합금의 기계적 및 전기적 특성 (Mechanical and Electrical Properties of an Al-Fe-Mg-Cu-B System Alloy for Electrical Wire Fabricated by Wire Drawing)

  • 정창기;우츠노미야 히로시;손현택;이성희
    • 한국재료학회지
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    • 제27권11호
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    • pp.597-602
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    • 2017
  • In this study, an Al-0.7wt%Fe-0.2wt%Mg-0.2wt%Cu-0.02wt%B alloy was designed to fabricate an aluminum alloy for electrical wire having both high strength and high conductivity. The designed Al alloy was processed by casting, extrusion and drawing processes. Especially, the drawing process was done by severe deformation of a rod with an initial diameter of 12 mm into a wire of 2 mm diameter; process was equivalent to an effective strain of 3.58, and the total reduction in area was 97 %. The drawn Al alloy wire was then annealed at various temperatures of 200 to $400^{\circ}C$ for 30 minutes. The mechanical properties, microstructural changes and electrical properties of the annealed specimens were investigated. As the annealing temperature increased, the tensile strength decreased and the elongation increased. Recovery or/and recrystallization occurred as annealing temperature increased, and complete recrystallization occurred at annealing temperatures over $300^{\circ}C$. Electric conductivity increased with increasing temperature up to $250^{\circ}C$, but no significant change was observed above $300^{\circ}C$. It is concluded that, from the viewpoint of the mechanical and electrical properties, the specimen annealed at $350^{\circ}C$ is the most suitable for the wire drawn Al alloy electrical wire.

3.6%C 회주철의 진동감쇠능 및 기계적 성질에 미치는 주입온도 및 합금원소 첨가의 영향 (Effects of Pouring Temperature and Alloying Elements on Damping Capacity and Mechanical Properties in 3.6%C Grey Cast Iron)

  • 김정철;백승한;최종술
    • 열처리공학회지
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    • 제13권4호
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    • pp.231-238
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    • 2000
  • Flake graphite cast irons with the high damping capacity have been used for the control of vibration and noise occurring in the members of various mechanical structures under vibrating conditions. However, the damping capacity which is morphological characteristics of graphite is one of the important factors in reducing the vibration and noise, but hardly any work has deal with this problem. Therefore, the authors have examined the damping capacity of various cast irons with alloying elements and studied the influences of the matrix structures, mechanical properties and morphological characteristics of graphite. The main results obtained are as follows: Effects of pouring temperature on the damping capacities and mechanical properties were investigated in 3.6%C cast iron. At $1400^{\circ}C$, specific damping capacity showed the maximum value, and decreased with increase pouring temperature. Mechanical properties showed opposite trend with the damping capacity. And then, effects of Ni on the damping capacities and mechanical properties have been investigated in 3.6%C gray cast iron. At 0.2%Ni content, specific damping capacity showed the maximum value, and decreased with further increase in Ni content. Graphite length also showed same behavior. This indicates that the specific damping capacity has a close relation with graphite length. In case of Mo addition in 3.6%C-0.2%Ni cast iron, specific damping capacity and tensile strength was 27% and $20kgf/mm^2$ at 3.6%C-0.2%Ni-0.3%Mo cast iron respectively.

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고망간강 플랜지의 열간 단조 후 냉각방법에 따른 미세조직 및 기계적 특성 평가 (Evaluation of Microstructure and Mechanical Properties according to Cooling Method after Hot Forging of High Manganese Steel Flange)

  • 박민하;이강호;김병준;김병구
    • 한국재료학회지
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    • 제34권1호
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    • pp.44-54
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    • 2024
  • High-Manganese (Mn) austenitic steel, with over 24 wt% Mn content, offers outstanding mechanical properties in cryogenic settings, making it a potential replacement for existing cryogenic materials. This high manganese steel exhibits high strength, ductility, and wear resistance, making it promising for applications like LNG tanks, flanges, and valves. To operate in cryogenic environments, hot forging and heat treatment processes are vital, especially in flange production. The cooling rate during high-temperature cooling after hot forging plays a critical role in influencing the microstructure and mechanical properties of high manganese steel. The rate at which cooling occurs during this process influences the size of the grains and the distribution of manganese and consequently has an impact on mechanical properties. This study assessed the microstructure and mechanical properties based on different cooling rates during the hot forging of High-Mn steel flanges. Comparing air and water cooling after hot forging, followed by heat treatment, revealed notable differences in grain size. These differences directly impacted mechanical properties such as tensile strength, hardness, and Charpy impact property. Understanding these effects is crucial for optimizing the performance and reliability of High-Mn steel in cryogenic applications.

탄소 섬유 프리프레그의 압축 물성을 고려한 복합재 고온 압축 성형 해석 평가 (Evaluation of Compression Molding Simulation with Compression Properties of Carbon Fiber Prepreg)

  • 배대령;이정완;이진우;엄문광
    • Composites Research
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    • 제31권6호
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    • pp.421-428
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    • 2018
  • 프리프레그 압축 성형(PCM, Prepreg Compression Molding) 공정을 최적화 하기 위해서 성형 해석을 통해 공정 시 나타날 문제를 사전에 예측할 필요가 있다. 해석 정확도를 높이기 위해서는 성형 물성을 구할 때 정확한 물성 측정이 필요하다. 그러나 대부분의 연구는 프리프레그의 압축 물성을 따로 구하지 않고 인장 물성과 동일하다고 가정하여 사용하고 있다. 따라서 본 연구에서는 성형 해석의 정확성을 높이기 위해 섬유의 면내 압축 물성 실험법을 제시했으며 측정 결과, 섬유의 압축 강성은 인장 강성에 비해 약 $10^{-2}$배 낮게 측정되었다. 실제 프리프레그의 성형성을 모사하기 위해 경사면($110^{\circ}$)을 갖는 정사각형 컵 금형을 설계 및 제작하였고 이를 이용한 프리프레그 고온 압축 성형성 평가를 수행하였다. 압축 물성 영향성 확인을 위해 금형 내 취약 지점으로 예상되는 각 코너 부근에서의 전단각을 측정하였으며 동일한 위치에서의 해석 결과와 실험 데이터를 비교하였다. 비교 결과 섬유의 압축 물성이 반영된 해석 결과에서 실험값과 유사한 패턴이 관찰되었으며 면내 압축 물성 반영이 성형 해석결과의 정확도를 향상시키는 것을 확인하였다.

표준화재조건 CFT기둥 내화성능예측을 위한 해석적 연구 (An Analytical Study on Prediction Fire Resistance of CFT Column in ISO Fire)

  • 김형준;김흥열
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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    • pp.257-260
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    • 2008
  • 강재요소의 경우엔 고온에 노출될 경우 높은 열전도성으로 인해 화재 발생상황에서 단면의 급격한 온도 상승으로 인한 강도저하 현상이 유발된다. 특히 CFT기둥의 경우엔 구조체의 인장응력을 외부의 강재부분이 전담하기 때문에, 내화성능을 확보하기 위하여 이 부분에 대한 강도저하 및 응력변화에 대한 수치해석적 검토가 선행되어야 한다. 이에 본 연구에서는 국내에서 수행한 콘크리트 및 강재의 고온재료물성 실험값을 토대로 유한요소해석법(ABAQUS)을 적용하여 CFT기둥의 화재거동을 예측하였다. 해석적용 강재는 SS400을 대상으로 하였으며, 내부 충진된 콘크리트의 강도를 40MPA와 50MPA를 변화시켜 전열특성 및 거동현상을 예측하였다. 표준화재 180분 노출조건으로 CFT기둥 해석결과 40MPA모델의 경우123mm의 변위가 발생하였으며, 50MPa모델의 경우 91mm의 수축량이 발생하는 것으로 해석되었다.

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Ca 첨가에 따른 Mg-4Al-2Sn-xCa 다이캐스팅 합금의 기계적특성 연구 (Effect of Ca additions on Mechanical Properties of Mg-4Al-2Sn-xCa Die-Casting Alloys)

  • 김영민;이영철;박용호
    • 한국주조공학회지
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    • 제31권5호
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    • pp.293-301
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    • 2011
  • Representative magnesium alloys applied to the die-casting are AZ91, AM60, etc., and the application of these alloys is restricted to components operating at moderate temperatures, due to grain boundary siding of ${\beta}$-phase($Mg_{17}Al_{12}$) at temperatures above $120^{\circ}C$. Heat-resistant magnesium alloys such as AE42, AE44 have been developed, but that have been too burdensome to produce because of the expensive rare earth materials. Research work for the development of low-priced heat-resistant magnesium alloy is actively in progress and positive results are being reported. This study aims to investigate the effect of Ca additions on mechanical properties of Mg-4Al-2Sn heat resistant magnesium alloys. Mg-4Al-2Sn alloys with Ca (0wt.%, 0.3wt.%, 0.7wt.%, 1wt.%) have been produced through the die-casting process for the development of low-priced heat-resistant magnesium alloy, and high temperature tensile tests are performed using the specimens. The results showed that mechanical properties of Mg-4Al-2Sn-xCa increased with the addition of Ca up to 0.7wt.% Ca and further addition of Ca deteriorated the mechanical properties of the alloys. A significant amount of porosity was observed at the sample with 1wt%. Ca and the longer freezing range of the alloy was believed to cause the formation of porosity.