• 제목/요약/키워드: High temperature stability

검색결과 1,956건 처리시간 0.04초

세라마이드의 액정에멀젼 내 고온 제형 안정성 연구 (Study on Stability of Ceramides in Liquid Crystalline Emulsions at High Temperature)

  • 홍성윤;장유진;이준배;박천호;박명삼
    • 대한화장품학회지
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    • 제45권1호
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    • pp.1-7
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    • 2019
  • 본 연구는 세테아릴 알코올, 세틸 팔미테이트, 소르비탄 팔미테이트, 소르비탄 올리베이트, 세라마이드 등을 이용하여 제조한 액정에멀젼의 다층구조에 따른 강화된 계면막에 의해 제형의 안정성이 확보됨을 확인하였다. 편광 현미경을 통해 제형 내 몰타 크로스(maltese cross) 무늬를 확인하고, cryo-SEM을 이용하여 다층구조가 형성되었음을 확인하였다. 소각 X선 산란법(SAXS)을 이용하여 라멜라 구조 생성여부를 확인하였으며, 점도계를 이용하여 점도변화를 확인하고 정적 광 산란법(SLS)을 이용하여 입도 분포를 확인하여 액정에멀젼의 제형 안정성을 입증하였다.

Stability and nonlinear vibration of a fuel rod in axial flow with geometric nonlinearity and thermal expansion

  • Yu Zhang;Pengzhou Li;Hongwei Qiao
    • Nuclear Engineering and Technology
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    • 제55권11호
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    • pp.4295-4306
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    • 2023
  • The vibration of fuel rods in axial flow is a universally recognized issue within both engineering and academic communities due to its significant importance in ensuring structural safety. This paper aims to thoroughly investigate the stability and nonlinear vibration of a fuel rod subjected to axial flow in a newly designed high temperature gas cooled reactor. Considering the possible presence of thermal expansion and large deformation in practical scenarios, the thermal effect and geometric nonlinearity are modeled using the von Karman equation. By applying Hamilton's principle, we derive the comprehensive governing equation for this fluid-structure interaction system, which incorporates the quadratic nonlinear stiffness. To establish a connection between the fluid and structure aspects, we utilize the Galerkin method to solve the perturbation potential function, while employing mode expansion techniques associated with the structural analysis. Following convergence and validation analyses, we examine the stability of the structure under various conditions in detail, and also investigate the bifurcation behavior concerning the buckling amplitude and flow velocity. The findings from this research enhance the understanding of the underlying physics governing fuel rod behavior in axial flow under severe yet practical conditions, while providing valuable guidance for reactor design.

자전연소합성법에 의해 제조된 BaTiO3 분말의 소결특성에 미치는 첨가제의 영향 (The Effect of Adittives on the Sintering Properties of Barium Titanate Powder Prepared by Self-propagating High-temperature Synthesis)

  • 임성재;신창윤;원형일;원창환
    • 한국분말재료학회지
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    • 제13권2호
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    • pp.129-137
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    • 2006
  • In this study, high purity fine $BaTiO_3$ powders were prepared by SHS (Self-propagating High-temperature Synthesis). We would examinate the study of sintering properties and characteristics as a function of temperature with various additives (binder, sintering agent). In separately binder addition, the green and sintered density of specimen were increased as binder content increases. The increased porosity resulted in fine grain size due to the inhibition of grain boundary moving. The $Al_{2}O_{3},\;TiO_{2}$ and MgO playa role of increasing dielectric constants at room temperature. These values were decreased at curie temperature. In case of $SiO_2$, the Curie temperature was decreased. In this study, a high dielectric ceramic capacitor material with temperature stability was synthesized by using various additives.

촉매연소 시스템 안정화 : 고온용 열교환기를 이용한 능동제어 (Catalytic Combustion System Stability:Active Control with High Temperature Heat Exchanger)

  • 유상필;송광섭
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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    • pp.65-69
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    • 2002
  • Catalytic combustion known as one of the traditional oxidation methods of VOC gas is restricted to its applicable fields because of its reaction characteristics. But recently innovative improvement of catalytic endurance makes its applicable range broader from MEMs to industrial power generation. Therefore, control technologies based on the catalytic combustion characteristics are researched and developed dynamically. Especially, the stable control of catalytic combustion is an essential factor in a view of maximizing its efficiency. In this research, the fuel equivalence ratio and the preheating temperature of mixture gas is controlled by catalytic combustion system enhanced in heat transfer with high temperature heat exchanger. As a result, the combustion characteristics of system was investigated, and both passive and active control type were compared and analyzed.

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고온 PEFC용 수소이온 전도 향상을 위한 가교된 이온성 액체를 갖는 세공충진막 (Pore-filling membrane with ionic liquids immobilized by cross-linking for high temperature PEFCs)

  • 백지숙;최영우;이미순;양태현;김창수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 추계학술대회 초록집
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    • pp.80.2-80.2
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    • 2010
  • The development of high temperature-proton exchange fuel cell (HT-PEFC) is a key in solving the problem of carbon monoxide poisoning of the platinum at anode as well as water management in PEFCs operated below $90^{\circ}C$. In order to overcome these main issues, PEFCs must be operated at high temperature above $120^{\circ}C$. Ionic liquids are available for HT-PEFC due to exhibiting non-volatility and thermal stability. Ionic liquids are however leached out from polymeric matrix resulting in the increase of gas permeability. In this study, we have prepared and characterized the composite membranes with the ionic liquids consisting of 1-(4-vinylbenzyl)-3-butyl imidazolium chloride immobilized by the cross-linkers in pore-filling membrane to prevent to be leached out from the membrane. We confirmed that cross-linked ionic liquids were not leached out from the composite membranes through the various characteristic analyses. It was also verified that the prepared membranes are thermally stable from the result of TG analysis. The pore-filling membranes with the immobilized ionic liquids have a high proton conductivity over $10^{-2}$ S/cm at high temperature (> $120^{\circ}C$).

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고온단시간 처리에 따른 저장 중 참당귀의 품질 특성 (Quality Characteristics of Angelica gigas Nakai in Response to High-Temperature-Short-Time Treatment during Storage)

  • 이은숙;지윤정;이지연;최수지;이승은;김형돈;최재훈;강민혜;김동휘;장귀영
    • 한국식품영양학회지
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    • 제33권6호
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    • pp.645-654
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    • 2020
  • Angelica gigas Nakai (A. gigas) easily changes its color during storage, and appropriate thermal treatment can improve storage stability through inactivation of enzymes such as polyphenol oxidase. Therefore, this study was performed to determine quality characteristics of dried A. gigas in response to high-temperature-short-time (HTST) treatment during storage. Dried A. gigas were treated at 120-180℃ for 10 min, the samples were stored at 4℃ and 50℃ for 10 weeks, and used for the analysis of qualities. Concerning the color values, the sample treated at 120℃ was similar to the control, and the color change was large when treated above 180℃. However, color difference (ΔE⁎ab) was lower in treated samples than in control. Browning index was similar for all the samples except for the sample treated at 180℃. Functional qualities (phenolics content, antioxidant activities, and level of major components) showed a slight difference according to storage periods in all samples without control, and nodakenin content was observed in control. The results of this study showed that HTST treatment improved storage stability such as stability of colors and browning index in dried A. gigas during storage, and the appropriate treatment temperature was 120℃ in terms of stability in color and browning index.

Simple Route to High-performance and Solution-processed ZnO Thin Film Transistors Using Alkali Metal Doping

  • 김연상;박시윤;김경준;임건희
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.187-187
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    • 2012
  • Solution-processed metal-alloy oxides such as indium zinc oxide (IZO), indium gallium zinc oxide (IGZO) has been extensively researched due to their high electron mobility, environmental stability, optical transparency, and solution-processibility. In spite of their excellent material properties, however, there remains a challenging problem for utilizing IZO or IGZO in electronic devices: the supply shortage of indium (In). The cost of indium is high, what is more, indium is becoming more expensive and scarce and thus strategically important. Therefore, developing an alternative route to improve carrier mobility of solution-processable ZnO is critical and essential. Here, we introduce a simple route to achieve high-performance and low-temperature solution-processed ZnO thin film transistors (TFTs) by employing alkali-metal doping such as Li, Na, K or Rb. Li-doped ZnO TFTs exhibited excellent device performance with a field-effect mobility of $7.3cm^2{\cdot}V-1{\cdot}s-1$ and an on/off current ratio of more than 107. Also, in case of higher drain voltage operation (VD=60V), the field effect mobility increased up to $11.45cm^2{\cdot}V-1{\cdot}s-1$. These all alkali metal doped ZnO TFTs were fabricated at maximum process temperature as low as $300^{\circ}C$. Moreover, low-voltage operating ZnO TFTs was fabricated with the ion gel gate dielectrics. The ultra high capacitance of the ion gel gate dielectrics allowed high on-current operation at low voltage. These devices also showed excellent operational stability.

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Ni기 초내열 합금 LESS 1의 합금설계 및 평가: I. 합금 설계 및 고온 상 안정성 평가 (Alloy Design and Properties of Ni based Superalloy LESS 1: I. Alloy Design and Phase Stability at High Temperature)

  • 윤정일;강병일;최봉재;김영직
    • 한국주조공학회지
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    • 제33권5호
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    • pp.215-225
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    • 2013
  • The alloys required for fossil power plants are altered from stainless steel that has been used below $600^{\circ}C$ to Ni-based alloys that can operate at $700^{\circ}C$ for Hyper Super Critical (HSC) steam turbine. The IN740 alloy (Special Metals Co. USA) is proposed for improved rupture strength and corrosion resistance at high temperature. However, previous studies with experiments and simulations on stable phases at about $700^{\circ}C$ indicated the formation of the eta phase with the wasting of a gamma prime phase, which is the most important reinforced phase in precipitation hardened Ni alloys, and this resulted in the formation of precipitation free zones to decrease the strength. On the basis of thermodynamic calculation, the new Ni-based superalloy named LESS 1 (Low Eta Sigma Superalloy) was designed in this study to improve the strengthening effect and structure stability by depressing the formation of topologically close packed phases, especially sigma and eta phases at high temperature. A thermal exposure test was carried out to determine the microstructure stability of LESS 1 in comparison with IN740 at $800^{\circ}C$ for 300 hrs. The experimental results show that a needle-shaped eta phase was formed in the grin boundary and it grew to intragrain, and a precipitation free zone was also observed in IN740, but these defects were entirely controlled in LESS 1.

소화성궤양시 병용약물이 수용액 중의 오메프라졸 안정성에 미치는 영향 (Effect of Other Medications on the Stability of Omeprazole in Aqueous Solution for the Peptic Ulcer Disease)

  • 이영재;황완균;조성완
    • 한국산학기술학회논문지
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    • 제10권11호
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    • pp.3494-3499
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    • 2009
  • 소화성 궤양의 치료에 일반적으로 병용되어 사용되는 소염진통제인 록소프로펜 또는 알칼리화제인 탄산수소나트륨을 함유한 수용액 중에서 소화성 궤양의 치료에 사용되는 오메프라졸의 안정성에 대한 영향이 실온상태에서 실험하였다. 록소프로펜과 탄산수소나트륨 각각 60 mg을 오메프라졸(600 ${\mu}g$/ml) 용액에 혼합한 후 그 용액을 실온 상태로 80시간 보존하면서 그 분해정도를 원래의 오메프라졸의 농도와 비교하여 각각의 소실 농도를 산출하였다. 오메프라졸의 농도와 크로마토그램의 면적비는 5 - 160 ${\mu}g$/ml 농도에서 상호 직선성을 나타내었고 상대 표준 편차는 3.05 %이하로서 분석이 제대로 이루어졌음을 확인할 수 있었으며 함유 약물과 시간에 따른 오메프라졸의 분해 양상은 가상의 일차 직선 속도식을 나타내는 것을 알 수 있었다. 결론적으로 오메프라졸은 탄산수소나트륨 또는 록소프로 펜과의 병용 투여에 의해 그 안정성이 영향을 받을 수 있다는 것을 확인할 수 있었다.

YSZ 전해질과 은 전극을 이용한 저온 산소센서에 대한 연구 (Oxygen sensor for the low temperature-measurement using yttria stabilized zirconia(YSZ) electrolyte and Ag electrode)

  • 양영창;박종욱
    • 센서학회지
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    • 제15권2호
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    • pp.97-101
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    • 2006
  • Silver electrode having a high Electrocatalytic activity is oxygen-permeable electrode, in which oxygen ad-atoms are adsorbed and moved toward YSZ electrolyte by bulk diffusion. It is the different point in comparison to usual porous electrodes, especially platinum, which react with oxygen only in TPBs(Three Phase Boundaries). Also ad-atoms at TPBs of Pt are diffused to YSZ electrolyte by interfacial diffusion mechanism. These properties were used for turning down the operating temperature of YSZ from over $600^{\circ}C$ to below $450^{\circ}C$. The different heat-treatment temperature between a working electrode and a reference electrode suppresses the formation of silver oxides and reduces a volatility of Ag as well. Above all, these own characteristics and special processes of Ag improved a long-term stability of a oxygen sensor.