• Title/Summary/Keyword: High temperature stability

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High Temperature Characteristics of Commercially Available Anion Exchange Membrane for Alkaline Water Electrolysis (알칼리 수전해를 위한 상용 음이온교환막의 고온 특성)

  • JANG, SU-YOEN;RYU, CHEOL-HWI;HWANG, GAB-JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.330-336
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    • 2022
  • In order to evaluate the possibility as a separator in alkaline water electrolysis, the high temperature characteristics were evaluated by measuring the membrane resistance and durability of 5 types of commercial anion exchange membranes in 7 M KOH solution and at 80℃. The membrane resistance of AEM membrane measured in 7 M KOH solution and at 80℃ had a lower value of about 8-24 times compared to the other membranes. The durability of AEM membrane tested with the soaking time in 7 M KOH solution and at 80℃ showed a very good stability and that of FAAM40 and FAAM75-PK showed secondly a good stability. The thermal stability with the soaking time in 7 M KOH solution and at 80℃ of FAAM40 and FAAM75-PK membrane analyzed by thermo-gravimetric analysis showed a good stability compared to the other membranes.

Development of Light-weight Fire Protection Materials Using Fly Ash and Light-weight Aggregate (플라이애시 및 경량골재를 활용한 경량 내화성 마감재료 개발)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu;Lee, Sea-Hyun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.95-102
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    • 2012
  • The serious issue of tall building is to ensure the fire resistance of high strength concrete. Therefore, Solving methods are required to control the explosive spalling. The fire resistant finishing method is installed by applying a fire resistant material as a light-weight material to structural steel and concrete surface. This method can reduce the temperature increase of the reinforcement embedded in structural steel and concrete at high temperature due to the installation thickness control. This study is interested in identifying the effectiveness of light-weight fire protection material compounds including the inorganic admixture such as fly ash, meta-kaolin and light-weight aggregate as the fire resistant finishing materials through the analysis of fire resistance and components properties at high temperature. Also, this paper is concerned with change in microstructure and dehydration of the light-weight fire protection materials at high temperatures. The testing methods of fire protection materials in high temperature properties are make use of SEM and XRD. The study results show that the light-weight fire resistant finishing material composed of fly ash, meta-kaolin and light-weight aggregate has the thermal stability of the slight decrease of compressive strength at high temperature. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction by the reason of the thermal analysis result not showing the decomposition of calcium hydrate. Developed light-weight fire protection materials showed good stability in high Temperatures. Thus, the results indicate that it is possible to fireproof panels, fire protection of materials.

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Computational thermal stability and critical temperature buckling of nanosystem

  • Chengda Zhang;Haifeng Hu;Qiang Ma;Ning Wang
    • Advances in nano research
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    • v.14 no.6
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    • pp.575-590
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    • 2023
  • Many of small-scale devices should be designed to tolerate high temperature changes. In the present study, the states of buckling and stability of nano-scale cylindrical shell structure integrated with piezoelectric layer under various thermal and electrical external loadings are scrutinized. In this regard, a multi-layer composite shell reinforced with graphene nano-platelets (GNP) having different patterns of layer configurations is modeled. An outer layer of piezoelectric material receiving external voltage is also attached to the cylindrical shell for the aim of observing the effects of voltage on the thermal buckling condition. The cylindrical shell is mathematically modeled with first-order shear deformation theory (FSDT). Linear elasticity relationship with constant thermal expansion coefficient is used to extract the relationship between stress and strain components. Moreover, minimum virtual work, including the work of the piezoelectric layer, is engaged to derive equations of motion. The derived equations are solved using numerical method to find out the effects of temperature and external voltage on the buckling stability of the shell structure. It is revealed that the boundary condition, external voltage and geometrical parameter of the shell structure have notable effects on the temperature rise required for initiating instability in the cylindrical shell structure.

Quality Assessment of Domestic Non-automatic Weighing Instruments for International Standards (국제표준에 대비한 국내 비자동저울의 품질평가에 관한 연구)

  • Namkoong Chai-Kwan;Kong Jae Hyang
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.13 no.6
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    • pp.127-134
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    • 2004
  • As the result of reduction of the barrier of national economy on matters of quality assurance of weighing instruments in recently, it is considering in domestic as well as international matters. Therefore, this study is to analysis and compare with international md national measuring standards on the electric self-indicating scale, to improve the quality of electronic machine by providing a reformation plan on currently problems of domestic manufactured, and to identify to introduce in domestic criteria from international standards. I had compared KSC 1313 to OIML R 76-1 as the performance assessment items, such as metrology Properties test, static temperature test, temperature effect testing under the un-load, electronic wave disturbance test, high-tempereature and high-humidity stability test and durability test. Therefore, only one company is passed all items of the test according to the international (reference) standards, but it is possible to improve the quality in general if it should be use the load cell and electric components which is stability of temperature change in order to supplementation to the static temperature test and temperature effect testing under the un-load. It is also possible to apply in the domestic with the OIML 76-1 after correcting the design.

Study of Tribological Characteristics Between Metallic Friction Materials and Brake Disk (금속계 마찰재와 제동디스크 간의 마찰특성 연구)

  • Kim, Sang-Ho;Lee, Hi-Sung
    • Journal of the Korean Society for Railway
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    • v.12 no.1
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    • pp.72-80
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    • 2009
  • The tribiological characteristics such as friction coefficient, friction stability, wear rate and braking temperature between various types of metallic friction materials and heat resistant steel disk, were investigated by using lab-scale dynamometer. Friction materials for high speed train have higher friction coefficient and friction stability as compared to aircraft friction materials even though friction materials for high speed train have lower wear rate. In addition. Cu-matrix friction materials have higher temperature increase rate than Fe-matrix friction materials. All friction surfaces have Fe-base oxide layer after completing test.

Enhancement of Thermal Stability in Photoluminescence by Carbonization of Porous silicon (다공성실리콘의 탄화를 이용한 PL의 열적안정성 증진)

  • 최두진;서영제;전희준;박홍이;이덕희
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.467-472
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    • 1997
  • Porous silicon was prepared by an anodic etching. The pore size was about 10 nm at an etching time of 20 sec and a current density of 20 mA/$\textrm{cm}^2$. The porous layer was composed of an micro-porous layer (0.6 ${\mu}{\textrm}{m}$) and a macro-porous layer (10 ${\mu}{\textrm}{m}$). Room temperature PL with maximum peak 6700$\AA$ appeared. The peak disappeared by an oxidation reaction when the porous silicon was heated to 100~20$0^{\circ}C$ in atmosphere. In order to avoid the oxidation a heat treatment was done in H2 atmosphere. The micro-pore and Si column, which formed quantum well, were collapsed by the high temperature. The PL maximum peak of heated sample was gradually red-shifted and showed about 300$\AA$ red-shift at 50$0^{\circ}C$. The intensity of PL was maintained to high temperatures in lower pressures. The porous Si was carbonized in C2H2+H2 gas in order to increase thermal stability. The carbonization of the porous Si prevented red-shift of the maximum PL peak caused by sintering effect at high temperatures, and the carbonized porous Si showed Pl signal at higher temperatures by above 20$0^{\circ}C$ than the sample in H2 atmosphere.

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Enhance Potential Stability of Organic Electrolyte in EDLC by Using Co-solvent and Its electrochemical properties. (전기 이중층 커패시터 적용을 목적으로 한 공용매상 전해액과 전기화학적 특성)

  • Lee, Hyeon-Seok;Yuk, Yeong-Jae;Kim, Han-Ju;Park, Su-Gil
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.164-164
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    • 2014
  • Characteristics of electrolyte are those; electrical stability, ion conductivity, viscosity, high temperature work, cell application. Theoretically, GBL has high oxidation voltage. Also, boiling point of GBL is $206^{\circ}C$ and flash point is over $280^{\circ}C$.

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Fabrication of Ceramic Thin Film Type Pressure Sensors for High-Temperature Applications and Their Characteristics (고온용 세라믹 박막형 압력센서의 제작과 그 특성)

  • 정귀상
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.790-794
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    • 2003
  • This paper describes the fabrication and characteristics of ceramic thin film type pressure sensors based on Ta-N strain gauges for high temperature applications. Ta-N thin-film strain gauges are deposited onto a thermally oxidized Si diaphragm by RF sputtering in an argon-nitrogen atmos[here($N_2$ gas ratio: 8%, annealing condition: 90$0^{\circ}C$, 1 hr.), patterned on a wheatstone bridge configuration, and used as pressure sensing elements with a high stability and a high gauge factor. The sensitivity is 1.097 ~ 1.21 mV/Vㆍkgf/$\textrm{cm}^2$ in the temperature range of 25 ~ 200 $^{\circ}C$ and the maximum non-linearity resistance), non-linearity than existing Si piezoresistive pressure sensors. The fabricated ceramic thin-film type pressure sensor is expected to be usefully applied as pressure and load sensors that os operable under high-temperature.

A Study on the Properties of Dicalcium Phosphate Dihydrate According to the Manufacturing Condition (제이인산(第二燐酸)칼슘의 제조조건(製造條件)에 따른 성상(性狀) 연구(硏究))

  • Lah, Woon-Lyong;An, Kyung-Ran;Han, Kwan-Sup;Lee, Gye-Joo
    • Journal of Pharmaceutical Investigation
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    • v.6 no.1
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    • pp.26-32
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    • 1976
  • Dicalcium phosphate dihydrate (DCPD) is the most widely-used dentifrice abrasive in non-therapeutic tooth-paste requiring, low abrasive level, high stability and excellent compatibility with other formulation ingredients. One of the difficulties encountered in the use of this material in tooth-paste is that unless storage of the product is maintained at a relative low temperature there is a distinct tendency to lose water of crystallization. Another difficulty which has been encountered is that there is a tendency for the product to become lumpy. Various means have been proposed for increasing the stability and overcoming the lumping tendency, most of which means comprise the addition of stabilizing agent. But there is not any report about the relationships between the mechanism of dehydration, physical properties, structure and manufacturing condition. In this experiment, DCPD were manufactured by methods of Moss' patent, its two varied and J.P.VIII, these were studied by means of stability test, IR spectra, and DTA. According to the manufacturing conditions, DCPD has different physical properties and structures, i. e., monoclinic system of low drying temperature, triclinic system of high drying temperature. Dehydration of DCPD may be supposed one step debydration at about $100^{\circ}$ and it finaly converts to ${\gamma}-pyrophosphate$ at about $465^{\circ}$ and if the drying temperature is high it becomes DCP anhydrous. DCPD made by Moss' patent is thought of the best polishing agent of tooth-paste.

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The Thermal Stability and Elevated Temperature Mechanical Properties of Spray-Deposited $SiC_P$/Al-11.7Fe-1.3V-1.7Si Composite

  • Hao, L.;He, Y.Q.;Wang, Na;Chen, Z.H.;Chen, Z.G.;Yan, H.G.;Xu, Z.K.
    • Advanced Composite Materials
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    • v.18 no.4
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    • pp.351-364
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    • 2009
  • The thermal stability and elevated temperature mechanical properties of $SiC_P$/Al-11.7Fe-1.3V-1.7Si (Al-11.7Fe-1.3V-1.7Si reinforced with SiC particulates) composites sheets prepared by spray deposition (SD) $\rightarrow$ hot pressing $\rightarrow$ rolling process were investigated. The experimental results showed that the composite possessed high ${\sigma}_b$ (elevated temperature tensile strength), for instance, ${\sigma}_b$ was 315.8 MPa, which was tested at $315^{\circ}C$, meanwhile the figure was 232.6 MPa tested at $400^{\circ}C$, and the elongations were 2.5% and 1.4%, respectively. Furthermore, the composite sheets exhibited excellent thermal stability: the hardness showed no significant decline after annealing at $550^{\circ}C$ for 200 h or at $600^{\circ}C$ for 10 h. The good elevated temperature mechanical properties and excellent thermal stability should mainly be attributed to the formation of spherical ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase particulates in the aluminum matrix. Furthermore, the addition of SiC particles into the alloy is another important factor, which the following properties are responsible for. The resultant Si of the reaction between Al matrix and SiC particles diffused into Al matrix can stabilize ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase; in addition, the interface (Si layer) improved the wettability of Al/$SiC_P$, hence, elevated the bonding between them. Furthermore, the fine $Al_4C_3$ phase also strengthened the matrix as a dispersion-strengthened phase. Meanwhile, load is transferred from Al matrix to SiC particles, which increased the cooling rate of the melt droplets and improved the solution strengthening and dispersion strengthening.