• Journal of Environmental Science International
• /
• v.23 no.3
• /
• pp.409-431
• /
• 2014

In this study, the characteristics in the simulation of high-resolution coastal weather, i.e. sea surface wind (SSW) and significant wave height (SWH), were studied in a southeastern coastal region of Korea using the WRF and SWAN models. This analyses was performed based on the effects of various input factors in the WRF and SWAN model during M-Case (moderate days with average 1.8 m SWH and $8.4ms^{-1}$ SSW) and R-Case (rough days with average 3.4 m SWH and $13.0ms^{-1}$ SSW) according to the strength of SSW and SWH. The effects of topography (TP), land cover (LC), and sea surface temperature (SST) for the simulation of SSW with the WRF model were somewhat high on v-component winds along the coastline and the adjacent sea of a more detailed grid simulation (333 m) during R-Case. The LC effect was apparent in all grid simulations during both cases regardless of the strength of SSW, whereas the TP effect had shown a difference (decrease or increase) of wind speed according to the strength of SSW (M-Case or R-Case). In addition, the effects of monthly mean currents (CR) and deepwater design waves (DW) for the simulation of SWH with the SWAN model predicted good agreement with observed SWH during R-Case compared to the M-Case. For example, the effects of CR and DW contributed to the increase of SWH during R-Case regardless of grid resolution, whereas the differences (decrease or increase) of SWH occurred according to each effect (CR or DW) during M-Case.

• Mass Spectrometry Letters
• /
• v.3 no.2
• /
• pp.43-46
• /
• 2012

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotron resonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have been combined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturated cyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with more than two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings were identified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compounds were observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICR MS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each other for more complete understanding of oil samples.

• Analytical Science and Technology
• /
• v.21 no.4
• /
• pp.245-258
• /
• 2008

Five triterpenic acids as marker compounds were extracted and isolated from Prunellae Spica by column chromatography and reversed-phase high-performance liquid chromatography (HPLC), and their purity was determinated by HPLC (purity ${\geq}90%$). Molecular weight and elemental compositions of the five marker compounds were determined by fast atom bombardment high-resolution mass spectrometry (FAB-HRMS). The structural determination of the five marker compounds was carried out fast atom bombardment collision-induced dissociation tandem mass spectrometry (FAB-CID-MS/MS). The collision-induced dissociation (CID) of protonated molecules $[M+H]^+$ and deprotonated molecules $[M-H]^-$ produced diverse product ions due mainly to retro Diels-Alder reaction (RDA), dehydration and decarboxylation. Moreover, the CID-MS/MS spectra of the $[M-H]^-$ ions were observed charge-remote fragmentation (CRF) patterns. On the basis of interpretation of CID-MS/MS spectra, structural elucidation of triterpenic acids isolated from Prunellae Spica was clearly performed.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.4
• /
• pp.1170-1178
• /
• 2011

In the present study, the approach of high accuracy mass measurements for phospholipid identifications was evaluated using a 7 T ESI-FTMS/linear ion trap MS/MS. Experiments were carried out for porcine brain, bovine liver, and soybean total lipid extracts in both positive and negative ion modes. In total, 59, 55, and 18 phospholipid species were characterized in the positive ion mode for porcine brain, bovine liver, and soybean lipid extracts, respectively. Assigned lipid classes were PC, PE, PEt, PS, and SM. In the negative ion mode, PG, PS, PA, PE, and PI classes were observed. In the negative ion mode, for porcine brain, bovine liver, and soybean lipid extracts, 28, 34, and 29 species were characterized, respectively. Comparison of our results with those obtained by other groups using derivatization-LC-APCI MS and nano-RP-LC-MS/MS showed that our approach can characterize PC species as effectively as those methods could. In conclusion, we demonstrated that high accuracy mass measurements of total lipid extracts using a high resolution FTMS, particularly, 7T FTMS, plus ion-trap MS/MS are very useful in profiling lipid compositions in biological samples.

• Progress in Medical Physics
• /
• v.12 no.2
• /
• pp.113-124
• /
• 2001

For veterinary imaging diagnosis, we obtained MR images of the canine brain, spine, kidney and pelvis from 3T MRI system which was equipped with the world first 3T active shield magnet. Spin echo (SE) and fast Spin Echo (FSE) images were obtained from the canine brain, spine, kidney and pelvis of normal and sick dogs using a homemade birdcage and transverse electromagnetic (TEM) resonators operating in quadrature and tuned to 128 MHz. In addition, we employed a homemade saddle shaped RF coil. Typical common acquisition parameters were as follows: matrix=512$\times$512, field of view (FOV)=20cm, slice thickness=3 w, number of excitations (NEX)=1. For T1-weighted MR images, we used TR=500 ms, TE=10 or 17.4 ms. For T2-weighted MR images, we used TR=4000 ms, TE=108 ms. Signal to noise ratio (SNR) of 3T system was measured 2.7 times greater than that of prevalent 1.57 system. The high resolution images acquired in this study represent more than a 4-fold increase in in-plane resolution relative to conventional images obtained with a 20 cm field of view and a 5 mm slice thickness. MR images obtained from 3T system revealed numerous small venous structures throughout the image plane and provided reasonable delineation between gray and white matter The present results demonstrate that the MR images from 3T system could provide better diagnostic quality of resolution and sensitivity than those of 1.5T system. The elevated SNR observed in the 3T high field magnetic resonance imaging can be utilized to acquire images with a level of resolution approaching the microscopic structural level under in vivo conditions. These images represent a significant advance in our ability to examine small anatomical features with noninvasive imaging methods. Moreover, MRI technique could begin to apply for veterinary medicine in Korea.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.3
• /
• pp.749-752
• /
• 2014

New software was developed for the assignment of elemental formulae based on high-resolution mass spectra and subsequent hydrogen/deuterium exchange data. Entire peaks in high-resolution mass spectra were grouped by their Kendrick mass defect values, and the weighted RMS deviations between theoretical and experimental values were used to determine elemental formulae. After this initial assignment, formulae containing deuterium atoms were sorted in order to interpret hydrogen/deuterium exchange spectra. The software was successfully applied to hydrogen/deuterium exchange spectra of resins and aromatic fractions from heavy crude oil.

• Mass Spectrometry Letters
• /
• v.14 no.4
• /
• pp.173-177
• /
• 2023

Kendrick plots offer an alternative visualization of mass spectral data which reveals ion series and patterning by turning a mass spectrum into a map, plotting the fractional mass (wrongly called mass defect) as a function of mass-to-charge ratios and ion abundances. Although routinely used for polymer mass spectrometry, two unreported applications of these Kendrick plots are proposed using the program "kendo2": the graphical recalibration of a mass spectrum via the simulation of a theoretical fractional mass and a multi-segment fit; and the rapid evaluation of scan-to-scan variation of accurate mass measurements used as tolerances for the blank subtraction of UPLC-MS data files. Both applications are compatible with any type of high-resolution MS data including LC/GC-MS(/MS).

• ETRI Journal
• /
• v.29 no.3
• /
• pp.408-410
• /
• 2007

A 9-bit 80-MS/s CMOS pipelined folding analog-to-digital converter employing offset-canceled preamplifiers and a subranging scheme is proposed to extend the resolution of a folding architecture. A fully differential dc-decoupled structure achieves high linearity in circuit design. The measured differential nonlinearity and integral nonlinearity of the prototype are ${\pm}0.6$ LSB and ${\pm}1.6$ LSB, respectively.

• Korean Journal of Remote Sensing
• /
• v.25 no.3
• /
• pp.287-294
• /
• 2009

KOMPSAT-2 like other high-resolution satellites has the time and angle difference in the acquisition of the panchromatic (PAN) and multispectral (MS) images because the imaging systems have the offset of the charge coupled device combination in the focal plane. Due to the differences, high altitude and moving objects, such as clouds, have a different position between the PAN and MS images. Therefore, a mis-registration between the PAN and MS images occurs when a registration algorithm extracted matching points from these cloud objects. To overcome this problem, we proposed a new registration method. The main idea is to discard the matching points extracted from cloud boundaries by using an automatic thresholding technique and a classification technique on a distance disparity map of the matching points. The experimental result demonstrates the accuracy of the proposed method at ground region around cloud objects is higher than a general method which does not consider cloud objects. To evaluate the proposed method, we use KOMPSAT-2 cloudy images.

• Atmosphere
• /
• v.21 no.4
• /
• pp.439-446
• /
• 2011

NCEP reanalysis data were analyzed in order to provide distribution of global wind resource and wind speed in the surface layer for the years 2000-2009. Wind speed at 10 m above ground level (AGL) was converted to wind speed at 80 m above the ground level using the power law. The global average 80 m wind speed shows a maximum value of $13ms^{-1}$ at the storm track region. High wind speed over the land exists in Tibet, Mongolia, Central North America, South Africa, Australia, and Argentina. Wind speed over the ocean increased with a large value in the South China Sea, Southeast Asia, East Sea of the Korea. Sea surface wind in Western Europe and Scandinavia are suitable for wind farm with a value of $7-8ms^{-1}$. Areas with great potential for wind farm are also found in Eastern and Western coastal region of North America. Sea surface wind in Southern Hemisphere shows larger values in the high latitude of South America, South Africa and Australia. The distribution of low-resolution reanalysis data represents general potential areas for wind power and can be used to provide information for high-resolution wind resource mapping.