Mass Spectrometry Letters

Korean Society for Mass Spectrometry (한국질량분석학회)
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Application of Comprehensive 2D GC-MS and APPI FT-ICR MS for More Complete Understanding of Chemicals in Diesel Fuel

  • Cho, Yun-Ju (Kyungpook National University, Department of Chemistry) ;
  • Islam, Annana (Kyungpook National University, Department of Chemistry) ;
  • Ahmed, Arif (Kyungpook National University, Department of Chemistry) ;
  • Kim, Sung-Hwan (Kyungpook National University, Department of Chemistry)
  • Received : 2012.06.08
  • Accepted : 2012.06.17
  • Published : 2012.06.28
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Abstract

In this study, comprehensive two dimension gas chromatography (2D GC-MS) and 15 T Fourier transform ion cyclotron resonance mass spectrometry (15T FT-ICR MS) connected to atmospheric pressure photo ionization (APPI) have been combined to obtain detailed chemical composition of a diesel oil sample. With 2D GC-MS, compounds with aliphatic alkyl, saturated cyclic ring(s), and one aromatic ring structures were mainly identified. Sensitivity toward aromatic compounds with more than two aromatic rings was low with 2D GC-MS. In contrast, aromatic compounds containing up to four benzene rings were identified by APPI FT-ICR MS. Relatively smaller abundance of cyclic ring compounds were found but no aliphatic alkyl compounds were observed by APPI FT-ICR MS. The data presented in this study clearly shows that 2D GC-MS and 15T FT-ICR MS provides different aspect of an oil sample and hence they have to be considered as complementary techniques to each other for more complete understanding of oil samples.

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References

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