• 한국수소및신에너지학회논문집
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• 제31권6호
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• pp.558-563
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• 2020

Hydrogen is attracting attention as an alternative energy source as an eco-friendly fuel without emitting environmental pollutants. In order to use hydrogen as an energy source, technologies such as hydrogen production and storage must be used, and new storage methods are being studied. In this study, the behavior of hydrogen in the storage tank were numerically studied under high-pressure hydrogen discharge conditions in a Type III hydrogen tank. Numerical results were compared with the experimental value and the results were quantitatively analyzed to verify the numerical implementation. With the results of pressure and temperature values under a given discharge condition, the Redich-Kwong gas model showed the adequate models with the smallest error between numerical and experimental results.

• 한국수소및신에너지학회논문집
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• 제18권2호
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• pp.132-139
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• 2007

Popular techniques for producing synthesis gas by converting methane include steam reforming and catalyst reforming. However, these are high temperature and high pressure processes limited by equipment, cost and difficulty of operation. Low temperature plasma is projected to be a technique that can be used to produce high concentration hydrogen from methane. It is suitable for miniaturization and for application in other technologies. In this research, the effect of changing each of the following variables was studied using an AC Glidarc system that was conceived by the research team: the gas components ratio, the gas flow rate, the catalyst reactor temperature and voltage. Glidarc plasma reformer was consisted of 3 electrodes and an AC power source. And air was added for the partial oxidation reaction of methane. The result showed that as the gas flow rate, the catalyst reactor temperature and the electric power increased, the methane conversion rate and the hydrogen concentration also increased. With $O_2/C$ ratio of 0.45, input flow rate of 4.9 l/min and power supply of 1 kW as the reference condition, the methane conversion rate, the high hydrogen selectivity and the reformer energy density were 69.2%, 36.2% and 35.2% respectively.

• 한국가스학회지
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• 제23권2호
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• pp.9-16
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• 2019

울산, 여주 등 산업단지의 고압매설배관에서 발생할 수 있는 굴착공사 등 타 공사로 인한 중대사고의 발생빈도를 도시가스 매설 배관과 비교하여 FTA에 의해 기초사상(Basic event)을 도출하여 제시한다. 또한 굴착빈도, 순찰주기 등 배관손상 영향 인자를 관찰 및 분석하고, 이들 인자의 중요도와 민감도를 Risk 비교분석을 통해 구해봄으로써 고압가스매설배관의 안전성 향상에 기여한다.

• 한국안전학회지
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• 제37권6호
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• pp.158-165
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• 2022

Eco-friendly policies proposed by the government of The Republic of Korea have encouraged the use of eco-friendly vehicles. Hydrogen vehicles have exhibited the highest growth rate, although the current number of registered vehicles is low. In hydrogen vehicles, a thermally activated pressure relief device (TPRD) is installed to prevent explosions in the hydrogen gas cylinder. When discharged due to low ignition energy, hydrogen gas readily forms a jet flame. The risks induced by such jet flames were analyzed through a numerical analysis. Jet flames can activate TPRDs installed in nearby hydrogen gas cylinders. As a result, high-voltage cables exposed in the lower area of a vehicle can ignite within seconds. There was a 9.5-kW/m2 area around the vehicle (which can result in casualties) at a distance of ~5 m from the hydrogen gas cylinder, and a 37.5-kW/m2 area (which can cause significant damage) in the form of an inverted triangle toward the lower section of the vehicle. We believe that the risk factors analyzed herein should be considered for addressing accidents in hydrogen vehicles.

• 한국수소및신에너지학회논문집
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• 제34권5호
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• pp.431-438
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• 2023

Recently, study on hydrogen is being conducted due to environmental pollution and fossil fuel depletion. High-pressure gas hydrogen commonly used is applied to vehicle and tube trailers. In particular, high-pressure hydrogen storage tank for vehicles must comply with the guidelines stipulated in SAE J2601. There is a charging temperature limitation condition for the safety of the storage tank material. In this study, numerical analysis method were verified based on previous studies and the nozzle angle was changed for thermal management to analyze the increase in forced convection effect and energy uniformity due to the promotion of circulation flow. The previously applied high-pressure hydrogen storage tank has a length/diameter ratio of about 2.4 and was analyzed by comparing the length/diameter ratio with 8. As a result, the circulation flow of hydrogen flowing into the high-pressure hydrogen storage tank is promoted at a nozzle angle of 30° than the straight nozzle and accordingly, the effect of suppressing temperature rise by energy uniformity and forced convection was confirmed.

• 한국수소및신에너지학회논문집
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• 제32권5호
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• pp.356-364
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• 2021

During the hydrogen fueling process, hydrogen temperature inside the compressed tank were limited below 85℃ due to the allowable pressure of tank material. The chiller system to cool compressed hydrogen used R407C, greenhouse gas with a high global warming potential (GWP), as a refrigerant. To reduce greehouse gas emission, it should be replaced by refrigerant with a low GWP. This study proposes a chiller system for fueling hydrogen with R290, consisted in propane, by applying the C3 pre-cooled system use d in the LNG liquefaction process. The proposed system consisted of hydrogen compression and cooling sections and optimized the operating pressure through exergy analysis. It was also compared to the exergy efficiency with the existing system at the optimal operating pressure. The result showed that the optimal operating pressure is 700 kPa in 2-stage, 840 kPa/490 kPa in 3-stage, and the exergy efficiency increased by 17%.

• Corrosion Science and Technology
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• 제4권6호
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• pp.236-241
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• 2005

Hydrogen induced cracking (HIC) is one of the hydrogen degradation phenomena of linepipe steels caused by $H_2S$ gas in the crude oil or natural gas. However, NACE TM0284-96 standard HIC test method is hard to satisfy the steel requirements for sour service application since it uses more severe environmental conditions than actual conditions. Therefore, in order to use steels effectively, it is required to evaluate HIC resistance of steels in the practical range of environmental severity. In this study, HIC resistance of two high strength low alloy (HSLA) steels being used as line pipe steels was evaluated in various test solutions with different $H_2S$ pressures and pH values. The results showed that the key parameter affecting crack area ratio (CAR) is $H_2S$ partial pressure of test solution when the pH value of test solution is not over 4. Hydrogen diffusivity was not a constant value, but it was rather affected by the hydrogen ion concentration (pH value) in the solution.

• 한국수소및신에너지학회논문집
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• 제20권4호
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• pp.274-282
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• 2009

Diaphragm compressor is widely used for hydrogen compression because it achieves high gas pressure without gas contamination. Diaphragm deflecting in the cavity with high pressure formed by an oil compression is the most important component in the compressor. Therefore, it is necessary to obtain deflection degree of diaphragm to predict the damage point of diaphragm. The objective of this study is to estimate the diaphragm's damage point through diaphragm deflection test by implementing with strain gauges attached on several radial points. Without gas compression, strain sum of each points varied as similarly as the variation of the pressure with respect to time. And while the motor speed was slower than 400rpm, the strain near the rim was larger than that of the center. When motor speed, however, was over 500rpm, strain became similar to that of the center and the rim. With gas compression, it was shown that the variation of the strain sum was delayed against that of the pressure and the strain near the rim was much higher than that of the center.

• Tribology and Lubricants
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• 제39권5호
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• pp.212-215
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• 2023

Diaphragm compressors play a crucial role in safely compressing large volumes of high-purity hydrogen gas without contamination or leakage, thereby ensuring quality and reliability. Diaphragm compressors use a thin, flat, triple-layered diaphragm plate that is subjected to repetitive piston pressure for compression. They are usually made of metallic materials such as stainless steel or Inconel owing to their high-pressure resistance. However, since they are consumable components, they fail due to fatigue from repetitive pressure and vibration stress. This study aims to evaluate the scratch characteristics of diaphragms in operational environments by conducting tests on three different samples: Inconel 718, AISI 301, and Teflon-coated AISI 301. The Inconel 718 sample underwent a polishing process, the AISI 301 sample used raw material, and the Teflon coating was applied to the AISI 301 substrate at a thickness of 50 ㎛. To assess the scratch resistance, reciprocating motion friction tests were performed using a tribometer, utilizing 220 and 2000 grit sandpapers as the counter materials. The results of the friction tests suggested that the Teflon-coated sample exhibited the lowest initial friction coefficient and consistently maintained the lowest average friction coefficient (0.13 and 0.11 with 220 and 2000 grit, respectively) throughout the test. Moreover, the Teflon-coated diaphragm showed minimal wear patterns, indicating superior scratch resistance than the Inconel 718 and AISI 301 samples. These findings suggest that Teflon coatings may offer an effective solution for enhancing scratch resistance in diaphragms, thereby improving compressor performance in high-pressure hydrogen applications.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.585-591
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• 2021

Liquefied hydrogen have advantage which reduces the volume by about 800 times or more compared to hydrogen gas, so it is possible to increase the storage density. However, liquefied hydrogen produced by cryogenic cooling of 20 K or less at normal pressure has a problem of maximizing the insulation effect that blocks heat introduced from the outside. Representative insulation technologies include vacuum insulation and multi-layer insulation materials and in general, heat blocking is attempted by combining insulation technologies. Therefore, in this study, the pressure of the internal vacuum layer was changed to 10^-1, 10^-2, 10^-3 and 10^-4 Torr to confirm the thermal insulation performance of the vacuum jacket valve for transporting liquefied hydrogen. As a result, it was confirmed that the insulation performance improved as the degree of vacuum increased.