• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 1999년도 추계학술대회 논문집
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• pp.424-425
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• 1999

오존은 대기 중에 있는 질소산화물 (NO$_{x}$)과 휘발성 유기화합물 (Volatile Organic Compounds, VOCs)이 강한 햇빛과 반응하여 생성되는 2차 오염물질이다. 오존의 농도는 오염물질의 배출과 기상조건, 그리고 대기 중 화학반응이 상호 연결되어 나타난다. 다양한 변수들이 오존 농도 상승에 영향을 미치며, 이러한 과정을 유기적으로 이해하기 위하여 다양한 광화학 수치 모델들이 사용되고 있다.(중략)

• Asian Journal of Atmospheric Environment
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• 제8권3호
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• pp.162-174
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• 2014

An abnormal decrease in ozonesonde sensor signal occurred during air-pollution study campaigns in November 2011 and March 2012 in Mexico City Metropolitan Area (MCMA). Sharp drops in sensor signal around 5 km above sea level and above were observed in November 2011, and a reduction of signal over a broad range of altitude was observed in the convective boundary layer in March 2012. Circumstantial evidence indicated that $SO_2$ gas interfered with the electrochemical concentration cell (ECC) ozone sensors in the ozonesonde and that this interference was the cause of the reduced sensor signal output. The sharp drops in November 2011 were attributed to the $SO_2$ plume from Popocat$\acute{e}$petl volcano southeast of MCMA. Experiments on the response of the ECC sensor to representative atmospheric trace gases showed that only $SO_2$ could cause the observed abrupt drops in sensor signal. The vertical profile of the plume reproduced by a Lagrangian particle diffusion simulation supported this finding. A near-ground reduction in the sensor signal in March 2012 was attributed to an $SO_2$ plume from the Tula industrial complex north-west of MCMA. Before and at the time of ozonesonde launch, intermittent high $SO_2$ concentrations were recorded at ground-level monitoring stations north of MCMA. The difference between the $O_3$ concentration measured by the ozonesonde and that recorded by a UV-based $O_3$ monitor was consistent with the $SO_2$ concentration recorded by a UV-based monitor on the ground. The vertical profiles of the plumes estimated by Lagrangian particle diffusion simulation agreed fairly well with the observed profile. Statistical analysis of the wind field in MCMA revealed that the effect Popocat$\acute{e}$petl was most likely to have occurred from June to October, whereas the effect of the industries north of MCMA, including the Tula complex, was predicted to occur throughout the year.

• Asian Journal of Atmospheric Environment
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• 제5권2호
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• pp.65-78
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• 2011

Ozone ($O_3$) is a main component of photochemical oxidants, and a phytotoxic anthropogenic air pollutant. In North America and Europe, the current concentration of $O_3$ has been shown to have significant adverse effects on vegetation. In this review, we summarize the experimental studies on the effects of $O_3$ on the growth and photosynthetic activity of Japanese forest tree species to understand the present knowledge and provide sound basis for future research toward the assessment of $O_3$ impacts on Japanese forest ecosystem. Since the 1990s, several Japanese researchers have conducted the experimental studies on the effects of ambient levels of $O_3$ on growth and physiological functions such as net photosynthesis of Japanese forest tree species. Although the sensitivity to $O_3$ of whole-plant growth is quite different among the species, it was suggested that the current ambient levels of $O_3$ in Japan are high enough to adversely affect growth and photosynthetic activity of Japanese forest tree species classified into high $O_3$ sensitivity group such as Japanese beech. The N load to soil has been shown to reduce the sensitivity to $O_3$ of Japanese larch and increase that of Japanese beech. To establish the critical level of $O_3$ for protecting Japanese forest tree species, therefore, it is necessary to take into account the N deposition from the atmosphere. There is little information on the combined effects of $O_3$ and other environmental factors such as elevated $CO_2$ and drought on growth and physiological functions of Japanese forest tree species. Therefore, it is necessary to promote the experimental study and accumulate the information on the combined effects of $O_3$ and any other abiotic environmental factors on Japanese forest tree species.

• 한국환경과학회지
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• 제21권2호
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• pp.153-163
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• 2012

The seasonal variations of ozone ($O_3$) concentrations were investigated with regard to the relationship between $O_3$ and wind distributions at two different sites (Jung Ang (JA): a semi-closed topography and Seo Chang (SC): a closed topography) within a valley city (Yangsan) and their comparison between these sites (JA and SC) and two non-valley sites (Dae Jeo (DJ) and Sang Nam (SN)) located downwind from coastal cities (Busan and Ulsan). This analysis was performed using the data sets of hourly $O_3$ concentrations, meteorological factors (especially, wind speed and direction), and those on high $O_3$ days exceeding the 8-h standard (60 ppb) during 2008-2009. In summer and fall (especially in June and October), the monthly mean values of the daily maximum $O_3$ concentrations and the number of high $O_3$ days at JA (and SC) were relatively higher than those at DJ (and SN). The increase in daytime $O_3$ concentrations at JA in June was likely to be primarily impacted by the transport of $O_3$ and its precursors from the coastal emission sources in Busan along the dominant southwesterly winds (about 5 m/s) under the penetration of sea breeze condition, compared to other months and sites. Such a phenomenon at SC in October was likely to be mainly caused by the accumulation of $O_3$ and its precursors due to the relatively weak winds under the localized stagnant weather condition rather than the contribution of regional transport from the emission sources in Busan and Ulsan.

• 조명전기설비학회논문지
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• 제16권6호
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• pp.130-136
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• 2002

본 논문은 비유전율이 100 이상으로 제작된 Ti-Si-Al형 세라믹 촉매 방전관에 전원 전압 4 ～6［kV］, 구동 주파수0.6～1.0［kHz］를 방전관 전극에 인가하여 오존 농도와 수율을 측정한 것이다. 측정 결과 구동 주파수 600［Hz］, 유량 2［1/min］, 동작 압력 1.6［atm］, 방전관 주위 온도 20［$^{\circ}C$］에서 산소 원료의 경우, 오존 발생 농도는 50～60［g/㎥］이었고, 오존 발생 수율은 180(g/kWh)로 나타났다. 그리고 반응기 내부 온도 또는 유입 가스 온도가 낮을수록 오존 수율은 상승하였다.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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• pp.615-617
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• 2003

Carbon monoxide (CO) is one of the important trace gases because its concentration in the troposphere directly influences the concentrations of tropospheric hydroxyl (OH), which controls the lifetimes of tropospheric trace gases. CO traces the transport of global and regional pollutants from industrial activities and large scale biomass burning. The distributions of CO were analyzed using the MOPITT data for East Asia, which were compared with the ozone distributions. In general, seasonal CO variations are characterized by a peak in the spring, which decrease in the summer. The monthly average for CO shows a similar profile to that for O$_3$. This fact clearly indicates that the high concentration of CO in the spring is possibly due to one of two causes: the photochemical production of CO in the troposphere, or the transport of the CO into East Asia. The seasonal cycles for CO and O$_3$ in East Asia are extensively influenced by the seasonal exchanges of different air mass types due to the Asian monsoon. The continental air masses contain high concentrations of O$_3$ and CO, due to the higher continental background concentrations, and sometimes to the contribution from regional pollution. In summer this transport pattern is reversed, where the Pacific marine air masses that prevail over Korea bring low concentrations of CO and O$_3$, which tend to give the apparent summer minimums.

• Journal of Electrical Engineering and Technology
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• 제13권6호
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• pp.2392-2401
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• 2018

Creepage discharge faults in air on solid insulating material play a vital role in degradation and ageing of material which ultimately leads to breakdown of power equipment. And electric discharge decompose air in to its by-products such as Ozone and $NO_x$ gases. By analyzing air decomposition gases is a potential method for fault diagnostic in air. In this paper, experimental research has been conducted to study the effect of creepage discharge on rate of generation of air decomposition by-products using different insulating materials such as RTV, epoxy and fiberglass laminated sheet. Moreover XRF analysis has been done to analyze creepage discharge effect on these insulating materials. All experiments have been done in an open air test cell under constant temperature and pressure conditions. While analysis has been made for low and high humidity conditions. The results show that the overall concentration of air decomposition by-products under creepage discharge in low humidity is 4% higher than concentration measured in high humidity. Based on this study a mathematical relationship is also proposed for the rate of generation of air decomposition by-products under creepage discharge fault. This study leads to indirect way for diagnostic of creepage discharge propagation in air.

• 설비공학논문집
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• 제8권1호
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• pp.140-150
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• 1996

CFC-12, which has been used most widely in automobile air conditioners and household refrigerators is scheduled to be phased out soon because of its high ozone depletion potential. Now HFC-134a is suggested as an alternative refrigerant for CFC-12. In this Study, we intended to investigate how PAG oil influence evaporation heat transfer and flow pattern, using R-134a and PAG oil influences evaporation heat transfer and flow pattern, using R-134a and PAG oil in the horizontal miro-fin evaporation tube. Experiments were conducted under the flowing est conditions : mass velocity 86-250kg/$m^2$s, heat flux 5-30 ㎾/$m^2$, oil concentration 0-21 wt.% and saturation temperature 5$^{\circ}C$. Local evaporation heat transfer coefficients were found to be higher at the top, side and bottom of the tube in this order. Average heat transfer coefficients turned out to increase with oil concentration increment up to 3 wt.% oil concentration, whereas heat transfer coefficients gradually decreased over 3 wt.% oil concentration, because of oil-rich liquid film was formed on the heat transfer surface. Flow patterns were rapidly transitioned to annular regimes up to 3 wt.% oil concentration. In case of pure refrigerant, measured heat transfer coefficients in the experiments were similar to those of Kandlikar＇s correlation.

• 한국대기환경학회지
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• 제20권1호
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• pp.87-97
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• 2004

NMHC (non-methane hydrocarbons) and fine particles such as P $M_{10}$ and P $M_{2.5}$ were measured at KIST (Korea Institute of Science and Technology) in Seoul for a month from the end of May. At the beginning of June, peak ozones exceeded 100ppb both near KIST and in Seoul while ozone and fine particles decreased from the middle of June due to frequent precipitation. Because the measurement site was close to trees on a hill, isoprene concentration went up to 4.1ppb with an average of 0.76ppb. Toluene was the highest all day long, but particularly high concentration in the afternoon implied a contribution of emission from solvent use as well as vehicle exhaust. Eighty-five percent of P $M_{10}$ was P $M_{2.5}$ on an average since major ions except sea salt, including nitrate, were present within P $M_{2.5}$. Daily variations of pollutants were generally similar except for NMHC. One of major differences in NMHC variation was maintenance of a relative high concentration in rainy day, showing that NMHC were not effectively scavenged by precipitation.ion.ion.

• 공업화학
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• 제35권1호
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• pp.23-28
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• 2024

세슘은 높은 수용성으로 인하여 인체에 쉽게 침투하여 암 또는 DNA의 변형을 유발하는 잠재적인 독성 오염물질이다. 본 연구에서는 활성탄소의 세슘 흡착 능력을 향상시키고자 오존 처리를 통하여 활성탄소 표면에 산소 작용기를 도입하였다. 오존 처리 시간의 증가에 따라 활성탄소 표면의 산소함량이 증가하였다. 이후 활성탄소와 세슘 사이의 정전기적 상호작용이 더욱 원활하게 이루어져 모든 시료의 세슘 이온 흡착 효율이 향상되었다. 특히 반응기 내부 오존 농도를 50000 ppm으로 하여 7 min 동안 오존 처리한 시료는 약 12%의 높은 산소 작용기 함량을 보이며 97.6%의 가장 높은 세슘 제거 효율을 보였다. 한편, 5 min 동안 처리된 시료는 7 min간 반응한 시료와 비교하여 0.3%의 근소한 세슘 제거율 차이를 보였으며, 이는 오존 기체의 반응 특성으로 인한 두 시료의 표면화학적 유사성에 기인한다. 그러나, 오존 처리된 활성탄소의 세슘 흡착 성능은 활성탄소의 비표면적 및 기공 구조도 중요하지만 표면에 도입된 산소 작용기 양이 주된 영향을 미치는 것으로 판단된다.