• 대한환경공학회지
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• 제32권4호
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• pp.325-332
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• 2010

본 연구에서는 오존을 이용한 잉여슬러지의 가용화 실험을 실시하였다. 오존의 접촉효율을 높이기 위해 마이크로버블화된 오존(이하 마이크로버블 오존이라 함)을 이용하였으며, 생성된 마이크로버블 오존의 사이즈는 평균 직경 30 ${\mu}m$ 정도였고, 40 ${\mu}m$ 이하가 전체의 약 90% 정도를 나타내었다. 마이크로버블 오존을 이용한 슬러지 처리에 있어서는 슬러지 농도에 상관없이 오존주입율을 0.34 g $O_3/g$ SS 이하로 주입할 경우, 폐오존의 발생 없이 오존소모율이 100%인 것으로 조사되었다. 각 농도별 슬러지 처리에 있어서 슬러지의 초기 SS 농도를 6,447 mg/L, 5,557 mg/L, 3,180 mg/L, 1,092 mg/L 및 515mg/L로 하였을 경우, 동일한 오존주입율에 있어서 초기 SS의 농도가 증가할수록 제거되는 SS량이 증가하는 경향을 나타내어, 오존의 산화효율을 높이기 위해서는 초기 SS의 농도가 높은 슬러지를 처리하는 것이 효과적이었다. 한편, 슬러지의 복합 처리로서 산과 알칼리 그리고 오존처리를 검토한 결과, 오존의 전처리로서 산처리를 이용하는 것이 알칼리처리에 비해 효과적이었으며, 슬러지에 주입하는 황산의 농도를 0.01 N로 하고, 오존주입율 0.05 g $O_3/g$ SS로 처리한 경우, 제거된 SS의 양은 153.9 g으로 오존단독처리시 81.2 g에 비해 1.9배의 많은 양이 제거되었다.

• Journal of Electrical Engineering and Technology
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• 제10권1호
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• pp.295-298
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• 2015

Ozone micro-bubble cleaning system was designed, and made to develop a unique technique to clean wafers by using ozone micro-bubbles. The ozone micro-bubble cleaning system consisted of loading, cleaning, rinsing, drying and un-loading zones, respectively. In case of the cleaning the silicon wafers of a solar cell, more than 99 % of cleaning efficiency was obtained by dipping the wafers at 10 ppm of ozone for 10 minutes. Both of long cleaning time and high ozone concentration in the wet-solution with ozone micro-bubbles reduced cleaning efficiency because of the re-sorption of debris. The cleaning technique by ozone micro-bubbles can be also applied to various wafers for an ingot and LED as an eco-friendly method.

• 생명과학회지
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• 제9권5호
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• pp.590-595
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• 1999

The objectives of this research were to estimate variation characteristics of TOC, UV-254 and NH4+-N, etc, if odorous generated algaes flowed into water treatment plant and they contacted with ozone known as typical advanced treatment. It was estimated that pH decreased from initial 7.4 to 2.1 after ozone contact 100min. pH declined to early 10min. suddenly and then pH drop did almost occur. TOC and UV-254 continued to decrease with passed time of ozone contact. NO3--N concentration was much higher than NH4+-N and NO2--N for whole test period. Because ozone oxidized organic matters as various kinds of ion material and ion intensity of sample was extended, conductivity showed high as passed time of ozone contact. Owing to ozone oxidation of algae, color did almost disappear after ozone contact 20min.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.124-127
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• 2003

Laboratory scale experiments on in-situ ozonation were carried out to delineate the effects of liquid phases, such as soil water and nonaqeous phase liquid (NAPL) on the transport of gaseous ozone in unsaturated soil. Soil water enhanced the transport of ozone due to water film effect, which prevent direct reaction between soil particles and gaseous ozone, and increased water content reduced the breakthrough time of ozone because of increased average linear velocity of ozone and decreased air-water interface area. Diesel fuel as NAPL also played a similar role with water film, so the breakthrough time of ozone in diesel-contaminated soil was significantly reduced compared with uncontaminated soil. However, ozone breakthrough time was retarded with increased diesel concentration, because of high reactivity of diesel fuel with ozone. In multiphase liquid system of unsaturated soil, the ozone transport was mainly Influenced by nonwetting fluid, diesel fuel in this study.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2000년도 하계학술대회 논문집 C
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• pp.2041-2043
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• 2000

Ozone is widely used to sterilize food and tap water because ozone is a strong oxidizer. To date, it has been difficult to dissolve a high concentration of ozone gas in water because the large size of the bubbles limits the contact area between the ozone gas and liquid water. The measurements of dissolved ozone can be used to control water quality and ozone dosage. Therefore the dissolved ozone measurement of most interest is that of residual ozone at the discharge point of a particular treatment chamber.

• 전기전자학회논문지
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• 제23권2호
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• pp.431-437
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• 2019

논문은 유전체 볼 충진 배리어 방전 리액터를 이용하여 오존 생성 및 TCE 분해 특성에 대하여 논하였다. 오존 발생량은 $Al_2O_3$ 또는 $TiO_2$ 유전체 볼을 충진한 경우가 유전체 볼을 충진하지 않은 배리어 방전리액터에 비하여 크게 증가됨을 보였으며, 이러한 방전구조는 오존 생성량을 증가시키기에 적절한 것으로 판단되었다. 또한, TCE 분해효율과 COx 전환율은 $MnO_2$ 충진 방전리액터를 사용한 경우가 높았으며, 이것은 방전공간에 위치한 촉매 표면에서 오존 분해에 따른 화학반응에 기인된 것으로 파악되었다. 촉매 표면 화학반응을 파악하기 위하여 Al2O3 유전체 볼 충진 방전리액터와 촉매 리액터를 직렬로 배치하여 TCE 분해 효율이 100[%]에 도달하였음을 확인하였으며, $MnO_2$ 촉매는 오존 분해에 매우 좋은 재료이며, 이러한 오존 분해 촉매 반응을 이용하여 TCE와 같은 VOCs 분해에 유용하게 활용될 것으로 사료된다.

• Journal of Microbiology and Biotechnology
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• 제28권8호
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• pp.1233-1246
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• 2018

Vibrio parahaemolyticus contamination causes serious foodborne illness and has become a global health problem. As a disinfectant, aqueous ozone can effectively kill a number of bacteria, viruses, parasites, and other microorganisms. In this study, three factors, namely, the aqueous ozone concentration, the exposure time, and the bacterial density, were analyzed by response surface methodology, and the aqueous ozone concentration was the most influential factor in the sterilization ratio. Under low aqueous ozone concentrations (less than 0.125 mg/l), the bacterial cell membranes remained intact, and the ozone was detoxified by intracellular antioxidant enzymes (e.g., superoxide dismutase and catalase). Under high aqueous ozone concentrations (more than 1 mg/l), cell membranes were damaged by the degree of peripheral electronegativity at the cell surface and the concentration of lactate dehydrogenase released into the extracellular space, and the ultrastructures of the cells were confirmed by transmission electron microscopy. Aqueous ozone penetrated the cells through leaking membranes, inactivated the enzymes, inhibited almost all the genes, and degraded the genetic materials of gDNA and total RNA, which eventually led to cell death.

• 한국지구과학회지
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• 제38권5호
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• pp.345-356
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• 2017

It is important to understand the variability of tropospheric ozone since it is both a major pollutant affecting human health and a greenhouse gas influencing global climate. We analyze the characteristics of East Asia tropospheric ozone simulated in a chemistry-climate model. We use a global chemical transport model, driven by the prescribed meteorological fields from an air-sea coupled climate model simulation. Compared with observed data, the ozone simulation shows differences in distribution and concentration levels; in the vicinity of the Korean Peninsula, a large error occurred in summer. Our analysis reveals that this bias is mainly due to the difference in atmospheric circulation, as the anomalous southerly winds lead to the decrease in tropospheric ozone in this region. In addition, observational data have shown that the western North Pacific subtropical high (WNPSH) reduces tropospheric ozone across the southern China/Korean Peninsula/Japan region. In the model, the ozone changes associated with WNPSH are shifted westward relative to the observations. Our findings suggest that the variations in WNPSH should be considered in predicting tropospheric ozone concentrations.

• 조명전기설비학회논문지
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• 제29권3호
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• pp.54-60
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• 2015

There are 5 purification plants with the adopted advanced water purification treatment process in Korea. Annual operating costs were 8,990 million won including purchase cost of oxygen and power usage charges. We need research to optimize, in the future, when considering the direction of domestic water treatment continues to adopt advanced water treatment process. In this paper, calculate the optimal operating costs by injected the oxygen gas, used power cost. approximately 25% of the operating costs can be reduced when injected the ozone gas is 1.0ppm than 2.0ppm, the necessary amount of oxygen is increased then power is lower. so operating costs are decided according to oxygen costs. On the other hand, high ozone concentration 2.0ppm, the necessary power is increased then amount of oxygen is lower. Therefore, in the case of G purification plant, the controlling factor of the input ozone concentration 2ppm, PID control operation by setting the concentration of over 10Wt% is efficient. The installed capacity is the more little the more better when considering on Ozone injection rate in the process of water treatment.

• 한국의류산업학회지
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• 제6권4호
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• pp.511-514
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• 2004

We studied on the bleaching properties of silk fabric by vapor type ozone processing using ozone's strong oxidation instead of 28% $H_2O_2$ chemical treatment. When vapor type ozone processing was directly treated to fabrics retaining water to 50~70% pick up ratio, high concentration ozone was generated 14,000ppm(168 mg/h) approximately and finally its bleaching improved. The fabric's bleaching effect was improved because vapor type ozone generated the highest decomposition to oxidation of surface and inter molecules. The experiment revealed that fabric's bleaching was improved by change of the pick-up ratio of vapor type ozone processing. However, tensile strength and elongation were reduced by increase of time, and the time that was assumed as the most optimized time to minimize the reduction of fabric's tensile strength and elongation as well as maximizing the fabric's bleaching was 30 minutes.