• Title/Summary/Keyword: High dielectric properties

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Dielectrical Characteristics of Ultrathin Reoxidized Nitrided Oxides by Rapid Thermal Process (급속 열처리 공정에 의한 초박막 재산화 질화산화막의 유전 특성)

  • 이용재;안점영
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.16 no.11
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    • pp.1179-1185
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    • 1991
  • Ultrathin Reoxidized Nitrided Oxides were formed by lamp heated rapid thermal annealing in oxyzen at temperatures of $1050^{\circ}C$-$1100^{\circ}C$ for 20, 40 seconds. The electrical characteristics of ultrathin films were evaluated by leakage current breakdown voltage. TDDB. FN tunneling. Nitridation and reoxidition condition dependence of charge trapping properties. i.e.. the flat band voltage shift $({\Delta}V_{FB})$ and the increase of charge-to-breakdown $(Q_{BD})$ induced by a high field stress where studied. As the results of analysis. rapid thermal reoxidation was achieved striking improvement of dielectric integrity, the charge to breakdown was increased and flat band voltage shift was reduced.

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A Study on the Microstructure Analysis and Dielectric Properties of Porcelain Suspension Insulators (자기제 현수애자의 미세구조분석과 유전특성에 관한 연구)

  • Kim, Chan-Yeong;Kim, Ju-Yong;Song, Il-Geun;Lee, Byeong-Seong
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.9
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    • pp.641-647
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    • 1999
  • The paper provides the results of microstructure analysis and dielectricproperties of porcelain suspension insulators. The evaluation of characteristics was also made as a function of the manufacturers and fabricated years for the experimental specimens which had been used in real distribution lines. Even though the series A contained higher alumina contents than the series B, the densification of series A was lower than that of series B, resulting from much porosity. The microstructure investigation confirmed that series A had much porosity than series B. The series A contained quartz $(SiO_2),\; mullite\; (Al_6Si_2O_{13}),\; corundum(Al_2O_3),\; and cristobalite\; (SiO_2)$ phases. However, the series B had no cristobalite phase which had very high thermal expansion coefficient. Also, the tan$\delta$of series A was more abruptly increased than that of series B as increasing temperature. The elevated temperature may make much expansion of cristobalite crystal than other crystals, resulting in crack and puncture inside cap during the summer days.

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The Effect of Conducting Particles on Breakdown Phenomena in GIS (GIS내에서 금속이물이 절연파괴에 미치는 영향)

  • Kim, Min-Kyu;Moon, In-Wook;Kim, Youn-Taeg;Kim, Ik-Soo;Lee, Hyeong-Ho
    • Proceedings of the KIEE Conference
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    • 1994.07b
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    • pp.1574-1576
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    • 1994
  • $SF_6$ gas has become an important insulation medium in modern electric power apparatus, because of its high insulation withstand levels and good arc quenching capability. For the application of $SF_6$ gas in GIS the estimation of insulation properties is a fundamental point. Moreover the reduction of withstand levels in case of inhomogeneous fields caused by particles or fixed protrusions is of special interest. It is known that the presence of free conducting particles in GIS can significantly lower the insulating level of $SF_6$ gas at elevated pressure and also it has been recently shown that dielectric strength is greatly reduced by fast transients such as disconnector surges where metallic particles are involved. In this paper, we have disigned the particle test chamber rated 362kV for the purpose of investigating the discharge characteristics in SF6 gas where inhomogenius fields are caused by metallic particles.

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Electrical Properties of Ferroelectric Polymer on Inorganic Dielectric Layer for FRAM

  • Han, Hui-Seong;Kim, Kwi-Jung;Jeon, Ho-Seung;Park, Byung-Eun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.258-258
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    • 2008
  • Among several available high-k dielectrics the lanthanum zirconium oxide ($LaZrO_x$) system is very attractive as a buffer insulating layer. Because both lanthanum and zirconium atoms, the constituents of the $LaZrO_x$ thin film, have been considered to be thermally stable in contact with Si. The $LaZrO_x$ films were deposited by a sol-gel method. After the deposition, The $LaZrO_x$ films were crystallized at $750^{\circ}C$ for 30 minutes in $O_2$ ambient. PVDF-TrFE films were deposited on these $LaZrO_x$/Si structures using a sol-gel technique. The sol-gel solution was spin-coated on $LaZrO_x$/Si structures at 500 rpm for 5 sec and 2500 rpm for 15 sec. The deposited layer was dried at $165^{\circ}C$ for 30 min in air on a hot-plate. Then, we deposited Au electrode on PVDF-TrFE films using thermal evaporation.

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Signal analysis of surface discharge and electromagnetic wave for insulator by kaolin contamination (카올린으로 오손된 애자의 표면방전 및 방사전자파의 신호 분석)

  • Park, Jae-Jun
    • The Journal of Information Technology
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    • v.7 no.3
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    • pp.113-118
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    • 2004
  • Recently, diagnosis techniques have been investigated to detect a partial discharge associated with a dielectric material defect in a high voltage electrical apparatus. However, the properties of detection technique of PD aren't completely understood because the physical process of PD. Therefore, this paper analyzes the process on Surface Discharge of Polymer Insulator using Wavelet transform. Wavelet transform provides a direct quantitative measure of spectral content in the time frequency domain. As it is important to develop a non-contact method for detecting the Contamination Degree, this research analyzes the electromagnetic waves emitted from PD using Wavelet transform. This result experimentally shows the process of PD as a two-dimensional distribution in the time-frequency domain. The method is shown to be useful for detecting prediction of contamination degree.

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Discharge Properties of Torch-Type Atmospheric Pressure Plasma and Its Local Disinfection of Microorganism (토치형 상압 플라즈마의 방전특성과 미생물의 국부 살균효과)

  • Son, Hyang-Ho;Lee, Won-Gyu
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.835-839
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    • 2011
  • The characteristics of torch-type atmospheric pressure plasma and its sterilization effects have been analyzed. The length of plasma flame was varied with the level of applied voltage and the mixture gases composed of argon and oxygen. The effect of plasma flame on the temperature increase of surface treated was limited to $43^{\circ}C$ as a maximum temperature under exposing time of 10 min. The sterilization for E. coli was strongly affected by the applied voltage, the oxygen ratio in the mixture gas and the treatment time. At a high concentration of ozone, the increase of treatment time under the direct contact with plasma flame yields to maximize the effect of the sterilization on E. coli.

Synthesis and Physicochemical Properties of Branched Solid Polymer Electrolytes Containing Ethylene Carbonate Group (에틸렌 카보네이트기를 함유하는 가지형 고체 고분자전해질의 합성 및 물리화학적 특성)

  • Kim, Doo-Hwan;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.18 no.4
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    • pp.150-155
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    • 2015
  • In this study polymer electrolytes containing ethylene carbonate group which have a high dielectric constant and poly(ethylene glycol) as branches were prepared by the Williamson reaction between poly(ethylene glycol) methyl ether and block copolymers composed of glycerol-1,2-carbonate and 4-chloromethyl styrene. Interestingly, the highest ionic conductivity of $1.75{\times}10^{-5}S\;cm^{-1}$ was observed from the polymer electrolyte having 7 mol% of ethylene carbonate and the [EO]:[Li] ratio of 32:1. Moreover, it was found that the electrochemical stability of polymer electrolyte was achieved up to 5.5 V because of the presence of ethylene carbonate.

Effect of Heating Rate and $V_2O_5$ Addition on Densification and Electrical Properties of $Pb(Mn_{1/3}Sb_{2/3})O_3-PZT$ Ceramics for Piezoelectirc Transformer (압전변압기용 $Pb(Mn_{1/3}Sb_{2/3})O_3-PZT$ 세라믹스에서 승온속도 및 $V_2O_5$ 첨가가 치밀화 및 전기적 특성에 미치는 영향)

  • 허수정;손준호;손정호;이준형;김정주;정우환;박명식;조상희
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.295-301
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    • 2000
  • The effect of V2O5 addition on the low temperature sintering of Pb(Mn1/3Sb2/3)O3-PZT ceramics, which is known as a prominent material for piezoelectric transformer application was studied, and the densification behavior and piezoelectric characteristics of the samples as a function of heating rate were also examined. V2O5 led the system to liquid phase sintering by forming liquid phase during sintering, which accelerated densification through the particle rearrangement in the early stage of sintering. The liquid phase mostly existed at grain boundaries retarded the evaporation of PbO, while the densification temperature and the weight loss of V2O5-free samples were higher than those of samples with V2O5. Faster heating improved the densification of the samples regardless of V2O5 addition. The low temperature sintering at 100$0^{\circ}C$ was achieved in PMS-PZT ceramics with high density and reasonable dielectric and piezoelectric characteristics. This result revealed optimistic way to the development of multi-layered piezoelectric transformers.

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Preparation and Characterization of Small Sized PZT Powders: A Sol-Gel Modified Approach

  • Choi, Kyu-Man;Lee, Hae-Chun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.1 no.2
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    • pp.27-32
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    • 2008
  • A current research basically diverted towards an increase in the operational output with the minimization of the materials used, which ultimately scaled down the dimensions of ceramic electronic components. In this direction the nano-technology pave the revolutionary changes in particular the electronic industries. The applications of nano-sized particles or nano-sized materials are hence, playing a significant role for various purposes. The PZT(lead, zirconium, titanium) based ceramics which, are reported to be ferroelectric materials have their important applications in the areas of surface acoustic waves (SAW), filters, infrared detectors, actuators, ferroelectric random access memory, speakers, electronic switches etc. Moreover, these PZT materials possess the large electro mechanical coupling factor, large spontaneous polarization, low dielectric loss and low internal stress etc. Hence, keeping in view the unique properties of PZT piezoelectric ceramics we also tried to synthesize indigenously the small sized PZT ceramic powder in the laboratory by using the modified sol-gel approach. In this paper, propyl alcohol based sol-gel method was used for preparation of PZT piezoelectric ceramic. The powder obtained by this sol-gel process was calcined and sintering to reach a pyrochlore-free crystal phase. The characterization of synthesized material was carried out by the XRD analysis and the surface morphology was determined by high resolution scanning electron microscopy.

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The Effects of Pressure, Temperature and Solvent Composition on Solvolysis of trans-[Co(N-eten)$_2Cl_2]^+$ in Water-t-butyl Alcohol Mixture

  • Park Yu Chul;Cho Young Je
    • Bulletin of the Korean Chemical Society
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    • v.9 no.1
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    • pp.1-4
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    • 1988
  • Rates of solvolysis of trans-[Co$(N-eten)_2Cl_2$]$^+$ have been investigated using spectrophotometric method at various pressures and temperatures in the mixtures of water with the t-butyl alcohol which possesses a high structure inducing capacity in water. The values of ${\Delta}V^{\neq}$ obtained from pressure effect on the rate constants were 2.55∼ 5.83 $cm^3mol^{-1}$. These values were discussed in terms of dissociative mechanism. Extrema found in the variation of ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$ with solvent composition correlated with extrema in the variation of the physical properties of the mixtures. The logarithms of rate constants correlated linearly with both Grunwald-Winstein parameter and the reciprocal of dielectric constant ($Ds^{-1}$). The gradient, m of Grunwald-Winstein plot for the trans-[Co$(N-eten)_2Cl_2$]$^+$ was 0.09, which is significantly lower than those for the other cobalt (Ⅲ)-dichloro complexes. It was suggested that the reaction is an Id mechanism with long extension of Co-Cl bond in the transition state, as found for the C-Cl bond in the transition state for the solvolysis of t-butyl chloride.