• Title/Summary/Keyword: High Membrane Voltage

Search Result 172, Processing Time 0.03 seconds

High-efficiency fuel-cell power inverter with soft-switching resonant technique (Soft-switching resonant technique을 적용한 고효율 PEMFC inverter)

  • Han, K.H.;Cho, Y.R.;Baek, S.H.
    • Proceedings of the KIEE Conference
    • /
    • 2005.10c
    • /
    • pp.326-328
    • /
    • 2005
  • In order to reduce the capital and overall operating cost of a fuel-cell system, a high-efficiency fuel-cell power inverter with a simple framework is required. The high-order two-inductance two-capacitance (LLCC) resonant technique is adopted in this study to implement a low-frequency 60-Hz sine wave voltage inverter utilized in the proton exchange membrane fuel-cell (PEMFC) system. The methodology for inverting dc voltage into low-frequency ac boltage is usually generated by the pulse-width-modulation (PWM) technique. However, the PWM-type inverter output has high-frequency harmonic components. Although an adequately designed filter could be utilized to overcome this problem, there are still some undesirable effects introduced by the high-frequency switching loss, electromagnetic-interference, harmonic current, and load variation. A novel power inverter via the LLCC resonant technique is designed for inverting dc voltage into 60-Hz ac sine wave voltage in the PEMFC system. This circuit scheme has the merits of low harmonic components, soft switching, high efficiency, and simplified implementation. The effectiveness of the proposed resonant inverter used for the PEMFC system is verified by numerical simulations and experimental results.

  • PDF

Changes of membrane resistance and membrane potentials by hyperpolarizing current stimulation in mouse unfertilized eggs (과분극 자극에 대한 mouse 미수정란의 세포막저항과 세포막전압의 변화)

  • Hong, Seong-geun;Kim, Ik-hyen;Cho, Young-deok
    • Korean Journal of Veterinary Research
    • /
    • v.31 no.1
    • /
    • pp.33-40
    • /
    • 1991
  • For the observations of both the membrane properties and the excitability on the unfertilized eggs of female mice, changes of the membrane resistance and the membrane potential by hyerpolarizing current stimulation were recorded. As current-voltage relation was linear over the entire range (-180mV~+60mV), membrane resistance($R_m$) was calculated from the amplitude of electrotonic potential to a given stimulus current. Also the presence of anode-break excitation was confirmed. The results were as follows; 1. There was a linear relation between the membrane resistance and resting membrane potential, the expected input resistance was 61. 4M$\Omega$(resting membrane potential was $-18.9{\pm}8.7mV$, mean${\pm}$SD, n=30). 2. Transient depolarization with overshoot was generated just after hyperpolarizing current stimulus and showed the dependency of stimulus duration. 3. Transient depolarization lasted over 30ms, amplitude of these depolarization was increased by high $Ca^{{+}{+}}$(20mM) and inhibited by $Ca^{{+}{+}}$-antagonist, $Mn^{{+}{+}}$. 4. From the above results, it was suggested that the unfertilized mouse egg showed the characteristics of the excitable cell.

  • PDF

Influence of the Catalyst Composition on Electrode Performance for Polymer Electrolyte Membrane Fuel Cells (촉매조성이 PEM용 연료전지의 전극특성에 미치는 영향)

  • 임재욱;최대규;류호진
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.9 no.3
    • /
    • pp.43-48
    • /
    • 2002
  • In this study, high performance electrode catalyst was developed in fabrication of membrane electrode assembly for PEMFCs(Polymer Electrolyte Membrane Fuel Cells). The I-V characteristics were measured to evaluate the influence of Nafion solution and Pt loading amount in the catalyst composition. The electrode characteristics were also investigated with respect to temperature change. The electrode performance was optimized at Nafion 5 wt% and 0.5 mg Pt/$\textrm{cm}^2$ content. The increase in the concentration of Nafion solution resulted in the decrease in electrode performance. At $80^{\circ}C$ of unit cell, I-V characteristics excelled those obtained at lower temperature. There was no difference in performance at low current density, but the improvement of voltage value in higher temperature could be found at high current density.

  • PDF

Low Actuation Voltage Capacitive Shunt RF-MEMS Switch Using a Corrugated Bridge with HRS MEMS Package

  • Song Yo-Tak;Lee Hai-Young;Esashi Masayoshi
    • Journal of electromagnetic engineering and science
    • /
    • v.6 no.2
    • /
    • pp.135-145
    • /
    • 2006
  • This paper presents the theory, design, fabrication and characterization of the novel low actuation voltage capacitive shunt RF-MEMS switch using a corrugated membrane with HRS MEMS packaging. Analytical analyses and experimental results have been carried out to derive algebraic expressions for the mechanical actuation mechanics of corrugated membrane for a low residual stress. It is shown that the residual stress of both types of corrugated and flat membranes can be modeled with the help of a mechanics theory. The residual stress in corrugated membranes is calculated using a geometrical model and is confirmed by finite element method(FEM) analysis and experimental results. The corrugated electrostatic actuated bridge is suspended over a concave structure of CPW, with sputtered nickel(Ni) as the structural material for the bridge and gold for CPW line, fabricated on high-resistivity silicon(HRS) substrate. The corrugated switch on concave structure requires lower actuation voltage than the flat switch on planar structure in various thickness bridges. The residual stress is very low by corrugating both ends of the bridge on concave structure. The residual stress of the bridge material and structure is critical to lower the actuation voltage. The Self-alignment HRS MEMS package of the RF-MEMS switch with a $15{\Omega}{\cdot}cm$ lightly-doped Si chip carrier also shows no parasitic leakage resonances and is verified as an effective packaging solution for the low cost and high performance coplanar MMICs.

Fast Fabrication of Nanoporous Anodic Alumina Membrane by Hard Anodization (하드애노디제이션에 의한 나노다공질 양극산화 알루미나 멤브레인의 제조)

  • Ha, Yoon-Cheol;Jeong, Dae-Yeong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2009.06a
    • /
    • pp.429-429
    • /
    • 2009
  • Nanoporous anodic alumina membranes (NAAM) with high-density through-hole pores fabricated by hard anodization of aluminum in 0.3 M oxalic acid under the applied voltage of 40 (mild anodization), 80, 100, 120 and 140 V were investigated. The current-time responses monitored using a PC-controlled anodization cell and the corresponding pore structures attainable from field-enhanced scanning electron microscopy (FE-SEM) were analyzed in order to establish the optimum fabrication process. The nanoporous structure can be produced for all the voltage conditions, while the stabilized through-hole pore formation seems to occur at 40, 80 and 140 V. The growth rate under 140 V hard anodization was over 30 times higher than under 40 V mild anodization (1.5 um/hr).

  • PDF

The Fabrication of Flow Sensors Using Pt Micro Heater (백금 미세발열체를 이용한 유량센서의 제작)

  • Noh, Sang-Soo;Chung, Gwiy-Sang
    • Proceedings of the KIEE Conference
    • /
    • 1997.11a
    • /
    • pp.609-611
    • /
    • 1997
  • Pt thin films flow sensors were fabricated by using aluminum oxide films as medium layer and their characteristics were investigated after annealing at $600^{\circ}C$ for 60min. Aluminum oxide improved adhesion of Pt thin films to $SiO_2$ layer without any chemical reactions to Pt thin films under high annealing temperatures. Output voltages increased as gas flow rate and gas conductivity increased because heat loss of heater, which was integrated with a sensing resistor in the flow sensor, increased. Output voltage of flow sensor fabricated on membrane structure was 101mV at $O_2$ flow rate of 2000sccm, heating power of 0.8W while flow sensor fabricated on Si substrate without membrane had output voltage of 78mV under the same conditions.

  • PDF

A Study on the Manufacturing of Porous Membrane for Separation of Gas Mixture by Al Anodizing Method (Al장극산화법에 의한 반휴분이용 다공성 격영의 제조에 관한 연구)

  • 윤은열;라경용
    • Journal of the Korean institute of surface engineering
    • /
    • v.15 no.2
    • /
    • pp.69-76
    • /
    • 1982
  • With a view to manufacturing membranes for separation of gas mixtures, Al foils were anodized in a 2% oxalic-acid electrolyte at 40V and 80V. When anodizing was completed and Barrier layer existed at the extreme back site of the foil, the anodized foil was made to react with only electrolyte, with switching off the electric power. When the size and density of pores were changed through voltage change, the membr-anes did not show large difference in the permeability. Reacting with electrolyte, the existing Barrier layer turns into porous layer. During this process, several small pores grow from one relatively large pore, getting to the back site. The number and size of the small pores getting to the back surface increase as time passing. This change of Barrier layer into porous layer is thought to be directly related to the permeability change of the membranes. The selectivity of an anodized Al membrane was not related to the voltage change, and was high, being similar to the theoretical selctivity of metallic membranes, according to my observation.

  • PDF

Understanding Thermodynamics of Operating Voltage and Efficiency in PEM Water Electrolysis System for Carbon Neutrality and Green Hydrogen Energy Transition (탄소중립과 그린 수소에너지 전환을 위한 PEM 수전해 시스템에서 작동 전압 및 효율의 열역학적 이해)

  • HyungKuk Ju;Sungyool Bong;Seungyoung Park;Chang Hyun Lee
    • Journal of the Korean Electrochemical Society
    • /
    • v.26 no.4
    • /
    • pp.56-63
    • /
    • 2023
  • The development of renewable energy technologies, such as solar, wave, and wind power, has led to the diversification of water electrolysis technologies, which can be easily coupled with renewable energy sources in terms of economics and scale. Water electrolysis technologies can be classified into three types based on operating temperature: low-temperature (<100 ℃), medium-temperature (300-700 ℃), and high-temperature (>700 ℃). It can also be classified by the type of electrolyte membrane used in the system. However, the concepts of thermodynamic and thermo-neutral voltages calculations and are very important factors in the evaluation of energy consumption and efficiency of water electrolysis technologies, are often confused. This review aims to contribute to a better understanding of the calculation of operating voltage and efficiency of PEM water electrolysis technologies and to clarify the differences between thermodynamic voltage and thermo-neutral voltage.

Characteristics of Hot-Film Type Micro-Flowsensors Fabricated on SOI Membrane and Trench Structures (SOI 멤브레인과 트랜치 구조상에 제작된 발열저항체형 마이크로 유량세선의 특성)

  • 정귀상;김미목;남태철
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.14 no.8
    • /
    • pp.658-662
    • /
    • 2001
  • This paper describes on the fabrication and characteristics of hot-film type micro-flowsensors integrated with Pt-RTD(resistance thermometer device) and micro-heater on the SOI(Si-on-insulator) membrane and trench structures, in which MGO thin-film was used as medium layer in order to improve adhesion of Pt thin-film to SiO$_2$ layer. Output voltages increased due to increase of heat-loss from sensor to external. The output voltage was 250 nV at N$_2$ flow rate of 2000 sccm/min, heating power of 0.3 W. The response time($\tau$:63%) was about 42 msec when input flow was step-input. The results indicated that micro-flowsensors with the SOI membrane and trench structures have properties of a high-resolution and ow consume power.

  • PDF

The Electrochemical Performance Evaluation of PBI-based MEA with Phosphoric Acid Doped Cathode for High Temperature Fuel Cell (인산 도핑 PBI계 막전극접합체를 적용한 고온형 수소연료전지의 전기화학적 내구성 연구)

  • RHEE, JUNKI;LEE, CHANMIN;JEON, YUKWON;LEE, HONG YEON;PARK, SANG SUN;KIM, TAE YOUNG;KIM, HEESEON;SONG, SOONHO;PARK, JUNG OCK;SHUL, YONG-GUN
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.28 no.5
    • /
    • pp.471-480
    • /
    • 2017
  • A proton exchange membrane fuel cell (PEMFC) operated at $150^{\circ}C$ was evaluated by a controlling different amount of phosphoric acid (PA) to a membrane-electrode assembly (MEA) without humidification of the cells. The effects on MEA performance of the amount of PA in the cathode are investigated. The PA content in the cathodes was optimized for higher catalyst utilization. The highest value of the active electrochemical area is achieved with the optimum amount of PA in the cathode confirmed by in-situ cyclic voltammetry. The current density-voltage experiments (I-V curve) also shows a transient response of cell voltage affected by the amount of PA in the electrodes. Furthermore, this information was compared with the production variables such as hot pressing and vacuum drying to investigate those effect to the electrochemical performances.