• Bulletin of the Korean Chemical Society
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• v.35 no.12
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• pp.3465-3474
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• 2014

Porous silica particles are the most prevailing raw material for stationary phases of liquid chromatography. During a long period of time, various methodologies for production of porous silica particles have been proposed, such as crashing and sieving of xerogel, traditional dry or wet process preparation of conventional spherical particles, preparation of hierarchical mesoporous particles by template-mediated pore formation, repeated formation of a thin layer of porous silica upon nonporous silica core (core-shell particles), and formation of specific silica monolith followed by grinding and calcination. Recent developments and applications of useful porous silica particles will be covered in this review. Discussion on sub-$3{\mu}m$ silica particles including nonporous silica particles, carbon or metal oxide clad silica particles, and molecularly imprinted silica particles, will also be included. Next, the individual preparation methods and their feasibilities will be collectively and critically compared and evaluated, being followed by conclusive remarks and future perspectives.

• The KIPS Transactions:PartA
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• v.16A no.5
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• pp.307-318
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• 2009

Modeling and rendering of atmospheric phenomena such as clouds is one of most difficult research themes in the field of computer graphics, mainly due to its complexity, huge volume, ubiquitousness, etc. In this paper, we represent a system for real-time modeling and rendering of clouds, mainly aiming at the computer games and flight simulation applications. Our implementation generates various kinds of clouds including cirrus, stratus, and cumulus, through intuitive real-timeuser interactions. Then, additional details are automatically attached to them, using our own methods based on meta-balls or hierarchical spherical particles. After processing multiple scattering and anisotropic scattering, resulting particles are rendered into billboards, to finally achieve real-time processing.

• Korean Journal of Materials Research
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• v.23 no.1
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• pp.53-58
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• 2013

Superhydrophobic $SiO_2$ layers with a micro-nano hierarchical surface structure were prepared. $SiO_2$ layers deposited via an electrospray method combined with a sol-gel chemical route were rough on the microscale. Au particles were decorated on the surface of the microscale-rough $SiO_2$ layers by use of the photo-reduction process with different intensities ($0.11-1.9mW/cm^2$) and illumination times (60-240 sec) of ultraviolet light. With the aid of nanoscale Au nanoparticles, this consequently resulted in a micro-nano hierarchical surface structure. Subsequent fluorination treatment with a solution containing trichloro(1H,2H,2H,2H-perfluorooctyl)silane fluorinated the hierarchical $SiO_2$ layers. The change in surface roughness factor was in good agreement with that observed for the water contact angle, where the surface roughness factor developed as a measure needed to evaluate the degree of surface roughness. The resulting $SiO_2$ layers revealed excellent repellency toward various liquid droplets with different surface tensions ranging from 46 to 72.3 mN/m. Especially, the micro-nano hierarchical surface created at an illumination intensity of $0.11mW/cm^2$ and illumination time of 60 sec showed the largest water contact angle of $170^{\circ}$. Based on the Cassie-Baxter and Young-Dupre equations, the surface fraction and work of adhesion for the micronano hierarchical $SiO_2$ layers were evaluated. The work of adhesion was estimated to be less than $3{\times}10^{-3}N/m$ for all the liquid droplets. This exceptionally small work of adhesion is likely to be responsible for the strong repellency of the liquids to the micro-nano hierarchical $SiO_2$ layers.

• Journal of Surface Science and Engineering
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• v.57 no.1
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• pp.49-56
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• 2024

Superhydrophobic surfaces have been expected to be able to provide considerable performance improvements and introduce innovative functions across diverse industries. However, representative methods for fabricating superhydrophobic surfaces include etching the substrate or attaching nanosized particles, but they have been limited by problems such as applicability to only a few materials or low adhesion between particles and substrates, resulting in a short lifetime of superhydrophobic properties. In this work, we report a novel coating technique that can achieve superhydrophobicity by electrophoretic deposition of aluminum nitride (AlN) nanopowders and their self-bonding to form a surface structure without the use of binder resins through a hydrolysis reaction. Furthermore, by using a water-soluble adhesive as a temporary shield for the electrophoretic deposited AlN powders, hierarchical aluminum hydroxide structures can be strongly adhered to a variety of electrically conductive substrates. This binder-free technique for creating hierarchical structures that exhibit strong adhesion to a variety of substrates significantly expands the practical applicability of superhydrophobic surfaces.

• Journal of Korean Society for Atmospheric Environment
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• v.13 no.5
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• pp.345-353
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• 1997

The purpose of the study was to stastically classify individual PM-10 measured by SEM/EDX (scanning electron microscopy/energy dispersive x-ray analyzer). The SEM/EDX provided various physical parameters like optical diameter, as well as major 18 chemical information (Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Br, Pb) for a particle-by-particle basis. The total of 1,419 particles were analyzed for the study. Thus density and mass of each particle can be estimated based on its chemical composition. Further the study developed 4 semisource profiles including highway, oil boiler, incinerator, and soil emissions, where each sample was collected near the source in the ambient air The profiles developed were consisted of mass fractions and their uncertainties based on a particle class concept. To obtain mass fraction of each particle class, an agglomerative hierarchical cluster analysis was initially applied to create particle classes for each sample. Then uncertainties were calculated for each class based on the jacknife method. The 1,258 particles out of 1,419 (88.7%) were assorted in newly generated particle classes. The study provides opportunities to identify particle's source quantitatively and to develope various receptor models.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.31 no.3
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• pp.133-140
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• 2018

This paper is concerned with the 2-D micostructure generation for $Ni-A{\ell}_2O_3$ dual-phase composite materials and the numerical analysis of mechanical characteristic of hierarchical models of microstructure which are defined in terms of the scale of microstructure. The microstructures of dual-phase composite materials were generated by applying the mathematical RMDF(random morphology description functions) technique to a 2-D RVE of composite materials. And, the hierarchical models of microstructure were defined by the number of Gaussian points. Meanwhile, the volume fractions of metal and ceramic particles were set by adjusting the level of RMD functions. The microstructures which were generated by RMDF technique are definitely random even though the total number of Gaussian points is the same. The randomly generated microstructures were applied to a 2-D beam model, and the variation of normal and shear stresses to the scale of microstructure was numerically investigated. In addition, through the crack analyses, the influence of RMDF randomness and Gauss point number on the crack-tip stress is investigated.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.50 no.6
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• pp.385-391
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• 2022

This paper presents to develop a path planning algorithm combining gradient descent-based path planning (GBPP) and particle swarm optimization (PSO) for considering prohibited flight areas, terrain information, and characteristics of fixed-wing unmmaned aerial vehicle (UAV) in 3D space. Path can be generated fast using GBPP, but it is often happened that an unsafe path can be generated by converging to a local minimum depending on the initial path. Bio-inspired swarm intelligence algorithms, such as Genetic algorithm (GA) and PSO, can avoid the local minima problem by sampling several paths. However, if the number of optimal variable increases due to an increase in the number of UAVs and waypoints, it requires heavy computation time and efforts due to increasing the number of particles accordingly. To solve the disadvantages of the two algorithms, hierarchical path planning algorithm associated with hierarchical particle swarm optimization (HPSO) is developed by defining the initial path, which is the input of GBPP, as two variables including particles variables. Feasibility of the proposed algorithm is verified by software-in-the-loop simulation (SILS) of flight control computer (FCC) for UAVs.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.44.2-44.2
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• 2012

Cosmological shock waves result from supersonic flow motions induced by hierarchical clustering during the large-scale structure formation in the Universe. Suprathermal particles are known to be produced via plasma interactions at collisionless shocks in tenuous plasmas and they can be further accelerated to become cosmic rays (CRs) via diffusive shock acceleration (DSA). The presence of CR electrons has been inferred from observations of diffuse radio halos and relics in some merging galaxy clusters. We have calculated the emissions from CR electrons accelerated at weak planar shocks, using time-dependent DSA simulations that include energy losses via synchrotron emission and Inverse Compton scattering. The simulated nonthermal emission are used to model the synchrotron emission from several observed radio relics.

• 유체기계공업학회:학술대회논문집
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• 2006.08a
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• pp.383-386
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• 2006

In this study, we propose a new fast algorithm for calculating short range forces in molecular dynamics, This algorithm uses a new hierarchical tree data structure which has a high adaptiveness to the particle distribution. It can divide a parent cell into k daughter cells and the tree structure is independent of the coordinate system and particle distribution. We investigated the characteristics and the performance of the tree structure according to k. For parallel computation, we used orthogonal recursive bisection method for domain decomposition to distribute particles to each processor, and the numerical experiments were performed on a 32-node Linux cluster. We compared the performance of the oct-tree and developed new algorithm according to the particle distributions, problem sizes and the number of processors. The comparison was performed sing tree-independent method and the results are independent of computing platform, parallelization, or programming language. It was found that the new algorithm can reduce computing cost for a large problem which has a short search range compared to the computational domain. But there are only small differences in wall-clock time because the proposed algorithm requires much time to construct tree structure than the oct-tree and he performance gain is small compared to the time for single time step calculation.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.200-200
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• 2011

Hierarchical mesoporous ZSM-5 with enhanced mesoporosity was synthesized by microwave through the rapid assembly via ionic interaction between sulfonic acid functionalized ZSM-5 nano particles and cationic surfactant. The catalytic performance of enhanced accessibility due to mesoporosity and acidity were investigated in the alkylation of mesitylene with benzyl alcohol as alkylating agent. The effect of mole ratio of aromatic with benzyl alcohol, reaction time and alkylation agent were also studied. The enhanced mesoporosity and acidity of sulfonic acid functionalized mesoporous ZSM-5 induced activity enhancement compared with non-functionalized mesoporous ZSM-5, sulfonic functionalized mesoporous ZSM-5 synthesized by hydrothermal method and conventional microporous ZSM-5. The sulfonic acid functionalized mesoporous ZSM-5 showed much higher chemoselectivity of benzylated mesitylene than others, whereas the others mainly show dibenzyl ether as product. This significant difference in catalytic selectivity was resulted from the existence of mesopores, which definitely allowed the benzylation in mesopores.