• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.23 no.2
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• pp.26-26
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• 1987

In this paper, an investigation of the property of blended fuel oil, combustion characteristics and engine performance was made, in case blended fuel oil(light oil+heavy oil) was used in a home-made precombustion diesel engine for small-sized fishing boat. The results may be summarized as follows: 1. The specific gravity was linearly increased in accordance with the increase in heavy oil ratio in blended fuel oil, and the relationship between viscosity and temperature was coincided with the formula of Walther-ASTM, and the CCAI, the ignition quality index, was increased nearly as a straight line of the gradient 1.0. 2. The ignition delay was slightly increased below 810 of CCAI(blending ratio to be 60% of heavy oil), but remarkably increased above 810 of CCAI. Therefore, it was considered that the practicable value of CCAI, ignition quality of blended fuel oil, was more than 810. 3. The maximum combustion pressure was increased until blending ratio of heavy oil was raised up to 40%. On the contrary, it came to be decreased at that ratio, with smoke emissions remarkably increasing above 60%. Therefore, it was found in this experiment that the best practicable limit of heavy oil blending ratio was around 50% for saving fuel costs with least smoke emissions.

• Journal of the Korean Wood Science and Technology
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• v.47 no.3
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• pp.344-359
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• 2019

Effects of various types of zeolite on the catalytic performance of hydrodeoxygenation (HDO) of bio-oil obtained from waste larch wood pyrolysis were investigated herein. Bifunctional catalysts were prepared via wet impregnation. The catalysts were characterized through XRD, BET, and SEM. Experimental results demonstrated that HDO enhanced the fuel properties of waste wood bio-oil, such as higher heating values (HHV) (20.4-28.3 MJ/kg) than bio-oil (13.7 MJ/kg). Water content (from 19.3 in bio-oil to 3.1-16.6 wt% in heavy oils), the total acid number (from 150 in bio-oil to 28-77 mg KOH/g oil in heavy oils), and viscosity (from 103 in bio-oil to $40-69mm^2/s$ in heavy oils) also improved post HDO. In our experiments, depending on the zeolite support, NiFe/HBeta exhibited a high Si/Al ratio of 38 with a high specific surface area ($545.1m^2/g$), and, based on the yield of heavy oil (18.3-18.9 wt%) and HHV (22.4-25.2 MJ/kg), its performance was not significantly affected by temperature and solvent concentration variations. In contrast, NiFe/zeolite Y, which had a low Si/Al ratio of 5.2, exhibited the highest improved quality for heavy oil at high temperature, with an HHV of 28.3 MJ/kg at $350^{\circ}C$ with 25 wt% of solvent.

• Korean Chemical Engineering Research
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• v.45 no.2
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• pp.109-116
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• 2007

As conventional light oil resources deplete, it is becoming necessary to develop unconventional resources. To meet the demand for petrochemical industry, heavier sources such as heavy oil and bitumen are being utilized. Bitumens, a complex hydrocarbon made up of a long chain of molecules, are found in oil sand. It is estimated that 830 billion barrels of oil are located in the oil sand in Alberta, Canada. This paper will review briefly (1) the basic concept of oil sand, bitumen, and heavy oil, (2) methods how to extract oil from oil sand, (3) methods how to upgrade to synthetic crude oil, and (4) economic evaluation of technology.

• Journal of Advanced Marine Engineering and Technology
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• v.34 no.2
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• pp.243-249
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• 2010

The improvement of fuel economy and the reduction of diesel exhaust PM(Particulate Matter) and $NO_X$ have been successfully achieved by supplying diesel engines with emulsified diesel oil. However, combustion analysis of emulsified C-heavy oil is difficult because the combustion characteristics of emulsified C-heavy oil compared to other fuels have a special form. Therefore, these experimental researches have analyzed the combustion characteristics of emulsified C-heavy oil in a chamber with high pressure and temperature. The pressure and the rate of heat releases in a combustion chamber was decreased with increasing the water content and the ignition delay time was increased with increasing the water percent.

• Membrane and Water Treatment
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• v.5 no.2
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• pp.147-170
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• 2014

This paper focuses on the study of the most recent ultra-filtration techniques, based on porous polymer membranes, used for the treatment of wastewater from oil, mine and hydrometallurgical industries. The performance of porous membranes used in separation and recovery of oil and heavy metals from wastewater, was evaluated by the polymer composition and by the membrane characteristics, as it follows: hydrophobicity or hydrophilicity, porosity, carrier (composition and concentration), selectivity, fouling, durability, separation efficiency and operating conditions. The oil/water efficient separation was observed on ultra-filtration (UF) techniques, with porous membranes, whereas heavy metals recovery from wastewater was observed using porous membranes with carrier. It can be concluded, that in the ultra-filtration wastewater treatments, a hybrid system, with porous polymer membranes with or without carrier, can be used for these two applications: oil/water separation and heavy metals recovery.

• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.343-352
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• 2016

It has been estimated that the Earth has nearly 1.688 trillion barrels of crude oil, which will last 53.3 years at current extraction rates. The organization of petroleum exporting countries (OPEC) group forecasted that the oil prices will not jump to triple-digit territory within a decade, but it can quickly increase as the political issue for reducing oil production appears. With the potential of serious shortage of conventional hydrocarbon resources, the heavy oil, one of unconventional hydrocarbon resources including oil sand and natural bitumen has attracted worldwide interest. The heavy oil contains heavy hydrocarbon compounds, commonly called as resins and asphaltenes, with long carbon chains more than sixty carbon atoms. The high content of heavier fraction corresponds with the high molecular weight, viscosity, and boiling point. Physicochemical properties of residues from vacuum distillation of conventional oil, referred to as vacuum residues (VR) were similar to those of heavy oil. For the development of heavy oil reserves, reducing the heavy oil viscosity is the most important. In this article, commercially employed aquathermolysis processes and their application to VR upgrading are discussed. VR contains transition metals such as Ni and V, but these metals should be eliminated in advance for further refining. Recent studies on demetallization technologies for VR are also reviewed.

• Clean Technology
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• v.22 no.4
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• pp.292-298
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• 2016

In this study, the pyrolysis process was carried out in order to upgrade of heavy oil contained in the resources from Indonesia. In order to investigate the composition and basic properties of the heavy oil contained in the resources, the various analytical methods was used and then the TGA (thermogravimetric) method was especially used for the thermal degradation characteristics of heavy oil in the pyrolysis. From the results obtained from the various analytical methods, the reaction conditions such as the reaction temperature was collected for the pyrolysis process and the pyrolysis using the resources containing the heavy oil was conducted using the fixed-bed reactor under the various reaction conditions. Consequently, We found that the content of heavy oil contained in the resources was about 35% and the conversion of heavy oil and the recovery efficiency of thermal degradation oil were about 21 and 80%, respectively.

• Journal of the Society of Naval Architects of Korea
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• v.46 no.4
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• pp.398-408
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• 2009

Crude oil carriers or product oil carriers are confronted with sea pollution due to hull damage from various accidents. To reduce the oil spillage of tankers, IMO(International Maritime Organization) and OPA 90(Oil Pollution Act 1990) adopted the hull structures of double skin type. In this study, oil spillage test of the double skin tanker with 1/100 scaled model was carried out under damaged condition due to collision and grounding accidents. A new structural type of oil tanker was also tested with pipe and valve system arranged in double side and single bottom hulls. Their results were compared with that of conventional type double hull on the view point of ship safety and oil spillage.

• Geosciences Journal
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• v.22 no.6
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• pp.1027-1039
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• 2018

Seismic attributes are often used to identify lithology and evaluate reservoir properties. However, interpretation based only on structural attributes and without knowledge of the Vp/Vs ratio can limit the ability to evaluate changes in heavy oil reservoirs. These limitations are often due to less obvious impedance differences. In order to investigate pieces of evidence of a heavy-oil shaly-sand reservoir from seismic data, besides geochemistry, we studied seismic attributes and characterized the reservoir using seismic stack data and well logging data. The study area was the Muglad rift basin in South Sudan. We conducted a seismic complex analysis to evaluate the target reservoir. To delineate the frequency responses of the different lithological units, we applied the spectral decomposition method to the target reservoir. The most unexpected result was continuous bands of strong seismic reflectors in the target reservoir, which extended across the borehole. Spectral decomposition analysis showed that the low-frequency zone of 25 Hz dominant frequency was consistent with instantaneous attributes. This approach can identify lithology, reveal frequency anomalies, and filter the stacked section into low- and high-frequency bands. The heavy-oil reservoir zones exhibited velocity attenuation and the amplitude was strongly frequency dependent.

• Applied Chemistry for Engineering
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• v.21 no.4
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• pp.372-376
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• 2010

Non-conventional energy is considered as important future energy source, as conventional energy has limitation for its capacity. The demand on value added process in heavy oil/oil sand bitumen is increasing in particular. Solvent Deasphalting (SDA) process for Deasphalted Oil (DAO) is used as heavy oil upgrading process in existing refinery process. SDA process for heavy oil upgrading has been already commercialized by leading countries. SDA R&D projects have been carried out actively by those countries. In this study, patent analysis for SDA technology development was carried out. From 1970's, when SDA patents were applied, the patents in Korea, USA, Japan, Canada and Europe were searched and distributed to extraction, recovery, solvent and etc. 334 patents were selected relating to heavy oil upgrading SDA process. The application status of SDA process patents showed a tendency to increase slightly. The number of patent applied was USA patent 131 (39%), Canada patent 83 (25%), Japan patent 35 (11%) and Korea patent 6 (2%). It will be necessary for efficient use of energy resource to support SDA R&D by government.