• Title/Summary/Keyword: Heavy Metal Pollution

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CO2 sequestration and heavy metal stabilization by carbonation process in bottom ash samples from coal power plant

  • Ramakrishna., CH;Thriveni., T;Nam, Seong Young;kim, Chunsik;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.74-83
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    • 2017
  • Coal-fired power plants supply roughly 50 percent of the nation's electricity but produce a disproportionate share of electric utility-related air pollution. Coal combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash and fly ash residues. These disposal coal ash residues are however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation process has been shown to have a potential for improving the chemical stability and leaching behavior of bottom ash residues. The aim of this work was to quantify the volume of $CO_2$ that could be sequestrated with a view to reducing greenhouse gas emissions and stabilize the contaminated heavy metals from bottom ash samples. In this study, we used PC boiler bottom ash, Kanvera reactor (KR) slag and calcined waste lime for measuring chemical analysis and heavy metals leaching tests were performed and also the formation of calcite resulting from accelerated carbonation process was investigated by thermo gravimetric and differential thermal analysis (TG/DTA).

Depositional Environment and Distribution of Heavy Metal off the Shihwa Dam

  • Oh, Jae-Kyung
    • Journal of the korean society of oceanography
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    • v.32 no.3
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    • pp.120-127
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    • 1997
  • Depositional environment off the Shihwa Dam has been studied to investigate the change of sedimentation process and the pollution. In order to understand how the sediments are distributed, polluted and modified, depositional factors have been analyzed and compared with the previous data. Study area, located off the Shihwa Dam, was surveyed to collect 25 bottom samples and 2 cores in 1996 and echo-sounding in 1997. These sediments were analyzed for the study of the global characteristics of sediment such as grain size and organic matter. Among these samples, the selected twenty surface sediments were analyzed for the comparison with their contents of metallic elements (Al, Mn, Fe, V, Cr, Co, Ni, Cu, Zn, Cd, Pb, As). According to field and lab analysis of sediments, three sedimentological zones have been generally identified around study area; near the dam (sandy Silt), near the dike (Sand) and offshore (silty Sand) zones. Textural parameters show that the content of silt and clay is dominant near the dam excepting the dike zone of LNG Storage Base and offshore (Palmido). The total concentration of Mn, Ni, Fe, Zn and Cd in bulk sediments was increased after the construction of the dam, while the content of Mn and Cr were higher near tidal channel than in the offshore area. Meanwhile, the annual increasing pattern of some heavy metal has appeared in this area. Based on this primary study, modification of the depositional environment may be caused by the construction of the dam and LNG Storage Base. Additionally, environmental evaluation on organic/inorganic factors has been suggested for interpreting environmental changes caused by coastal development in the nearshore such as the Shihwa coastal area.

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A Survey on the Heavy Metal Concentrations of Crop Materials Grown near Onsan Industrial Complex (온산공단(溫山工團) 주변 농작물(農作物)의 중금속(重金屬) 농도조사)

  • Lee, Su-Rae;Song, Ki-Joon
    • Korean Journal of Environmental Agriculture
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    • v.5 no.1
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    • pp.43-47
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    • 1986
  • In order to evaluate the pollution potential of agricultural crops after the construction of Onsan Industrial Complex (non-ferrous metal refineries), concentrations of hazardous heavy metals were analyzed for crop samples (rice, barley, soybean, vegetables and fruits) grown near the Complex in 1978. Although a slight difference was found among the kinds, parts and growing regions of the crops, no definite tendency was observed. The mean/maximum concentrations of crop samples were 0.23/4.0ppm As, 0.4/1.2 ppm Cd, 4.88/12.7ppm Cu, 0.09/0.4 ppm Hg, 3.86/5.0 ppm Pb and 41.3/105 ppm Zn, which may serve as the natural background data for this region.

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Assessment of Environmental Pollution for Streams of Andong City in Gyeongbuk Province Using Invertebrate Biomarker and Chemical Residual Analysis (무척추동물 생체지표와 화학잔류량 분석을 통한 경북 안동지역내 하천들의 환경오염 평가)

  • Ryoo Keon-Sang;Choi Jong-Ha;Kim Young-Gyun;Cho Sung-Hwan;Lee Hwa-Sung
    • Journal of Environmental Science International
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    • v.14 no.6
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    • pp.583-596
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    • 2005
  • Samples of water, soil, and sediment were taken from 10 streams of Andong city in Gyeongbuk province in October 2004. To assess the degree of environmental pollution for each stream site, the chemical analyses of pollutants such as T-N, T-P, COD, heavy metal, organophosphorous and organochlorine pesticides, and dioxin-like PCB congeners were implemented using the standard process tests or the U. S. EPA methods. In addition, biological assessment using insect immune biomarkers was conducted on the same environmental samples to complement the chemical assessment. Except Waya stream (T-N; 2.91 mg/L, T-P; 0.16 mg/L, COD; 14.0 mg/L) with above the environmental quality standards, the T-P and COD concentrations of 9 sites are relatively low. The contents of Pb and Cd in samples taken from each stream were much lower than environmental quality standards. However, in comparison with soil samples of other streams, several times higher concentrations of Pb and Cd were found in locations at Mi, Gilan, Yeonha, and Waya stream sites. Dementon-S-methyl, diazinon, parathion, and phenthoate compounds among organophosphorous pesticides were detected as concentrations of ppb levels, respectively, from soil samples collected in the vicinity of Gilan, Mi, Norim, and Waya stream. On the other hand, 16 organochlorine pesticides and 12 dioxin-like PCB congeners selected in this study were not found in all samples. In particular, considering significant disrupting effects of Waya stream's samples on insect immune capacity, this stream seems to be contaminated with investigated and/or univestigated pollutants in this study.

Avian research trends in Korea analyzed by text-mining and co-word analysis: based on articles of the Korean Journal of Ornithology (텍스트마이닝과 동시출현단어 분석을 이용한 국내 조류학 연구동향: 한국조류학회지 논문을 대상으로)

  • Jin, Chaelyeong;Eo, Soo Hyung
    • Korean Journal of Ornithology
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    • v.25 no.2
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    • pp.126-132
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    • 2018
  • For balanced development of ornithological research in Korea, it is important to review what birds and what research topics have been studied so far. We quantitatively investigated the trends of domestic ornithological research using text-mining and co-word analysis. As a result of studying 372 articles published in the Korean Journal of Ornithology, which is the most representative ornithological journals, words related to research topics such as population and community monitoring, first record of species and breeding ecology, and heavy metal pollution in birds have been widely used in research articles. Except for subjects such as monitoring and first record of species, studies have not been conducted widely. It was also found that research were concentrated on specific birds such as Anas platyrhynchos, Calidris alpina, and Anas poecilorhyncha. The present study, which analyzed the research topics and avian taxa that were relatively active until now and those which were insufficient, suggests what we should do in the future for the balanced development of ornithological research in Korea.

Concentration of Zn, Cu, and Pb in Soils and Accumulation of Its in Plants around Abandoned Mine Vicinity (폐광산 주변 토양의 Zn, Cu, Pb의 함량 및 식물체내 축적)

  • Seo Sang-Woo;Moon Sung-Gi;Choi Chul-Mann;Park Yeon-Kyu
    • Journal of Life Science
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    • v.15 no.5 s.72
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    • pp.826-833
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    • 2005
  • This study was conducted to inform basic data for management of abandoned mine that was based on soil heavy metal concentration of the non-rearing and the rearing sites in Guundong Mine which had been completed of improve contamination soils, and examined into standard plant which had tolerances about pollution that analyzed into its accumulated heavy metals contents in the wild plant of naked soil. Consider form the result of contents by depth of soils heavy metals in the non-rearing sites, S1 point judged by contaminated to heavy metals of tailing leach after weathering caused by rainfall and permeate in S1 point soils when restored rest of tailing in 1996 restoration project. Lead of S2 point was not contaminated seriously by restoration and S3 point considered that heavy metals which leach by rainfall in the contaminated soils in mine vicinity accumulated in the abandoned paddy through river When heavy metals of rearing sites soils were examined from the view point of upside of mine point (SP1, SP2, and SP3) of same above the sea level, zinc (537.5 mg/kg) content of SP1 point was highest, and copper (535 mg/kg) and lead (141.5 mg/kg) in the SP3 point were high. To considered as orderly plenty of heavy metals in the plant were respectively in order, Perilla frutescens var. cauta KUDO (SP1 and SP4) >Artemisia princeps PAMPAN (SP2) > Miscanthus sinensis ANDERSSON(SP5) > Vicia angustifolia var. segetilis (THUILL.) K. KOCH. (SP2). Especially, there were plenty of heavy metals in P. frutescens var. acuta, so it judged as a standard plant which have tolerances about heavy metals pollution sites. Therefore, we need more study about the heavy metals accumulate ability of P frutescens var. acuta in future.

Sanitory Significance on Drinking Water Quality Standard (음체수 수질기준에 대한 위생학적 의의)

  • 김종택
    • Journal of environmental and Sanitary engineering
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    • v.9 no.2
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    • pp.58-62
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    • 1994
  • Until 1960 water pollution was caused by virus but now in according to industrial develop cent it has been continued environmental pollution by surfactant heavy metal, and hazardous chemical substance erst.. It is possible to Prevent contamination by virus owing to development of antibiotic but not to dissolve basely health effect by hazardous chemical substances because it takes very long time, about 5-40 years, average 20 years, in appearing a disease after exposure by then To maintain human life for 75 years, it need 55 ton of water. In the experiment of Public Health Institute, Tokyo, they reported that over 200 chemical substances can be detected in case of human being to drink tap water of Tokyo(1989) continuously. In our country, elevation of life style and development of industry result in increase of water use and overappreciation of pesticides in farm land a(sects drinking water quality. We estimated analytical item of drinking water hygienically by dividing into 5 groups such as physical effect item health hazardous inorganic item and health hazardous organic item ect. based on hygienic purpose.

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Manufacturing of 2025 Coin Type PAn/Li-Al Secondary Battery (2025 Coin형 PAn/Li-Al 2차전지의 제조)

  • Moon, Seong-In;Yun, Mun-Soo
    • Proceedings of the KIEE Conference
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    • 1990.07a
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    • pp.202-206
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    • 1990
  • The existing batteries such as lead acid battery and Nicad battery have been at serious issue, because heavy metal such as Pb and Cd give rise to environmental pollution. Therefor, when these material is changed over polymeric electroactive material, we expect environmental pollution will be prevented. We decided to develop 2025 coin type PAn/Li-Al secondary battery for goal of memory back-up battery. This report is concerned with manufacturing of 2025 coin type PAn/Li -Al secondary battery.

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Effects of Acute Metal Exposures on the Viability and mRNA Expression of Metallothionein in Hemibarbus mylodon Fry

  • Bang, In-Chul;Cho, Young-Sun;Lee, Il-Rho;Nam, Yoon-Kwon
    • Korean Journal of Ecology and Environment
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    • v.40 no.4
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    • pp.489-494
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    • 2007
  • Transcriptional modulation of metallothionein (MT) during acute metal exposures (cadmium, copper or zinc) was examined in fry of Hemibarbus mylodon, a threatened fish species in Korean peninsula. Viability of H. mylodon fry was most affected by copper exposure (up to 79% of mortality at 1 ppm for 48 hours) and considerably by cadmium exposure (21 to 54% of mortality). On the other hand, Zn showed the least adverse effect on the viability (0 to 13% of mortality) of this species. Based on the semi-quantitative RT-PCR analysis, the stimulation of MT mRNA in response to metal exposures followed generally in a dose-dependent fashion where cadmium was the most potent inducer for the induction of MT transcripts in fry (up to more than 5-fold) while the lowest response was observed in zinc-exposed group (2-fold at maximum). From the exposure using environmentally realistic doses of cadmium (0 to 0.05 ppm for 24 hours), MT expression at mRNA level was also sensitively modulated toward upregulation up to more than 3-fold as relative to non-exposed control. Results from the present study would be a good basis for understanding the adaptive capacity and stress physiology of this endangered fish species during metal pollution.

Determination of Heavy Metal Content in Astacus leptodactylus caspicus of Anzali Wetland, Iran

  • Riahi, A.R.;Fazeli, M.Sh.;Paydar, M.
    • The Korean Journal of Ecology
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    • v.27 no.1
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    • pp.15-20
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    • 2004
  • With attention to different human activities around Anzali wetland and introduction of different pollutants containing heavy metals into this water ecosystem and absorption and accumulation of heavy metals in shell and muscle of Astacus leptodactylus which is native benthose of Anzali wetland and enjoys food and economic importance; Sampling of waters and sediments from 18 stations and shell and muscle of Astacus leptodactylus from 5 stations had been conducted. After biometric evaluation of Astacus leptodactylus, the chemical analysis of the samples by using international and standard methods and then their heavy metals content was determined by Atomic Absorpotion Spectrophotometer (AAS), model P.U 9400 philips. Result of the analysis stated that; 1) The mean values of Cr, Zn, Pb, Ni, V in Anzali waters were 6.4, 184.5, 28.8, 28.9, 47.1 ($\mu$ gr/lit) respectively, which comparing to the international standards, is not suitable for drinking, but it can be used for agricultural and aquacultural purposes. Even though the concentration of heavy metals in sediments were high, there are in range of acceptable limit for aquatics organisms; 2) Comparatively, the concentration of heavy metals in shell and muscle of Astacus leptodactylus in Anzali wetland (Cr, Zn, Pb, Ni, V in shell were 3.48, 109.3, 14.13, 7.17, 36.2 and in muscle were 2.98, 131.98, 3.12, 4.77, 9.05 ppm respectively) were more than what is determined for Aras dam (in shell were 1.6, 224.3, 7.8, 7.6, 10.3 and in muscle were 1.4, 60.2, 0.45, 2.7, 4.4 mg/kgr respectively); 3) For all samples, concentration of heavy metals in all Astacus leptodactylus in Anzali wetland and Aras dam, was at tolerance level for human consumption; 4) There was no association with significant difference between weight and size of Astacus leptodactylus with absorption and accumulation of heavy metals; but there was a significant association between heavy metals content in water and in sediments, and in sediments, shell and muscle of Astacus leptodactylus in Anzali wetland.