• Korean Chemical Engineering Research
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• 제45권4호
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• pp.319-327
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• 2007

소각은 유기성 유해폐기물에 대해 가장 발달된 유용한 처리기술로 인정되어 왔다. 그러나 PCBs와 같이 유해한 폐기물의 처리를 위한 소각로의 부지확보나 인허가가 유해한 대기오염 물질의 배출에 대한 주민의 우려로 용이하지 않다. 최근에 많은 소각 대체기술들이 개발되어 왔으며 이 기술들은 소각에 비해 다이옥신이나 퓨란과 같은 유해한 물질의 배출이 적어 주민의 우려를 완화시킬 수 있다. 본 논문에서는 다양한 유해폐기물의 종류에 대해 현재 적용이 가능한 소각 대체기술들을 검토하였다. 다양한 범주의 비열처리 및 열처리 소각 대체기술들을 공정운전조건, 적용대상 폐기물 및 이차폐기물 발생특성의 관점에서 평가하고 몇 가지 소각 대체기술들에 대해서는 공정의 운전원리에 대해 자세히 설명하였다.

• 한국대기환경학회지
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• 제16권6호
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• pp.665-674
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• 2000

A major source of the hazardous waste generated is from chemical industries producing plastics, herbicides, pesticides and chlorinated solvents. All of these processes produce a class if hazardous waste termed the chlorinated hydrocarbons(CHCs), either directly or from undesirable side reactions. In this study, we investigated the destruction characteristics of hazardous waste through incineration. A nonequilibrium combustion model was used to describe the effect of the chemical kinetics due to the flame inhibition characteristics of $CCl_4$ which was used as the surrogate of hazardous waste. A parametric screening studies was made in a dump incinerator proposed in this study. The dump incinerator showed high $CCl_4$ DRE(Destruction and Removal Efficiency) as 5 nines. $CCl_4$/CH$_4$ ratio appeared to be most important in the destruction of $CCl_4$ through incineration.

• 한국대기환경학회지
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• 제16권6호
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• pp.653-663
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• 2000

A lot of hazardous wastes are discharged as by-products of working process by industrial development. Hazardous wastes is physical characteristics of difficult destruction at hight temperature. Numerical simulation and combustion experiment performed of dump incinerator for hazardous waste incineration. For the numerical simulation, the SIMPLEST algorithm was used to ensure rapid converge A K-$\varepsilon$ model was incorporate for the enclosure of turbulence flow. Combustion model was used by ESCRS (extended simple chemically reacting system) model available of CHEMKIN thermodynamic data for the source term of species conservation equation or energy equation. Radiation model is used by six flux model. A parametric screening studies was carried out through numerical simulation and experiment. Residence time and concentration in the incinerator was strongly dependent on the parameters of mixture velocity, mixture equilibrium ratio, surrogate velocity and surrogate equilibrium ratio.

• 한국연소학회지
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• 제1권1호
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• pp.31-39
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• 1996

An equilibrium analysis was carried out to determine principal species in the incineration of hazardous waste, which was assumed as a compound of hydrocarbon fuel, chlorine, sulfur, and heavy metals, and their behaviors with variation of temperature, chlorine and sulfur concentrations. Calculated results showed that the most important parameter influencing the principal species was temperature. Chlorine concentration affected on mole fractions of the species, especially at high temperature. Existence of sulfur had a significant effect on the species at low temperature, regardless of surfur concentration. Generally, principal species at high temperature were chlorides and oxides, while the principal species at low temperature were sulfides. As temperature increased, mole fractions of the principal species increased at low temperature, however, mole fractions of some metal species decreased at high temperature.

• 대한기계학회논문집B
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• 제20권6호
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• pp.1983-1993
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• 1996

For selected (pure and compound) metallic species effects of saturation ratio, temperature, particle size and number density on condensation mechanisms are first reviewed. The tendencies for vaporization and condensation differ between metallic species because of the significant differences in their saturation pressures. Then particle pressure of a metal vapor species at incineration temperature is calculated by simplifying waste as a compound of methane, chlorine and small amounts of metals and assuming a thermodynamic equilibrium state. Next the condition is assessed for which supersaturation of combustion gases by the species above the critical level for homogeneous condensation may occur, when the gases contain a large number of pre-existing particles such as entrained ashes. Regardless of the presence of chlorine in the waste, the homogeneous condensation of PbO vapors may occur, depending on number density of the pre-existing particles. However, when chlorine exists in the waste, the homogeneous condensation of PbCl$_2$vapors does not occur, which is similar to the case of Cd and Hg vapors. Thus these highly volatile species, PbCl$_2$, Cd, and Hg, may emit to atmosphere as vapor phase. In general, for reducing the emission of hazardous metallic species into the atmosphere, the number density of pre-existing particles has to be increased. For fixed particle number density, the temperature drop rate must be kept in low if the temperature at which a condensable vapor species emits from a incineration system is fixed, while the temperature drop rate must be kept in high if the residence time for which a condensable species stays in the system is fixed.

• 공업화학
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• 제3권2호
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• pp.207-212
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• 1992

Main disposal technology for industrial wasites in Korea has been landfilling, however, this is encountering serious problems such as the lack of landfill sites and objections of residents. Incineration, therefore, has become a final solution for this dilema. Various kinds of air pollutants generation are possible because of the variety of types and compositions of wastes generated in industry. In this paper, air pollutants produced while incinerating hazardous industrial wastes are discussed and some control technologies are surveryed with the purpose of optimal design of incinerators and emission reduction. From this initial stage of incinerator utilization, low-emission type should be developed and applied and intensive research on pollutant generation due to waste incineration and advanced control technologies should be also performed.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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• pp.15-19
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• 2006

The meat consumption produces a lot of bone waste everyday. Dumping bone waste without treatment results into environmental hazards. Conventional treatment by pyrolysis is slow, inefficient and produces hazardous by-products. In the work, an investigation of bone waste incinerated using thermal plasma technology is presented. A high temperature arc plasma torch operated at 33 kW was employed for the experiments. Bone waste was incinerated to remove the infectious organic matter and to vitrify the inorganic matter using plasma torch. Bone waste was reduced its 2/3 weight after the treatment. The process was highly efficient, economical, convenient, and fuel free. This method could be used as an alternative method for disposal of bone waste, small infectious animals, hazardous hospital waste, etc.

• 한국지역사회생활과학회지
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• 제18권1호
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• pp.39-53
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• 2007

The purpose of this study was to determine the characteristics of an experimental protective clothing material with regard to comfort and isolation from the hazardous heavy metals produced in municipal waste incineration. An analysis was conducted on the total concentrations of heavy metals in some parts such as surface, middle layer, and interior for the treated fabric, and the untreated one, and working clothes. We conclude that the processed fabric with charcoal for working clothes showed the least exposure to heavy metals of the three. Working clothes worn by workers during waste incineration were much more contaminated than the untreated and treated materials. The material of working clothes could be chosen according to the function with regard to its original chemical characteristics, which are the proper results of the dyeing process. The processed fabric material has high degrees of moisture regain, thermal insulation, water vapor penetration, and antibacterial function; consequently, it is much more comfortable to wear. The fabric material proposed in this research contributed much more to blocking heavy metal concentrations (such as Cd, Pb, Cu, Cr, Zn, Mn) than did the fabric of working clothes at present. Consequently, we strongly suggest that the material of working clothes be upgraded by adopting the above-mentioned charcoal-processed fabric. Materials of working clothes must be improved to increase comfort and prevent harmful gas, flying dust, and heavy metals from permeating the fabrics.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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• pp.165-172
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• 2004

Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as $SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge.

• 한국환경보건학회지
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• 제47권1호
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• pp.20-35
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• 2021

Objectives: Waste treatment by incineration is gradually increasing as the emission of harmful substances has decreased owing to developments in incineration technology. However, residents living near incinerators continue to express anxiety regarding the effects on their health. Therefore, we attempted to summarize the health impact of incinerators by comprehensively reviewing the recently reported literature. Methods: Sixty-two epidemiological research papers related to incineration and health effects were selected from the Google Scholar database and analyzed (from between January 2001 and December 2019). Results: When compared to older incinerators, newer incinerators established after 2000 are considered relatively safe in terms of health effects. Nevertheless, there have been some studies that have linked them to various diseases, such as malignant tumors including soft tissue cancer and non-Hodgkin's lymphoma, reproductive disorders, respiratory diseases, and more. In addition, incinerator workers and local residents are considered to be exposed to dioxins and some heavy metals from the incinerator. Since most studies included subjects exposed to older incinerators, it is difficult to apply these results to the health impact assessment of new incinerators. However, it is not appropriate to conclude that new incinerators made with state-of-the-art technology are safe, as chronic environmental diseases caused by hazardous substances tend to appear only after prolonged exposure. Conclusions: In terms of environmental health, it is necessary to continuously monitor the health effects of incinerators. Also, there is a need to develop a research methodology that can minimize various confounders in incineration-related epidemiological study.