• Computers and Concrete
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• v.6 no.1
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• pp.1-18
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• 2009

Chloride diffusivity of concrete is a crucial material parameter for service life determination and durability designing of marine concrete. Many research works on this issue have been conducted, varying from empirical solutions obtained experimentally to image analysis, based on multi-scale modeling. One of the simple approaches is to express the chloride diffusivity of concrete by a multi-factor function, however, the influences of various factors on the chloride diffusivity are ambiguous. Furthermore, the majority of these research works have not dealt with the carbonation process of concrete, although this process affects the chloride diffusivity of concrete significantly. The purpose of this study is to establish a simple approach to calculate the chloride diffusivity of (non)carbonated concrete. The chloride diffusivity of concrete should be defined, based on engineering and scientific knowledge of cement and concrete materials. In this paper, a lot of parameters affecting the chloride diffusivity, such as the diffusivity in pore solution, tortuosity, micro-structural properties of hardened cement paste, volumetric portion of aggregate, are taken into consideration in the calculation of the chloride diffusivity of noncarbonated concrete. For carbonated concrete, reduced porosity due to carbonation is calculated and used for calculating the chloride diffusivity. The results are compared with experimental data and previous research works.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.107-108
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• 2022

In recent years, the construction industry has a tendency to increase of high-rise builidngs. High rise buildings can use limited space efficiently. But High rise buildings have problem that have extremely heavy weight. Various studies are being conducted to reduce the weight of buildings. Although lightweight aggregate is a meterial that can effectively reduce the weight of buildings, the strength of the aggregate itself is weak and the absorption rate is high, so the strength of the ITZ(Interfacial Transition Zone) area is weak. Therefore, it is essential to improve the interfacial area when using lightweight aggregates. In this study, an experiment was conducted to improve the adhesion between the aggregate and cement paste and to strengthen the interfacial area by coating the surface of the lighteight aggregate with Blast Furnace Slag. To confirm the improvement, compressive strength and EIS(Electrochemical Impedance Spectroscopy) measurements were perfromed. Using EIS, the change in electrical resistance of the cement hardened body was confirmed. As a result, it was confirmed that the lightweight aggregate coated on the surface showed highter compressive strength and electrical resistance than the non-coated lightweight aggregate, and that the coating material was filled in the interfacial area and inside the aggregate that helped to strengthen the compresssive strength and higher electrical resistance.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.2A
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• pp.297-304
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• 2008

It is well known that cracks in concrete decrease permeability and durability of concrete because cracks enhance the penetration of water or corrosive chemicals like as chlorides, carbon dioxides, sulfates and some others. But some of cracks in hardened cements may be sealed in case of contacting water. This phenomenon is called "self healing" and it has a close relation to hydration products newly formed on surfaces of cracks. Many studies on self healing in concretes commonly showed that CSH gel has been observed on crack surfaces. And some studies have reported that calcium hydroxides and ettringite were observed as well as CSH gel on crack surfaces. This study was carried out to investigate hydration products formed by self healing process and also examine the influence of waterproof admixture for concretes on self healing of cement. As a result of XRD, DSC, SEM and EDX analysis of crack surfaces, it was found that self healing of cement was related to CSH gel, calcium hydroxides and ettringite. And waterproof admixture increased fibrous (needle-like) hydration products which were in network form. It is estimated that such fibrous products are effective for self healing process of cement system.

• Magazine of the Korea Concrete Institute
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• v.6 no.5
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• pp.131-139
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• 1994

The min aim of thls study was to evaluate the effect of particle slze of the fly ash as a cement additive. Experimental work was carried out with three different sizes of fly ash. 18.58, 8.95 and 4.02{$mu}m$ in average radius. Namely, the effect of particle size variation of fly ash on the physical properties of cement paste was investigated. The jluidity was decreased with increasing the addition of fly ash to cement paste regardless of the particle size variation. The decrement of the fluidity of the pulverized fly ash was higher than that of the spherical fly ash. On the other hand, the pozzolan reactivity increased with lowering particle size. In the case of specimens with 5% up to 10% addition of fly ash having a particle size of 4.02{$mu}m$. the compressive strength was increased as compared with the plain specimens before curing for 28 days and showed higher value above 800kg /$cm^2$ when cured for 60 days.This increased compressive strength was ascribed to both the closer packlng of fine particles and the pozzolan reactivity of fly ash. These results were comfirmed by measuring both the porosity of the specimens and Ca(OH ), contents remained in specimens. This work showed that could be effectively ut~lized as a blending material without any de crease in the strength of early hydration stage if we can control the particle size of fly ashes by sizing or pulverizing.

• Journal of the Korean Ceramic Society
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• v.24 no.1
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• pp.77-85
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• 1987

Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

• Journal of the Korea Concrete Institute
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• v.18 no.2 s.92
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• pp.189-198
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• 2006

The composition of most engineering materials is heterogeneous at some degree. It is simply a question of scale at which the level of heterogeneity becomes apparent. In the case of cementitious granular materials such as concrete the heterogeneity appears at the mesoscale where it is comprised of aggregate particles, a hardened cement paste and voids. Since it is difficult to consider each separate particle in the topological description explicitly, numerical models of the meso-structure are normally confined to two-phase matrix particle composites in which only the larger inclusions are accounted for. 2-D and 3-D concrete blocks(Representative Volume Element, RVE) are used to simulating heterogeneous concrete meso-structures in the form of aggregates in the hardened mortar with nearly zero-thickness linear or planar interfaces. The numerical sensitivity of these meso-structures are Investigated with respect to the different morphologies of heterogeneity and the different level of coupling constant among fracture mode I, II and III. In addition, a numerically homogenized concrete block in 3-D using Hashin-Shtrikman variational bounds provides an evidence of the effective cracking paths which are quite different with those of heterogenous concrete block. However, their average force-displacement relationship show a pretty close match each other.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.367-374
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• 2019

Drying shrinkage in the hardened cement is known to change in volume by decreasing the moisture content in the hardened body, and it is known that the higher the W / C and the higher the content of the paste, the larger the drying shrinkage. In the case of ECC, more drying shrinkage occurs compared to concrete, since it does not contain coarse aggregate. Since ECC is an important material for tensile performance, the effect of restrained tensile stress on mechanical tensile behavior should be considered. The purpose of this study is to analyze the effect of stress caused by restraint on the tensile behavior of ECC. The mechanical properties of the specimens were tested by uniaxial tension tests with different restraints. As a result, the difference of tensile behavior according to restraint stress was observed and the cause was analyzed.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.461-464
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• 2008

This study investigated mechanical properties of the concrete using standard contents which was existent fibers in korea to apply the method for reducing crack of the non-reinforced concrete for the public space of an apartment with a fiber reinforcement. Results were summarized as following. The slump was slightly declined corresponding to the increase of the surface area and bridge effect of the fibers. For properties of the hardened concrete, the compressive strength was slighty reduced caused by the decrease of bonding strength between fiber and cement paste. The tensile strength was little increased according to bridge effect of the fibers, and the flexible strength and length change due to the drying shrinkage did not showed remarkable tendency.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2007.04a
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• pp.9-12
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• 2007

Recently, research and development related to high strength concrete for the high rise and large scale reinforced concrete building has been actively promoted in worldwide by national and private research project. But, it is reported that violent explosive explosion would be happened when it was exposed in fire. In the existed study, a explosion in a reinforced concrete structure looses the organism by the different contraction and expansion of hardened cement paste and aggregate, and causes crack by thermal stress. In case of the Europe, Japan and America, they have studied the explosion for a long time. However it would hardly study the explosion in domestic, So it is needed base on mechanical properties of fire deterioration in high strength concrete. Therefore, this study is intend as an mechanical properties of specimen to high heating by heating and load test machine and $700^{\circ}C$. As a result, it is willing to propose fundamental data for quick and accurate diagnosis of deteriorated concrete structure by fire damage with experiment according to the design high strength concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05b
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• pp.305-308
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• 2005

The sulfuric acid may react with the hardened cement paste and originate expansive products which can induce swelling and disaggregation of concrete. The purpose of this study is to estimate the antibacterial performance of antibiotics and the effect of absorbed condition of restorative mortar, the number of coating times and coating contents with antibiotic on the fundamental properties of restorative mortar spead with antibiotics. Also, testing items such as bonding strength, abrasion contents, contents of water absorption, contents of air permeability was tested to estimate the fundamental properties in this study. In results, the novellus bacillus inhabiting in sewer concrete structures was restrained by antibiotics developed in this study. And bonding strength of restorative mortar spread with antibiotics was similla to that of plain mortar. But, resistance to abrasion, water absorption and air permeability of restorative mortar spread with antibiotics was superior to that of plain mortar.