• Carbon letters
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• 제10권3호
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• pp.190-197
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• 2009

Various silanes, amino silane, vinyl silane, sulfur silane (TESPD), and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB) and CIIR/hard clay/CB compounds and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. Comparing hard clay and soft clay filled compounds, hard clay (Suprex) filled system shows a higher die C tear than the soft clay (GK) filled one. The other properties (Mooney, extrusion torque/pressure, torque rise ($M_H-M_L$), modulus at 300%) are close to each other. Among various silanes, the ZS treated hard clay (Suprex) compound shows the highest mechanical property following hard clay(S)/vinyl silane(V) and soft clay(GK)/vinyl silane(V) compounds. The TESPD and the ZS effectively helps a formation of a strong 3-dimensional network structure between silica and CIIR via coupling reaction due to bifunctional nature of TESPD. In addition to that, the ZS added compounds show both a better processability and mechanical properties compared to the S2 ones at low concentration due to improved compatibility between zinc soap and CIIR matrix. Only the ZS added compound shows both improved processabilities (Mooney, Extrusion torque-& pressure) and improved mechanical properties (degree of crosslinking, elongation modulus, tear, and fatigue to failure counts) on both CIIR/hard clay/CB and CIIR/soft clay/CB compounds.

• Carbon letters
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• 제10권2호
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• pp.101-108
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• 2009

Various silanes, amino silane, vinyl silane, TESPD, and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/hard clay/carbon black (CB) compound and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. In hard clay/CB filled system, only ZS silane added compound shows both lower Mooney viscosity and extrusion torque while vinyl silane added compound showed only a lower extrusion torque. All the ZS added compounds showed the lowest viscosity among them. The silane added compounds showed an increased modulus. In 'fatigue to failure' count test, the ZS added compound showed superior counts compared to other silane (amino, vinyl, TESPD) added compounds. The mechanical properties were significantly increased when the S2 and ZS were added into CIIR/hard clay/CB compound. The ZS added compounds showed a significant improvement on elongation modulus.

• Elastomers and Composites
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• 제24권4호
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• pp.276-289
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• 1989

This study deals with both effects of inorganic fillers to vulcanized rubbers such as NR, CR, EPDM, NBR & SBR and inorganic characteristics of domestic fillers in comparision with hard clay produced in the USA. The results were as follows. 1. Main ingredient of domestic clay "Ha-dong clay" was Halloysite, "No-ha Island" was Pyrophyllite with $\alpha$-Quartz, and both of "Hard clay" & "Hwa-soon clay" were proved to be Kaolinite by XRD, DT-TGA and chemical analysis by XRF. 2. Tensile strength value of SBR compounded with these fillers, was Hard clay $146kg\;f/cm^2$, Kaolinite $123kg\;f/cm^2$, Pyrophyllite $82kg\;f/cm^2$, Halloysite $80kg\;f/cm^2$, precipitated $CaCO_3\;27kg\;f/cm^2$, and ground $CaCO_3$ was $21kg\;f/cm^2$. These results showed the increase of seven times according to filler species. 3. The physical properties of non-crystalline rubbers, such as SBR, NBR & EPDM, compared with NR & CR, have been considerably changed according to crystalline phase, particle size, shape and surface structure of fillers. Especially, tensile strength value in case of SBR & EPDM, was differentiated about 1.5 times by the particle size of fillers. 4. In SBR, physical properties of rubber compounded with Kaolinite which was surface treated with fatty acid and silane, almost approach to the value of hard clay. 5. Delayed cure time of Kaolinite and decrease of rubber properties by $CaCO_3$ can be improved by blending kaolinite & $CaCO_3$ in the ratio of 2:1.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2006년도 춘계 학술발표회 논문집
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• pp.1032-1037
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• 2006

This thesis studied effects of the excavation around railroads on the deformation of the lateral ground and neighboring railroads. The conclusions of the study are as follows. 1. When the depth of excavationis 10m, the influential area should be 35m for soft clay, 20m for normal clay, 15m for hard clay, 15m for loose sand, 12m for slightly dense sand, and 8m for dense sand. 2. When the influential area is 10m, the allowable excavation depth should be 2.5m for soft clay, 4.8m for normal clay, 7.5m for hard clay, 7.2m for loose sand, 8.8m for slightly dense sand, and 10m for dense sand. 3. When the influential area is 20m, the allowable excavation depth should be 4.5m for soft clay, and up to 10m for the other five kinds of soil. 4. When the influential area is 30m, the allowable excavation depth should be 7.5m for soft clay, and up to 10m for the other five kinds of soil. 5. When the influential area is 35m, the allowable excavation depth should be up to 10m for all kinds of soil.

• 한국지반공학회지:지반
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• 제1권2호
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• pp.27-40
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• 1985

본고는 기약지반변형해석에 이용될 범용 program을 개발하고 이를 이용하여 성토부끝에 sheet pile을 타설하거나 혹은 성토부아래의 연약정토지반을 개취하였을 때의 변형억제효과를 연구한 것이다. 본고에 적용된 압밀리론으로서 Biot의 압밀방정식과 구성방정식으로서 탄소성리론에 근거한 modified Cam-clay 이론을 적용하였고 유한요소해석으로서는 Christian-Boehmer계를 도입하여 program화한 것이다. 그 주요한 결론은 다음과 같다. 1. 속변지반의 침하효과에 관해서는 sheet pile이나 심우혼합처새깊이를 자지층까지 관입하여 시공하고 그 자신의 침하가 없을 경우에만 유효하다. 2. 흔히 사용되는 sheet pile대책공법은 통상의 steel sheet pile의 각성으로서는 성토직후의 봉기, 측방변위의 억제효과는 기대할 수 없다. 3. Sheet pile에 대한 예상론인 사용방법은 성토하부에 세밀을 촉진하기 위해 vertical drain을 설치하고 점증재하 방법만이 확실한 효과가 있다. 4. 체층혼합처리공법은 예상한 바와 같이 그 자종가 강성이 클수록 침하억제핵과가 있다. 특히 grouting을 통한 지반강화가 곧장 주변지반의 변형억제효과가 있다고 단정하는 것은 그 강성 까 관련하여 신중히 고려하여 결정해야 한다.

• 한국결정성장학회지
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• 제21권2호
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• pp.92-97
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• 2011

화력발전소에서 발생하는 석탄회의 일종인 저회는 현재 적절한 재활용 방법이 연구 되지 않아 대부분 매립에 의존하고 있는 실정이다. 본 연구에서는 비가소성 분체인 저회의 재활용율을 높이며, 저회를 점토 대체 원료로 재활용하기 위하여 저회와 점토의 계면화학적 성질을 조절하여 Bottom-ash(B/A)-Hard Clay(H/C) 소지의 물성변화를 관찰하였다. H/C 100 %, H/C60 % + B/A40 %에 대하여 각 조성별 pH에 따른 침강높이를 관찰한 결과 점토와 저회는 계면 화학적 성질이 비슷하여 혼합하여 슬립제조 시 hetero-polar 응집현상이 없었다. 또한 각 조성별 점도가 조절된 Slip을 주입 성형하여 $1100{\sim}1250^{\circ}C$에서 $50^{\circ}C$ 간격으로 소결하여 각 시편에 대한 비중, 흡수율을 측정하고 미세구조를 관찰하였다. 그 결과 분산된 점토와 저회 슬립은 Bingham 가소성 거동을 보이므로 주입성형 및 가소성형이 가능하며, 분산된 점토와 저회 슬립으로부터제조된 소결체는 $1250^{\circ}C$에서 KSL 4201과 KSL 1001의 규격을 만족할 뿐 아니라 특히 비중이 약 15 % 이상 경량이므로 도자기나 위생도기 등의 소지로 응용 가능성이 있다고 사료된다.

• 청정기술
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• 제12권1호
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• pp.11-18
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• 2006

poly[hexamethylene carbonate]glycol(PHMCG)과 isophorone diisocyanate (IPDI), dimethylol propionic acid(DMPA)를 이용하여 수분산성 폴리우레탄을 합성하였다. 또한 여기에 나노 clay(PM) 및 이를 각기 다른 유기화제로 개질시킨 C15A와 C30B를 첨가하여 폴리우레탄/clay 나노복합재료를 제조하였다. 제조된 나노복합재료에서의 clay의 분산정도를 XRD를 이용하여 조사하였으며 clay가 첨가된 경우의 기계적 물성 및 열적성질을 UTM 과 TGA를 통하여 분석한 결과, C15A가 첨가된 경우 나노clay가 폴리우레탄에 가장 잘 분산된 것으로 관찰되었으며, 기계적 물성과 열적 물성이 C30B 또는 PM을 첨가한 경우보다 높게 측정되었다. 이로부터 clay에서 개질유기화제의 종류 및 함량이 나노복합재료의 최종물성에 영향을 주는 것을 알 수 있었다.

• 한국해양공학회지
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• 제10권4호
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• pp.141-148
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• 1996

Use of stone column for deep ground treatment in soft clay soils is an effective method. The stone column significantly increases load carrying capacity of the soft clay soil. A analysis method for bearing capacity of stone column in soft clay soil is developed. The capacity made by developed method are compared wity observed values from field load test and a reasonable correlation is noted.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 추계 학술발표회
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• pp.1144-1156
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• 2008

In this paper, heaving phenomenon is analyzed by laboratory tests. A laboratory test is consist of building soft clay foundation in plane-strain soil tank, construction of retaining wall, and excavation work. And range of shear strain, and destruction shape about soft clay foundation is compared, and analyzed with results of proposal formula. Using this study, safety factor is suggested for heaving phenomenon in the construction of wall on the soft clay. Actual theory is suggested by this suggested safety factor. There are various proposal formula for heaving phenomenon. For example, Terzaghi & Peck, Tschebotarioff, Bjerrum & Eide(Experience formula) and so on. Terzaghi & Peck's proposal formula is chosen, compared with laboratory test's result and analyzed in this study. A soft clay used in study is assumed homogeneous. A Depth of foundation is enough to observe shear strain by heaving phenomenon. Retaining wall is enough hard not to have vertical displacement.

• 한국건축시공학회지
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• 제1권1호
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• pp.160-168
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• 2001

This study aims at the development of computer program for the deformation analysis of soft ground, and using this computer program, study the constraint effect of deformation heaving, lateral displacement of the soft ground reinforced with improvement of soft ground up to hard strata, under intact state(natural). The following results are obtained. 1. Improvement of soft ground to the hard strata works well against the settlement of neighboring ground. 2. the larger the rigidity or width of improvement of layer to hard strata is, the less settlement occurs. 3. Improvement of soft ground to the hard strata is of no use.