• Title/Summary/Keyword: HEAT 탄

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Heat Transfer Characteristics on the High Speed Bullet Penetrated a Fuel Tank (고속충격탄의 연료탱크 관통시 열전달 특성)

  • Lee, Seung-Chul;Park, Young-Rok;Jeon, Woo-Chul;Lee, Hae-Pyeong
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.11a
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    • pp.533-536
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    • 2011
  • 본 연구에서는 차량 연료탱크에 충격탄 관통 시 화재발생 여부를 분석하기 위한 연구의 전단계로서, 충격탄 속도 변화에 따른 연료탱크 내부의 열전달특성을 분석하기 위해 전산유체역학기법을 도입하여 수치해석을 수행한 결과 다음과 같은 결론을 얻었다. 잔류속도 120m/s의 경우, 관통부를 지난 위치에서 최대온도는 약 324.8K를 나타내고 잔류속도 360m/s의 경우, 충격탄이 관통부로 유입되면서 급격하게 증가되어 최고온도 약 382.1K를 나타낸다. 이러한 결과로 미루어 최고 온도가 가솔린 연료의 착화온도보다 높아 화재의 위험성이 있지만 순간적인 온도변화가 심하고 착화시간이 만족되지 않을 것으로 판단된다.

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Application of Suspension-Polymerized Spherical PAN beads as a Precursor of Spherical Activated Carbon (현탁중합으로 합성된 구형 PAN 수지의 구형 활성탄의 전구체로서의 활용)

  • Hyewon, Yeom;Hongkyeong, Kim
    • Journal of Institute of Convergence Technology
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    • v.12 no.1
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    • pp.13-18
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    • 2022
  • Polyacrylonitrile was synthesized through suspension polymerization and then sieved to obtain spherical beads with a size of 200~510 ㎛. PAN was copolymerized with 2 mol% MMA monomer which is known to promote cyclization and crosslinking of nitrile group. The resonance cyclization reaction of the nitrile group in the synthesized PAN beads was observed near 170℃ with thermal analysis and FT-IR. The reaction conversion of the nitrile group in spherical beads was 23% during heat treatment, which was lower than that of the well-oriented PAN fiber used as a precursor of carbon fiber. This is because the stereo-regularity of molecular chains in the form of a random coil (spherical bead) is much lower than that of PAN fiber. It was confirmed that the compressive strength of the spherical PAN bead was greatly improved through the resonance cyclization and shrinkage according to the heat treatment, and it was also observed that the pores in PAN beads were formed after the heat treatment.

Performance of EDLC Electrodes Prepared by Post Treatments of Commercial Activated Carbon (상업용 활성탄의 후처리에 의하여 제조된 전기이중층 커패시터용 전극재의 특성)

  • Wu, Jing-Yu;Hong, Ik-Pyo;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.2
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    • pp.362-370
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    • 2013
  • The coconut shell based activated carbon was applied for EDLC (electric double layer capacitor) electrode with the post treatments. The electrochemical properties were evaluated with a coin cell using the activated carbon as electrode. The initial gravimetric and volumetric capacitance of the coconut shell based activated carbon electrode s were 66 F/g and 39 F/cc, and these values decreased to 54 F/g and 32 F/cc after 100 cycles, respectively showing 82% of charge-discharge efficiency. The properties of CV graph with the commercial activated carbon electrodes showed the serious polarization as the result of additional reaction between electrolyte and impurities of the electrode materials. In order to remove impurities efficiently, the commercial activated carbon was treated by alkali and acid solutions consecutively, and then heat treated to control the pore size distribution and the content of surface functional groups. The surface functional groups decreased with the increased heat temperature and the specific capacitance increased with the decreased surface functional groups. The initial capacitance of coconut shell based activated carbon elec trode which was treated with NaOH and HNO3, and then heat treated at $800^{\circ}C$ was 44 F/cc, and the value turned out to be 42 F/cc after 100 cycles, showing over 95% of charge-discharge efficiency.

Architecture Model of IOT Based Smart Animal Farms in Pakistan (파키스탄에서 IOT에 기반한 스마트 동물 농장의 아키텍처 모델)

  • Mateen, Ahamed;Zhu, Qingsheng;Afsar, Salman;Nazeer, Farah
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.18 no.6
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    • pp.43-52
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    • 2018
  • Livestock production is the second largest economic activity of Pakistan's rural population, more specifically; sixty-seven percent of Pakistan's total population that live in rural areas sources their income from livestock activities. As this subsector of agriculture within rural Pakistan is so critical to Pakistan's economy it is especially important to further develop the sector through the introduction of cost effective, efficient, and practical technologies. In an effort to improve such an important sector within the agriculture sector in Pakistan research has been carried out to better understand the capabilities and feasibility of leveraging Internet of Things based technologies, such as, microprocessors and microcontrollers within Pakistan's livestock production and management. The internet of Things can potentially allow for the scaling of small-scale rural livestock production to larger operations through cost effective and efficient livestock management through the application of IoT technologies. This paper discusses the architecture models of IoT based smart animal farms and delves into the pitfalls and advantages of applying IoT technologies in this sector. In this work we will explore the cheap sensors to monitor the internal activities of cattle farm with the aim of using these sensors as part of system to detect the important operations that need on the time response. This system should provide the feed and water as required, and control the temperature in sheds to protect the cattle being ill and on heat, and humidity level .internet connection used to connect these devices with smartphones or computers. In this paper we proposed the architecture model of IoT based smart animal farm.

Measuring the benefits from integrated energy business-based combined heat and power plant as a decentralized generation source with a focus on avoiding the damages caused by large-scale transmission facilities (분산형 전원으로서의 집단에너지사업 열병합발전의 송전망 피해 회피편익 추정)

  • Kim, Hyo-Jin;Choi, Hyo-Yeon;Yoo, Seung-Hoon
    • Journal of Energy Engineering
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    • v.24 no.3
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    • pp.67-73
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    • 2015
  • Almost base-loaded power plants such as flaming coal and nuclear energy require large-scale transmission facilities (LTFs) in order to send electricity to remote consumption areas. As well known, LTFs incur various social costs. However, a decentralized generation source such as integrated energy business (IEB)-based combined heat and power (CHP) plant is located in nearby electricity-consuming area, and thus it does not demand LTFs, providing the benefits from avoiding the damages caused by them. This study attempts to measure the benefits of avoiding the damages from the LTFs by the use of the contingent valuation (CV) method. To this end, a national survey of randomly chosen 1,000 households was implemented and the public's willingness to pay (WTP) for substituting consumption of electricity generated from flaming coal-fired power plant, currently a dominant generation source in Korea, with that produced from IEB-based CHP plant. The results show that the WTP for the substitution is estimated to be about 41.4 won per kWh. Considering that this value amounts to 33% of the average price of residential electricity in 2014, the external benefit of the IEB-based CHP as a decentralized generation appears to be large.

Characteristics of Isotherm, Kinetic and Thermodynamic Parameters for the Adsorption of Acid Red 66 by Activated Carbon (활성탄에 의한 Acid Red 66의 흡착에 대한 등온선, 동력학 및 열역학적 특성)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.26 no.1
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    • pp.30-38
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    • 2020
  • The kinetic and thermodynamic parameters of Acid Red 66, adsorbed by granular activated carbon, were investigated on areas of initial concentration, contact time, and temperature. The adsorption equilibrium data were applied to Langmuir, Freundlich, Temkin, Redlich-Peterson, and Temkin isotherms. The agreement was found to be the highest in the Freundlich model. From the determined Freundlich separation factor (1/n = 0.125 ~ 0.232), the adsorption of Acid Red 66 by granular activated carbon could be employed as an effective treatment method. Temkin's constant related to adsorption heat (BT = 2.147 ~ 2.562 J mol-1) showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo-second order model with good agreement. The results of the intraparticle diffusion equation showed that the inclination of the second straight line representing the intraparticle diffusion was smaller than that of the first straight line representing the boundary layer diffusion. Therefore, it was confirmed that intraparticle diffusion was the rate-controlling step. From thermodynamic experiments, the activation energy was determined as 35.23 kJ mol-1, indicating that the adsorption of Acid Red 66 was physical adsorption. The negative Gibbs free energy change (ΔG = -0.548 ~ -7.802 kJ mol-1) and the positive enthalpy change (ΔH = +109.112 kJ mol-1) indicated the spontaneous and endothermic nature of the adsorption process, respectively. The isosteric heat of adsorption increased with the increase of surface loading, indicating lateral interactions between the adsorbed dye molecules.

Low-Temperature SCR of NO over Physical Mixture of MnO2 and Metal-Loaded Activated Carbon (MnO2와와 금속담지활성탄의 물리적 혼합물을 이용한 NO의 저온 선택적 촉매 환원 반응)

  • Choi, Jong Cheol;Cho, Chul-Hoon;Jeong, Kwang-Eun;Jeon, Jong-Ki;Yim, Jin-Hyeong;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.92-97
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    • 2008
  • Selective catalytic reduction (SCR) of NO with ammonia was carried out over the physical mixture of $MnO_2$ and K or Cu-loaded activated carbons (AC) at low temperature. Introduction of oxygen affected positively the reduction of NO. Metal-impregnated AC showed significantly enhanced catalytic activity. Without water, the mixed catalyst of $MnO_2$ and K-loaded AC exhibited the best activity in the reduction of NO at $120^{\circ}C$. On the contrary, the activities of all the catalysts were significantly diminished in the presence of water. The mixed catalyst of $MnO_2$ and Cu-loaded AC treated with nitric acid and heat (1 : 1, w/w) exhibited the better activity for the reduction of NO than each single catalyst in presence of water.

Characterization of Activated Carbon from Wood by ZnCl2 (염화아연(ZnCl2) 부활법에 의해 제조한 목재 활성탄의 특성)

  • Kwon, Gu-Joong;Kwon, Sung-Min;Kim, Nam-Hun
    • Journal of Forest and Environmental Science
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    • v.23 no.1
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    • pp.51-55
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    • 2007
  • The effect of ratio between chemical activating agent and raw material in the preparation of activated carbons from wood has been studied. Pinus koraiensis wood and zinc chloride ($ZnCl_2$) were used for materials in this study. Mixtures of wood and zinc chloride were heated under nitrogen flow in the temperature ranging from room-temperature to $600^{\circ}C$ for 1 hr using thermogravimetric technique. During heat treatment, activated carbons with various pore size and specific surface properties were obtained. The maximum BET surface area and total pore volume were $1468m^2/g$ and 1.74 cc/g, respectively, at the mixture ratio of 1 (wood powder) to 5 ($ZnCl_2$). It can be concluded that the differences in the properties of the activated carbons were related significantly with the ratio of chemical activating regent.

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A study on the Optimization of Activated carbon Adsorbent Preparation condition and Evaluation of Application Supporting of K-Fe-Li ternary metal ions for Improving Adsorption Capacity of Hydrogen Sulfide (H2S) (황화수소(H2S) 흡착성능 증진을 위한 K-Fe-Li 3원계 금속이온물질이 담지된 활성탄 흡착제 제조조건 최적화 및 적용성 평가 연구)

  • Choi, Sung Yeol;Han, Dong hee;Kim, Sung Su
    • Clean Technology
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    • v.25 no.3
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    • pp.189-197
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    • 2019
  • In this study an optimization of the preparation conditions of activated carbon with a ternary metal ion material to treat $H_2S$, which is classified as a representative odor substance, was carried out. For a metal ion material for enhancing the adsorption performance of hydrogen sulfide, performance enhancement was confirmed by combining Li and Fe or a ternary combination (K, Li, Fe) based on KI, which is a substance promoting hydrogen sulfide adsorption performance. Also, it was determined by XRD analysis that the reaction of each active substance with $H_2S$ was because of binding. The adsorption performance increased more than 3 times with heat treatment of the adsorbent with nitrogen compared with heat treatment with air. The maximum adsorption constant ($q_m$) value of the optimum adsorbent was 97.07, which is 6 times higher than that of the existing K-based impregnated activated carbon. It was confirmed that the objective adsorption amount ($0.3g\;g^{-1}$) was secured by an equilibrium between the mass transfer rate and adsorption rate. From the results, it was confirmed that the performance improvement was noticeable even when activated carbon with a reagent grade activated carbon particle size was modified. It was confirmed that the adsorption performance exists at high relative humidity levels of 60 and 100%, and the optimized preparation can be applied to a wet process such as a scrubber downstream.