• Title/Summary/Keyword: HCHO (Formaldehyde)

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Preparation and Characterization of Porous Catalyst for Formaldehyde Removal using Domestic Low-grade Silica (국내산 저품위 실리카를 이용한 포름알데히드 제거용 다공성 촉매의 제조 및 특성)

  • Han, Yosep;Jeon, Ho-Seok;Kim, Seongmin
    • Resources Recycling
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    • v.30 no.2
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    • pp.68-74
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    • 2021
  • This study investigated formaldehyde (HCHO) removal by preparing porous supports using domestic low-grade silica coated with Co-ZSM5 and Cu-ZSM5 as the catalysts. First, the sample of the raw material for the support contained 90% silica with quartz crystal phase, which was confirmed as low-grade silica. According to Energy-dispersive X-ray spectroscopy (EDS) and Fourier-transform infrared spectroscopy (FT-IR) analyses, the catalysts, Co-ZSM5 and Cu-ZSM5, were successfully coated on the surface of the porous silica supports. During the removal test of HCHO using the prepared Co-ZSM5 and Cu-ZSM5 coated beads, depending on the reaction temperature, the Co-ZSM5 coated beads exhibited higher removal efficiencies (>97%) than the Cu-ZSM5 beads at 200 ℃. The higher efficiency of the Co-ZSM5 coating may be attributed to its superior surface activity properties (BET surface area and pore volume) that lead to the favorable HCHO decomposition. Therefore, Co-ZSM5 was determined to be the suitable catalyst for removing HCHO as a coating on a porous support fabricated using domestic low-grade silica.

Characteristics of Low Density Fiberboards Bonded with Different Adhesives for Thermal Insulation (II) - Formaldehyde·Total Volatile Organic Compounds Emission Properties and Combustion Shapes - (다양한 접착제로 제조한 단열재용 저밀도섬유판의 특성(II) - 폼알데하이드·총휘발성유기화합물 방출 특성 및 연소 형상 -)

  • Jang, Jae-Hyuk;Lee, Min;Kang, Eun-Chang;Lee, Sang-Min
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.5
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    • pp.580-587
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    • 2017
  • Woodfiber insulation board can be considered as a one of the key material for low energy consumption, comfortable and safety construction of residential space because of its eco-friendly and high thermal insulation performance. This study was carried out to investigate the formaldehyde (HCHO) total volatile organic compounds (TVOC) emission properties and combustion shapes by flame test of low density fiberboards (LDFs) prepared with different adhesives. HCHO TVOC emission and combustion properties of LDFs prepared by melamine urea formaldehyde (MUF), phenol formaldehyde (PF), emulsified methylene diphenyl diisocyanate (eMDI) and latex resin adhesives were measured by desiccator method, 20 L chamber method, and flame test, respectively. As results, LDFs manufactured by MUF, eMDI and latex resin adhesives satisfied the Super $E_0$ grade of HCHO emission performance except PF resin. Furthermore, TVOC emission of all LDFs were satisfied the Korean indoor air quality standard (below $400{\mu}g/m^2{\cdot}h$). Especially, LDF with eMDI resin adhesive showed the lowest HCHO and TVOC emissivity, that $0.14mg/{\ell}$, $12{\mu}g/m^2{\cdot}h$, respectively. However, eMDI emitted the small amount ($3{\mu}g/m^2{\cdot}h$) of toluene in VOC components. In the flame test, LDF with MUF resin adhesives showed the most favorable shape after flame test compare to LDFs prepared other adhesives. Based on HCHO and TVOC emission, and combustion shapes, MUF resin adhesive may be recommended to prepare LDF for insulation purpose.

A Study on the HCHO Grade of Architectural Material's Standard for Greenness with Consideration for Residents' Safety (거주자 안전을 고려한 친환경건축자재의 HCHO 듬급에 관한 고찰)

  • Song, Hyuk;Go, Seong-Seok;Chung, Woo-Yang
    • Journal of the Korean Society of Safety
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    • v.21 no.1 s.73
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    • pp.133-140
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    • 2006
  • According to Tokyo protocol which suggests the prevention of global environmental pollution, Korean government establishes the standard of architectural materials emission consistency with best effort to decrease the environmental pollution. But many current architectural materials which are used for constructing and remodeling buildings are composed of a variety of chemicals. These include stimuli bad for the residents' health and safety and harmful discharged air polluting substances such as volatile organic compounds(TVOCs) and formaldehyde(HCHO) that in tern include a variety of carcinogen substances. These discharged substances are also researched into inducing 'sick building syndrome' which induces headache, dizziness, vomiting and concentration failure among residents. But the standard of architectural materials according to the Korean apartment provision is limited to emission factors: HCHO and TVOCs. So the aim of this study is to present a standard of functional material's emission consistency about TVOCs including glues and paints, and a certification grade for green building by instituting a materials standard for green building which has consideration for the residents' safety.

A study on the field measurement of the TVOC and HCHO concentration in the newly constructed apartment houses in spring seasons (입주전 신축공동주택의 봄철 TVOC, HCHO농도 실태조사에 관한 연구)

  • Choi, Seung-Hyuck;Kim, Keon-Woo;Lee, Jong-Sik;Park, Jin-Chul;Kim, Sin-Do
    • Proceedings of the SAREK Conference
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    • 2007.11a
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    • pp.126-131
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    • 2007
  • This study aims to present the fundamental strategies for improving the Indoor Air Quality(IAQ) in newly-constructed apartment buildings. To investigate the concentration of indoor air pollutants such as HCHO and VOCs and the field measurement were conducted. According to the field measurement of 60 new houses in spring season, the concentration of HCHO in about 20% were higher the IAQ standards.

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Characteristic Analysis of Tropospheric Ozone Sensitivity from the Satellite-Based HCHO/NO2 Ratio in South Korea (위성 기반 HCHO/NO2 비율을 통한 국내 대류권 오존 민감도 특성 분석)

  • Jinah Jang;Yun Gon Lee ;Jeong-Ah Yu;Kyoung-Hee Sung;Sang-Min Kim
    • Korean Journal of Remote Sensing
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    • v.39 no.5_1
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    • pp.563-576
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    • 2023
  • In this study nitrogen dioxide (NO2), formaldehyde (HCHO) from the Ozone Monitoring Instrument (OMI) and TROPOspheric Monitoring Instrument (TROPOMI), OMI/ Microwave Limb Sounder (MLS) tropospheric column ozone (TCO), and Airkorea ground-based O3 data were analyzed to examine the photochemical reaction relationship between tropospheric ozone and its precursors nitrogen oxides (NOx) and volatile organic compounds (VOCs). As a result of analyzing the trend of long-term changes from 2006 to 2020 using OMI satellite data, TCO showed an increasing trend, NO2 steadily decreased, and HCHO continued to increase in Northeast Asia. In addition, formaldehyde nitrogen dioxide ratio (FNR; HCHO/NO2 ratio), an indicator of ozone sensitivity, is gradually increasing, which means that the VOC-limited regime is decreasing. This study conducted a sensitivity analysis of ozone generation using TROPOMI FNR and ground-based ozone (O3) over the recent years (2019~2022) to identify the possible cause for the continuous increase of ozone in Korea. Similar to the previous studies, VOC-limited and transitional regimes appeared in megacities, and VOC-limited regimes also appeared in areas where major power plants were located. In VOC-limited regimes, in other words, areas where NOx is excessively saturated, the reduction in NOx emissions may have weakened the ozone titration and thus led to the increase of ozone. Therefore, VOC emissions should be reduced in the short term rather than NOx emissions to reduce ozone concentrations under the VOC-limited regime.

Damage Characteristics of Korean Traditional Textiles by Formaldehyde (포름알데히드에 의한 전통직물의 손상 특성)

  • Kim, Myoung Nam;Lim, Bo A;Lee, Sun Myung
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.353-364
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    • 2014
  • Formaldehyde(HCHO) may have a damage effect on Korean traditional textiles, because concentration is high and occurrence frequency is frequent at the exhibition room and storage area. Total 20 specimens were prepared using 4 different materials (silk, cotton, ramie, hemp) after dyeing with 5 colors (undyed, red, yellow, blue, black). The specimens were exposed to HCHO gas in the test chamber. The gas acceleration test was conducted to identify the deterioration of Korean traditional textiles according to HCHO concentration(0.5, 1, 10, 100, 500ppm), to temperature-humidity condition at HCHO 500ppm, and deterioration conditions at HCHO 500ppm. Optical, chemical, and physical evaluation was carried out after the exposure. The results, color difference, grey scale rating, formate($HCO_2{^-}$) of some textiles increased at 500ppm, while pH decreased at 500ppm. Also, color difference, grey scale rating, formate($HCO_2{^-}$) of some textiles increased double damage at high temperatures & humidity, high humidity condition. But, damages of accelerated degradation textiles were slight, because of degradation degree and degradation products. The results suggest that determined the damage to the korean traditional textile, damage level, damage-weighted condition, damage to accelerated degradation textiles. In addition, formaldehyde damaged to yellowing of red textiles, bleaching of accelerated degradation textiles, formic acid damaged to bleaching of total 20 specimens.

Formaldehyde Deodorization Effect and Far-Infrared Emission Characteristics of Ceramics Prepared with Sawdust, Risk Husk, and Charcoal: Effect of Material Mixing Ratio

  • HWANG, Jung-Woo;OH, Seung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.2
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    • pp.104-112
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    • 2022
  • Indoor air quality is a very important environmental factor in modern society. However, air pollutants generated from various interior construction materials significantly affect the human body, including formaldehyde (HCHO) and volatile organic compounds that threaten public health by deteriorating indoor air quality. Effective in removing these harmful substances are porous materials, such as woodceramics. In this study, charcoal, a porous material, was added to rice husk, an agricultural by-product, and sawdust generated during the sawing process to prepare boards and ceramics at different mixing ratios, and the HCHO deodorization performance and far-infrared emission characteristics were measured. As the mixing ratio of charcoal increased, the deodorization rate of the boards and ceramics tended to increase. Overall, the deodorization rate was measured to be 80% to 90%, indicating that the boards and ceramics prepared with charcoal are suitable to be used for the purpose of deodorization. The effect of the material mixing ratio on far-infrared emissivity and emission power was insignificant.

Effect of Heating Temperature and Time of Coffee Waste on The Adsorptivity of Formaldehyde (폼알데하이드 흡착능에 대한 커피부산물의 열처리 조건 영향)

  • Ahn, Sye Hee
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.3
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    • pp.390-399
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    • 2015
  • This study was conducted to examine the potential use of coffee waste (CW) as an adsorbent of HCHO by adding into fiberboard. For the purpose, CW treated with various temperatures and times was placed in desiccator with a HCHO solution and then the HCHO adsorptivity of the CW was measured by acetylacetone (ATAN) and DNPH methods. In the results of ATAN analysis, amount of HCHO adsorbed in distilled water was the lowest on the non-treated CW and steadily increased to $100^{\circ}C$-treated temperature. However, over the $100^{\circ}C$, heating temperature (H-Temp) had not an effect on the HCHO adsorptivity of CW. Amount of HCHO adsorbed on CW itself was the highest at $100^{\circ}C$ H-Temp, following by $50^{\circ}C$, $150^{\circ}C$, $0^{\circ}C$, $250^{\circ}C$ and $200^{\circ}C$. For the HCHO adsorptivity of CW measured by DNPH methods, HCHO was not detected in the distilled water stirred with non-treated CW, but detected from the distilled water stirred with heating-treated CW. The content was the highest in the CW heating-treated at $100^{\circ}C$ for 10 min. In addition, HCHO adsorbed on CW itself increased to the H-Temp of $100^{\circ}C$ regardless of heating time, but decreased or reduced greatly degree of the increase over $100^{\circ}C$ H-Temp. In conclusion, optimal heating conditions of CW for the HCHO adsorption might be H-Temp between 100 and $150^{\circ}C$ with 10 min according as technical and economical reasons. Heating-treated CW manufactured with above the conditions can be used as an adsorbent in conventional fiberboard production for reducing HCHO emssion.

A Study for the Indoor Air Concentration of VOCs and HCHO in Newly Built and Remodeled Classrooms (신개축 교사내 실내공기중 휘발성유기화합물과 폼알데히드의 농도 특성)

  • Park, Jeong Ho;Yang, Su Myoung
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.3
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    • pp.222-228
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    • 2013
  • Objectives: The indoor air quality of newly-built (NC) and remodeled (RC) school classrooms was assessed. The primary aim was to show correlations between volatile organic compounds (VOCs) and formaldehyde (HCHO) pollutant levels. Methods: This study investigated the indoor air concentrations of VOCs and HCHO at 26 sites of newly built and 68 sites of remodeled classrooms located in South Gyeongsang Province between 2010 and 2012. VOCs in the indoor air were determined by adsorbent tube (Tenax TA) and automatic thermal desorption coupled with GC-MS analysis. Target analytes were five VOCs: benzene, toluene, ethylbenzene, xylene, and styrene. HCHO was collected with a 2,4-DNPH cartridge and analyzed by HPLC. Conclusions: This study estimated that indoor VOCs and HCHO concentrations in the classrooms were mainly affected by interior building materials and classroom equipment. For proper indoor air quality in schools, classroom air should be improved through reduction of hazardous materials by adequate ventilation, selecting environmental friendly materials, etc.

The Concentration Variation of Volatile Organic Compounds before and after Renovation in Apartment Houses (아파트 개조 전후의 휘발성유기화합물 농도변화 실태)

  • Choi, Yoon-Jung;Shim, Hyun-Suk;Shin, Hae-Chul
    • Journal of the Korean housing association
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    • v.18 no.4
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    • pp.59-67
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    • 2007
  • The purposes of this study were to make clear the present condition of the TVOC and HCHO concentration after renovation in apartment houses. The field measurements of TVOC and HCHO concentration according to the Korea Test Method Standard for Indoor Air Quality were carried out in 4 subject apartment houses. The results are as follows; the TVOC concentration after renovation in apartment houses ranged from mean 0.35ppm to mean 5.08ppm and increased of $0.35{\sim}5.08ppm$. The TVOC concentration of 3 subjects exceeded the Indoor Air Quality Management standard for the newly-built apartment houses (0.58ppm). The HCHO concentration after renovation ranged from mean 0.13ppm to mean 0.43ppm and increased of $0.06{\sim}0.26ppm$. The HCHO concentration of 2 subjects exceeded the Standard (0.17ppm). As results of analysis on the relation of concentrated ascension and renovation elements, the amount and the types of finishing materials and adhesives affected concentrated ascension. Also, production method for installed or purchased furniture had certain effect on the TVOC and HCHO concentration ascension.